Arrays of hundreds or thousands of low temperature detectors have been deployed for many experiments, both bolometers for long wavelength applications and calorimeters for shorter wavelength applications. One challenge that is common to many of these arrays is the efficient use of focal plane area to achieve a large fill fraction of absorbers coupled to detectors. We are developing an integrated fabrication of soft X-ray transition edge sensors (TES) and microwave SQUID multiplexers ($\mu$MUX) with the goal of maximizing the fill fraction of the focal plane area on a scale of many thousand pixel detectors. We will utilize lithographically defined high density interconnects to circumvent limitations in existing solutions that use wirebonds or flip-chip bonds. Here we report the first demonstration of combining TES and $\mu$MUX processes into a single TES-System-on-a-Chip (TES-SoC) fabrication on a silicon wafer. The $\mu$MUX SQUIDs and TES electrothermal feedback circuits are microfabricated first and protected with passivating SiO$_{2}$, then the TES devices and TES-to-SQUID interconnects are fabricated, and finally the protective layer is removed before the fabrication of the microwave resonators. We show that the microwave SQUIDs are functional and have reasonable yield, and that we are able to read out the transition temperature of the connected TESs using those SQUIDs.

Proximity effects at superconducting interfaces, between different superconductors (S-S') or between superconductors and normal metals (S-N), are fundamental to the performance of superconducting electronics, yet only few experiments have directly probed the spatial structure of proximity effects within a device. This is particularly relevant for transition edge sensors (TESs), where the interplay of direct and inverse proximity effects governs detector sensitivity. Here, we use scanning superconducting interference device (SQUID) susceptometry to directly image the local diamagnetic response in functional S-S'-S TES structures. We resolve long range proximity coupling extending over tens of micrometers, revealing that the local transition temperature is dramatically tuned by neighboring regions, being either enhanced by superconducting (S) leads or suppressed by normal metal (N) contacts. Our observations are quantitatively supported by Ginzburg Landau modeling of the device geometry and calculations of the temperature dependent diamagnetism based on self-consistent Usadel equations. By providing spatially resolved measurements of the interplay of proximity effects in TES devices, this work establishes a framework for understanding and controlling superconducting states in heterogeneous superconducting structures.

PAX (antiProtonic Atom X-ray spectroscopy) is a new experiment with the aim to test strong-field quantum electrodynamics (QED) effects by performing high-precision x-ray spectroscopy of antiprotonic atoms. By utilizing advanced microcalorimeter detection techniques and a low-energy antiproton beam provided by the ELENA ring at CERN, gaseous targets will be used for the creation of antiprotonic atoms, and the measurement of transitions between circular Rydberg states will be conducted with up to two orders of magnitude improved accuracy over previous studies using high-purity germanium detectors. Our approach eliminates the longstanding issue of nuclear uncertainties that have hindered prior studies using highly charged ions, thus enabling direct and purely QED-focused measurements. By precisely probing atomic systems with electric fields up to two orders of magnitude above the Schwinger limit, PAX will test vacuum polarization and second-order QED corrections, opening new frontiers in fundamental physics and uncovering potential pathways to physics beyond the Standard Model.

We present time-resolved X-ray diffraction measurements using advanced timing schemes that provide high temporal resolution while also maintaining a high flux in the X-ray probe beam. The method employs on-off patterned probe pulse sequences that are generated with the WaveGate solid-state pulse picker. We demonstrate the feasibility of our method at two different beamlines on millisecond and microsecond time scales.

Ultra-high energy resolution microcalorimeter gamma-ray spectroscopy—with energy resolution 5 to 10 times better than observed in spectra obtained by commercial-off-the-shelf high purity germanium detectors—is an enabling technology for ultra-precise isotope identification and quantification. Microcalorimeter gamma spectroscopy complements measurements requiring high-accuracy mass spectrometry, a costly, destructive analysis technique, and may offer benefits over mass spectrometry in the future. Microcalorimeter detectors are fabricated from superconducting materials and operate at ultra-low temperatures (<0.1 K), properties which permit measurement of spectra with peak full width half maximum (FWHM) of less than 100 eV at 100 keV. The microcalorimeter collaboration between Los Alamos National Laboratory, National Institute of Standards and Technology, and University of Colorado, Boulder has deployed three microcalorimeter gamma-ray spectrometers to nuclear facilities and analytical laboratories so far. These are the Spectrometer Optimized for Facility Integrated Applications (SOFIA), a portable system that can be moved to any facility, and two instruments called the High Efficiency and Resolution Microcalorimeter Spectrometers (HERMES) intended for permanent installation at Idaho National Laboratory and Pacific Northwest National Laboratory. Each spectrometer was customized to satisfy requirements for their specific applications. This work describes samples examined by microcalorimeter gamma-ray spectrometers, including recently irradiated materials, nuclear material from various stages of the fuel cycle, and medical isotope products. It also highlights useful signatures from actinide and fission product gamma-rays that are otherwise infeasible to observe or use for analysis without costly chemical separations and mass spectrometric assay. Microcalorimeter technology provides additional spectral signatures to existing techniques to better constrain the origin and intended use of nuclear and radioactive materials.

