This paper provides a synthesis of results that have emerged from recent modeling studies of the potential sensitivity of U.S. regional ozone (O3) concentrations to global climate change (ca. 2050). This research has been carried out under the auspices of an ongoing U.S. Environmental Protection Agency (EPA) assessment effort to increase scientific understanding of the multiple complex interactions among climate, emissions, atmospheric chemistry, and air quality. The ultimate goal is to enhance the ability of air quality managers to consider global change in their decisions through improved characterization of the potential effects of global change on air quality, including O3 The results discussed here are interim, representing the first phase of the EPA assessment. The aim in this first phase was to consider the effects of climate change alone on air quality, without accompanying changes in anthropogenic emissions of precursor pollutants. Across all of the modeling experiments carried out by the different groups, simulated global climate change causes increases of a few to several parts per billion (ppb) in summertime mean maximum daily 8-h average O3 concentrations over substantial regions of the country. The different modeling experiments in general do not, however, simulate the same regional patterns of change. These differences seem to result largely from variations in the simulated patterns of changes in key meteorological drivers, such as temperature and surface insolation. How isoprene nitrate chemistry is represented in the different modeling systems is an additional critical factor in the simulated O3 response to climate change.
A number of regulatory actions focused on reducing NOx emissions from stationary combustion sources have been taken in the United States in the last decade. These actions include the Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, and the NOx SIP Call rulemakings. In addition to these regulations, the recent Interstate Air Quality Rulemaking proposal and other bills in the Congress are focusing on additional reductions of NOx Industrial combustion sources accounted for about 18016 of NOx emissions in the United States in 2000 and constituted the second largest emitting source category within stationary sources, only behind electric utility sources. Based on these data, reduction of NOx emissions from industrial combustion sources is an important consideration in efforts undertaken to address the environmental concerns associated with NOx. This paper discusses primary and secondary NOx control technologies applicable to various major categories of industrial sources. The sources considered in this paper include large boilers, furnaces and fired beaters, combustion turbines, large IC engines, and cement kilns. For each source category considered in this paper, primary NOx controls are discussed first, followed by a discussion of secondary NOx controls. (c) 2005 American Institute of Chemical Engineers Environ.
The 1990 Clean Air Act (CAA) includes substantial new requirements to reduce emissions of nitrogen oxides (NOx) from major stationary sources. To help attain the ozone air quality standard in the near-term, certain existing sources must install reasonably available control technology (RACT) and new sources must install controls representing the lowest achievable emission rate. To reduce acid rain, coal-fired utility boilers must meet emission limits in two phases. In a longer-term, the CAA requires States to adopt additional control measures as needed to attain the ozone standard. Many of these attainment strategies will include new NOx controls which achieve emission reductions much greater than the NOx RACT/phase I acid rain limits. The CAA NOx requirements are new and experience with NOx controls is limited. There is a clear need for the development of NOx control systems to meet near- and long-term CAA requirements