Mars’ water history is fundamental to understanding Earth-like planet evolution. Water escapes to space as atoms, and hydrogen atoms escape faster than deuterium giving an increase in the residual D/H ratio. The present ratio reflects the total water Mars has lost. Observations with the Mars Atmosphere and Volatile Evolution (MAVEN) and Hubble Space Telescope (HST) spacecraft provide atomic densities and escape rates for H and D. Large increases near perihelion observed each martian year are consistent with a strong upwelling of water vapor. Short-term changes require processes in addition to thermal escape, likely from atmospheric dynamics and superthermal atoms. Including escape from hot atoms, both H and D escape rapidly, and the escape fluxes are limited by resupply from the lower atmosphere. In this paradigm for the escape of water, the D/H ratio of the escaping atoms and the enhancement in water are determined by upwelling water vapor and atmospheric dynamics rather than by the specific details of atomic escape.

lis, D. Y. Lo, A. Rahmati, J. I. Deighan, J. L. Fox, R. Yelle, Y. Lee, F. Leblanc, J.-Y. Chaufray, T. Cravens, M. Gacesa, M. Chaffin, B. M. Jakosky UC Berkeley Space Sciences Laboratory (rlillis@ssl.Berkeley.edu), Lunar and Planetary Laboratory, University of Arizona, Laboratory for Atmospheric and Space Physics, University of Colorado Boulder, Department of Physics, Wright State University, NASA Goddard Space Flight Center, LATMOS, Paris, Physics department, U. Kansas, NASA Ames Research Center

We analyze the ultraviolet nightglow in the atmosphere of Mars through nitric oxide (NO) δ and γ band emissions as observed by the Imaging UltraViolet Spectrograph (IUVS) instrument onboard the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft when it is at apoapse and periapse.In the dayside thermosphere of Mars, solar extreme-ultraviolet radiation dissociates CO2 and N2 molecules. O(3P) and N(4S) atoms are carried from the dayside to the nightside by the day-night hemispheric transport process, where they descend through the nightside mesosphere and can radiatively recombine to form NO(C2Π). The excited molecules rapidly relax by emitting photons in the UV δ and γ bands. These emissions are indicators of the N and O atom fluxes from the dayside to Mars’ nightside and the descending circulation pattern from the nightside thermosphere to the mesosphere (e.g. Bertaux et al., 2005 ; Bougher et al., 1990 ; Cox et al., 2008 ; Gagne et al., 2013 ; Gerard et al., 2008 ; Stiepen et al., 2015, 2017).Observations of these emissions are gathered from a large dataset spanning different seasonal conditions.We present discussion on the variability in the brightness and altitude of the emission with season, geographical position (longitude), and local time, along with possible interpretation by local and global changes in the mesosphere dynamics. We show the possible impact of atmospheric waves forcing longitudinal variability and data-to-model comparisons indicating a wave-3 structure in Mars’ nightside mesosphere. Quantitative comparison with calculations of the Laboratoire de Meteorologie Dynamique-Mars Global Climate Model (LMD-MGCM) suggests the model reproduces both the global trend of NO nightglow emission and its seasonal variation. However, it also indicates large discrepancies, with the emission up to a factor 50 times fainter in the model, suggesting that the predicted transport is too efficient toward the night winter pole in the thermosphere by ˜20° latitude to the north.These questions are now addressed through an extensive dataset of disk images, in complement to improved simulations of the LMD-MGCM and the Mars Global Ionosphere-Thermosphere Model (MGITM) models.

Workshop organized by ESA-ESAC & IAA-CSIC, with the support of the ESAC Faculty and the EU H2020 project UPWARDS MAVEN IUVS Remote Sensing Highlights Relevant to Upcoming TGO Observations M. Chaffin (1), N. M. Schneider (1), J. Deighan (1), S.K. Jain (1), A. Stiepen (2), F. Lefevre (3), H. Groller (4), M. Crismani (1), A.I.F. Stewart (1), J.T. Clarke (5), M. Mayyasi (5), J.S. Evans (6), M.H. Stevens (7), J.-Y. Chaufray (3), W.E. McClintock (1), G.M. Holsclaw (1), F. Montmessin (3), R.V. Yelle (4), D. Lo (4), and B. M. Jakosky (1) (1) Laboratory for Atmospheric and Space Physics, Boulder, Colorado, USA, (2) LPAP, University of Liege, Liege, Belgium, (3) LATMOS/IPSL, Guyancourt, France, (4) LPL, University of Arizona, Tucson, Arizona, USA, (5) CSP, Boston University, Boston, Massachussets, USA, (6) Computational Physics Incorporated, Springfield, Virginia, USA, (7) Space Science Division, Naval Research Laboratory, Washington DC, USA