Time Division multiplexing (TDM) using superconducting quantum interference devices (SQUIDs) is being developed to read out Transition-edge sensor arrays for the Athena X-ray integral field unit (X-IFU) and Cosmic Microwave Background Stage-4, which have baselined differential TDM architectures. We present the design of symmetric multiplexer circuit read out by a second stage SQUID series array amplifier (SSAA) that has differential input coils that reject the current response to common mode pickup. We present measurements showing that readout with differential input coils has lower EMI susceptibility than with single ended input coils. We also present increases in bandwidth and reductions in crosstalk enabled by related changes to the multiplexer circuit.

A highly charged muonic ion is a unique few-body atomic system where a negatively charged muon and a few electrons are simultaneously bound to a single nucleus. We report the first state-selective observation of highly charged muonic Ar (mu Ar) by electronic K x-ray spectroscopy using an array of transition-edge sensor microcalorimeters. The high-precision K x-ray spectra provide a clear signature of the presence of muonic atoms with one, two, and three electrons, i.e., H-like, He-like, and Li-like mu Ar. With the aid of theoretical calculations, we confirmed that the peak positions are consistent with the x-ray energies from highly charged Cl ions, and the intensities reflect deexcitation dynamics of highly charged mu Ar.

A Super-Conducting ENergetic x-ray Telescope (ASCENT) is a concept for a future balloon-borne high-energy X-ray telescope in the energy range 60–85 keV to study gamma-ray emissions of 67.87 keV and 78.32 keV from the radioactive isotope 44Ti. For the focal plane instrumentation, ASCENT will use Mo-Cu/Mo-Au bilayer transition edge sensor (TES) microcalorimeter gamma-ray detectors with tin (Sn) absorbers. ‘Spectrometer to Leverage Extensive Development of Gamma-ray TESs for Huge Arrays using Microwave Multiplexed Enabled Readout’ (SLEDGEHAMMER), a detector development project at the National Institute of Standards and Technology, acts as the basis for the detector arrays for ASCENT. SLEDGEHAMMER has tin (Sn) absorbers attached to the SU-8 epoxy posts, lithographically placed on the detectors, but we are also considering other geometries for the chips where the absorbers are attached to the chips separated from the TESs, which could help to avoid parallel path for a current flow around the detectors with these BiSn sphere attachments. In this work, we are reporting on developing a method to attach Tin (Sn) absorbers to the transition edge sensors (TESs) with 0.2 mm diameter BiSn solder spheres replacing epoxy. The goal is to improve the thermal conductivity between the absorbers and the TESs compared to what was achieved using epoxy, potentially reducing the presence of an athermal component in the tails of signal pulses. We describe our efforts toward finding optimal temperature and pressure conditions for making this contact and the progress toward contact resistance measurements of these joints.

We present a detailed investigation of the performance of transition-edge sensor (TES) microcalorimeters with ^163 Ho atoms embedded by ion implantation, as part of the HOLMES experiment aimed at neutrino mass determination. The inclusion of ^163 Ho atoms introduces an excess heat capacity due to a pronounced Schottky anomaly, which can affect the detector’s energy resolution, signal height, and response time. We fabricated TES arrays with varying levels of ^163 Ho activity and characterized their performance in terms of energy resolution, decay time constants, and heat capacity. The intrinsic energy resolution was found to degrade with increasing ^163 Ho activity, consistent with the expected scaling of heat capacity. From the analysis, we determined the specific heat capacity of ^163 Ho to be (2.9 ± 0.4 (stat)± 0.7 (sys)) J/K/mol at (94 ± 1) mK, close to the literature values for metallic holmium. No additional long decay time constants correlated with ^163 Ho activity were observed, indicating that the excess heat capacity does not introduce weakly coupled thermodynamic systems. These results suggest that our present TES microcalorimeters can tolerate ^163 Ho activities up to approximately 5 Bq, with only about a factor of three degradation in performance compared to detectors without ^163 Ho. For higher activities, reducing the TES transition temperature is necessary to maintain or improve the energy resolution. These findings provide critical insights for optimizing TES microcalorimeters for future neutrino mass experiments and other applications requiring embedded radioactive sources. The study also highlights the robustness of TES technology in handling limited amounts of implanted radionuclides while maintaining high-resolution performance.

Sub-1 AMU mass determination is important for determining fission yields and neutron multiplicity, which are necessary inputs for fission models. Fission models can improve spent nuclear waste stream analysis and nuclear fuel burnup determination. To achieve this goal, we have used superconducting microcalorimeter detectors to directly measure the energy of fission fragments from the spontaneous fission of 252 Cf. With a fiber coupled LED pulser setup we demonstrate that we can reach a relative energy resolution of 0.1% and better for photon pulses with energies above 60 MeV. This instrument, in conjunction with time-of-flight (TOF) measurement, would allow for sub-1 atomic mass unit (AMU) mass determination of fission fragments in a future beamline application.

The electronic structure of oxyhemoglobin has been controversial since the discovery of the compound's diamagnetism in 1936. This study uses partial fluorescence yield Fe L-edge X-ray absorption spectroscopy (XAS) in the 3s→2p fluorescence on oxyhemoglobin solutions, measured using a transition-edge sensor detector, to obtain a quantitative experimental description of the electronic structure of the O2-bound iron site. The spectrum is very different from typical low-spin FeII and FeIII heme spectra, and multiplet simulations indicate a mixed ground configuration with ∼57% low-spin FeIII and ∼43% low-spin FeII character. This is also very different from the FeII character found for the picket-fence porphyrin model complex. The oxyhemoglobin L-edge XAS data further show that the O2 ligand engages in a weak σ- but strong π-bond with the iron ion, leading to the overall strong Fe-O2 bond required for O2 transport.

We demonstrate a method for radionuclide assay that is spectroscopic with 100 % counting efficiency for alpha decay. Advancing both cryogenic decay energy spectrometry (DES) and drop-on-demand inkjet metrology, a solution of Am-241 was assayed for massic activity (of order 100 kBq/g) with a relative combined standard uncertainty less than 1 %. We implement live-timed counting, spectroscopic analysis, validation by liquid scintillation (LS) counting, and confirmation of quantitative solution transfer. Experimental DES spectra are well modeled with a Monte Carlo simulation. The model was further used to simulate Pu-238 and Pu-240 impurities, calculate detection limits, and demonstrate the potential for tracer-free multi-nuclide analysis, which will be valuable for new cancer therapeutics based on decay chains, Standard Reference Materials (SRMs) containing impurities, and more widely in nuclear energy, environmental monitoring, security, and forensics.

We demonstrate a method for radionuclide assay that is spectroscopic with 100

Time division SQUID multiplexing is being developed as the TES readout technology for the ATHENA X-ray integral field unit and CMB-S4. Close packing of TDM and dc-biased SQUID components is motivated by chip area constraints but has resulted in significant physical neighbor crosstalk in previous generation chips. We present techniques to reduce physical neighbor crosstalk in both linear and two dimensional (2D) TDM chips as well as measurements of crosstalk in these chips.

X-ray nanotomography is a powerful tool for the characterization of nanoscale materials and structures, but it is difficult to implement due to the competing requirements of X-ray flux and spot size. Due to this constraint, state-of-the-art nanotomography is predominantly performed at large synchrotron facilities. We present a laboratory-scale nanotomography instrument that achieves nanoscale spatial resolution while addressing the limitations of conventional tomography tools. The instrument combines the electron beam of a scanning electron microscope (SEM) with the precise, broadband X-ray detection of a superconducting transition-edge sensor (TES) microcalorimeter. The electron beam generates a highly focused X-ray spot on a metal target held micrometers away from the sample of interest, while the TES spectrometer isolates target photons with a high signal-to-noise ratio. This combination of a focused X-ray spot, energy-resolved X-ray detection, and unique system geometry enables nanoscale, element-specific X-ray imaging in a compact footprint. The proof of concept for this approach to X-ray nanotomography is demonstrated by imaging 160 nm features in three dimensions in six layers of a Cu-SiO2 integrated circuit, and a path toward finer resolution and enhanced imaging capabilities is discussed.