As a minor species in the Martian thermosphere, Carbon Monoxide (CO) is a tracer that can be used to constrain changing circulation patterns between the lower thermosphere and upper mesosphere of Mars. By linking CO density distributions to dynamical wind patterns, the structure and variability of the atmosphere will be better understood. Direct measurements of CO can therefore provide insight into the magnitude and pattern of winds and provide a metric for studying the response of the atmosphere to solar forcing. In addition, CO measurements can help solve outstanding photochemical modeling problems in explaining the abundance of CO at Mars. CO is directly observable by electron impact excitation and solar resonance fluorescence emissions in the far-ultraviolet (FUV). The retrieval of CO from solar fluorescence was first proposed over 40 years ago, but has been elusive at Mars due to significant spectral blending. However, by simulating the spectral shape of each contributing emission feature, electron impact excitation and solar fluorescence brightnesses can be extracted from the composite spectrum using a multiple linear regression approach. We use CO Fourth Positive Group (4PG) molecular band emission observed on the limb (130 - 200 km) by the Imaging Ultraviolet Spectrograph (IUVS) on NASA’s Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft over both northern and southern hemispheres from October 2014 to December 2016. We present the first direct retrieval of CO densities by FUV remote sensing in the upper atmosphere of Mars. Atmospheric composition is inferred using the terrestrial Atmospheric Ultraviolet Radiance Integrated Code adapted to the Martian atmosphere. We investigate the sensitivity of CO density retrievals to variability in solar irradiance, solar longitude, and local time. We compare our results to predictions from the Mars Global Ionosphere-Thermosphere Model as well as in situ measurements by the Neutral Gas and Ion Mass Spectrometer on MAVEN and quantify any differences.

The Imaging Ultraviolet Spectrograph (IUVS) instrument on the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft takes mid-UV spectral images of the Martian atmosphere. From these apoapse disk images, information about clouds and aerosols can be retrieved and comprise the only MAVEN observations of topographic clouds and cloud morphologies. Measuring local time variability of large-scale recurring cloud features is made possible with MAVEN’s ~4.5-hour elliptical orbit, something not possible with sun-synchronous orbits. We have run the LMD MGCM (Mars global circulation model) at 1° x 1° resolution to simulate water ice cloud formation with inputs consistent with observing parameters and Mars seasons. Topographic clouds are observed to form daily during the late mornings of northern hemisphere spring and this phenomenon recurs until late summer (Ls = 160°), after which topographic clouds wane in thickness. By northern fall, most topographic clouds cease to form except over Arsia Mons and Pavonis Mons, where clouds can still be observed. Our data show moderate cloud formation over these regions as late as Ls = 220°, something difficult for the model to replicate. Previous studies have shown that models have trouble simulating equatorial cloud thickness in combination with a realistic amount of water vapor and not-too-thick polar water ice clouds, implying aspects of the water cycle are not fully understood. We present data/model comparisons as well as further refinements on parameter inputs based on IUVS observations.

Nitric oxide (NO) is a well-known indicator of solar and auroral activity in the terrestrial upper atmosphere. Direct measurements of NO on Mars can therefore constrain studies of energetic processes controlling the composition and structure of its upper atmosphere (80-200 km). Identifying and quantifying these processes is one of the science objectives of NASA’s Mars Atmosphere and Volatile Evolution (MAVEN) mission currently orbiting Mars. NO can be observed directly by solar resonance fluorescence in the mid-ultraviolet (MUV). Indeed, this approach has routinely been used to measure terrestrial NO for 50 years. On Mars, this “dayglow” emission is very weak relative to other bright MUV features and thus has confounded attempts at its detection there for nearly the same amount of time. Here, we report the first detection of the NO dayglow in the Martian atmosphere using limb observations by the Imaging Ultraviolet Spectrograph (IUVS) on the MAVEN spacecraft. The detection is enabled by the spectral modeling and removal of the carbon monoxide Cameron bands, which dominate the MUV limb spectra. We focus on the spectral region between 213.0-225.5 nm, where three NO gamma bands emit. We will infer NO densities from the dayglow spectra and compare our observations with predictions from a photochemical model. We will discuss the implications, particularly in the context of previous in situ measurements.