Martensitic transformations enable various emerging applications like the shape memory effect and elastocaloric applications in NiTi. Increasing the speed of this transformation can shorten the response time for actuation and increase the power density of caloric cooling systems. Up to now, research on the speed and possible time limits of the martensitic transformation in NiTi has been limited to milli- and microsecond experiments. The dynamics of the transformation for shorter time scales are therefore unknown. Here, we report the fastest transformations in NiTi so far by heating an epitaxial NiTi film with a ns laser pulse and tracking the martensitic transition with in-situ synchrotron x-ray diffraction. We find that the martensite to austenite transition upon heating can proceed within the 7 ns pulse duration of the laser, but it requires substantial overheating as the rate of the transformation increases with the driving energy. The austenite to martensite transition is slower because cooling proceeds by conductive heat transfer, but with appropriate undercooling, the complete transformation from martensite to austenite and back only takes 200 ns. We compare our results to previous experiments on the Heusler alloy Ni-Mn-Ga and (K, Na)NbO3 and find very similar trends, which reveal that fast martensitic transformations in general follow a universal scaling law.

We have examined the influence of bump shape and bonding pressure on low-temperature electrical properties of indium bump connections including superconducting transition temperature, normal state resistance, and superconducting critical current. We describe our test structures, bonding process, and methods of characterization. At temperatures below 1 K, we observe critical currents greater than 70 mA for indium bump connections with a nominal bump size of 17 µm × 17 µm.

Superconducting transition-edge sensors (TESs) used in X-ray and γ -ray microcalorimeters suffer degraded performance if cooled in a magnetic field B sufficient to trap flux in the sensors. We report measurements of γ -ray TESs before and after implementing measures to reduce stray B fields from sources inside and outside the cryostat. These measurements showed a correlation between anomalous features in TES current–voltage (IV) curves and degraded energy resolution. After reducing internal sources of stray B field and improving shielding against external sources, both IV curves and energy resolution improved. Finally, we placed magnetized screws with remnant fields ∼ 10 T near similar γ -ray TESs in a different type of detector package and observed the same effects.

We have developed fine-pitch, multilayer, superconducting wiring for routing around a ninety-degree corner terminated with wirebonding interfaces. The component-level testbed for the Advanced Telescope for High Energy Astrophysics (ATHENA) X-Ray Integral Field Unit (X-IFU) focal plane requires compact, high-density, low-crosstalk wiring fanout to connect the detectors in the focal plane array with NIST-fabricated SQUID time domain multiplexing (TDM) readout chips. The full assembly baselines two interface chips: a flexible interface chip bending around the corner and a planar silicon carrier chip. The TDM readout is indium bump-bonded to the silicon carrier and afterward the flexible chip is clipped in place and wirebonded to the detector and fanout wiring on the carrier. This assembly is repeated for each side of the hexagonal focal plane structure. As conventional commercial cables are not able to achieve the fine-pitch, low-crosstalk, superconducting wiring required, we fabricate these flexible interface chips in-house via lithographic patterning and etching of sputter deposited thin films to create broadside-coupled superconducting niobium microstrips. Within the chip, the wiring on the flexible polyimide region transitions to silicon substrate for the closely spaced wirebond pads. The Nb microstrip wiring climbing a thick polyimide sidewall presents a fabrication challenge which we shall discuss in this paper. We describe the function of these components to build an effective engineering testbed for the ATHENA X-IFU.

We report on the 1,000-element transition-edge sensor (TES) x-ray spectrometer implementation of the TOMographic Circuit Analysis Tool (TOMCAT). TOMCAT combines a high spatial resolution scanning electron microscope (SEM) with a highly efficient and pixelated TES spectrometer to reconstruct three-dimensional maps of nanoscale integrated circuits (ICs). A 240-pixel prototype spectrometer was recently used to reconstruct ICs at the 130 nm technology node, but to increase imaging speed to more practical levels, the detector efficiency needs to be improved. For this reason, we are building a spectrometer that will eventually contain 3,000 TES microcalorimeters read out with microwave superconducting quantum interference device (SQUID) multiplexing, and we currently have commissioned a 1,000 TES subarray. This still represents a significant improvement from the 240-pixel system and allows us to begin characterizing the full spectrometer performance. Of the 992 maximimum available readout channels, we have yielded 818 devices, representing the largest number of TES x-ray microcalorimeters simultaneously read out to date. These microcalorimeters have been optimized for pulse speed rather than purely energy resolution, and we measure a FWHM energy resolution of 14 eV at the 8.0 keV Cu K$\bm {\alpha}$ line.