Newly released Imaging Ultraviolet Spectrograph/Mars Atmosphere and Volatile EvolutioN (IUVS/MAVEN) measurements of CO2 density in the Martian thermosphere have been used for comparison with the predictions of the Max Planck Institute Martian General Circulation Model (MPI-MGCM). The simulations reproduced (within one standard deviation) the available zonal mean density and derived temperature above 130 km. The MGCM replicated the observed dominant zonal wave number 3 nonmigrating tide and demonstrated that it represents a nonmoving imprint of the topography in the thermosphere. The comparison shows a great dependence of the simulated density and temperature to the prescribed solar flux, atomic oxygen abundances and gravity wave effects, with the former two being especially important in the thermosphere above 130 km and the latter playing a significant role both in the mesosphere and thermosphere.

The Imaging Ultraviolet Spectrograph (IUVS) on NASA's Mars Atmosphere and Volatile Evolution (MAVEN) mission observed the Martian upper atmosphere in late 2015 (Ls ~ 70) and early 2016 (Ls ~ 150). Although designed to measure the dayglow between 90-200 km IUVS also scans the limb down to 60 km, where solar scattered light dominates the mid-ultraviolet (MUV) signal. Occasionally, this MUV light shows enhanced scattering between 60-90 km indicating the presence of aerosols in the mesosphere. We quantify the solar scattering for each daylight scan obtained between October and December, 2015 and between April and June, 2016. We then identify over 100 scans of enhanced scattering between 60-90 km and assemble them both geographically and diurnally. The geographical distribution of the enhancements in 2015 is preferentially located near the equator, consistent with previous observations of mesospheric clouds for this part of the season. A wave three pattern in equatorial cloud occurrence suggests forcing from a non-migrating tide, possibly linked to the longitudinal variation of Mars surface topography. At the same time, there are indications of a diurnal variation such that the clouds seen in 2015 and 2016 are preferentially observed in the early morning, between 0600-0900 local solar time. This suggests an important role for a migrating temperature tide controlling the formation of Martian mesospheric clouds.

We report the observations of longitudinal variations in the Martian thermosphere associated with nonmigrating tides. Using the Neutral Gas Ion Mass Spectrometer (NGIMS) and the Imaging Ultraviolet Spectrograph (IUVS) on NASA's Mars Atmosphere and Volatile EvolutioN Mission (MAVEN) spacecraft, this study presents the first combined analysis of in situ and remote observations of atmospheric tides at Mars for overlapping volumes, local times, and overlapping date ranges. From the IUVS observations, we determine the altitude and latitudinal variation of the amplitude of the nonmigrating tidal signatures, which is combined with the NGIMS, providing information on the compositional impact of these waves. Both the observations of airglow from IUVS and the CO2 density observations from NGIMS reveal a strong wave number 2 signature in a fixed local time frame. The IUVS observations reveal a strong latitudinal dependence in the amplitude of the wave number 2 signature. Combining this with the accurate CO2 density observations from NGIMS, this would suggest that the CO2 density variation is as high as 27% at 0-10 degrees latitude. The IUVS observations reveal little altitudinal dependence in the amplitude of the wave number 2 signature, varying by only 20% from160 to 200 km. Observations of five different species with NGIMS show that the amplitude of the wave number 2 signature varies in proportion to the inverse of the species scale height, giving rise to variation in composition as a function of longitude. The analysis and discussion here provide a roadmap for further analysis as additional coincident data from these two instruments become available.

Ozone (O3) on Mars is a product of the CO2 photolysis by ultraviolet radiation. It is destroyed with a timescale of less than ~1 hour during the day by the H, OH, and HO2 radicals. This tight coupling between O3 and HOx species makes ozone a sensitive tracer of the odd hydrogen chemistry that stabilizes the CO2 atmosphere of Mars, and ozone measurements offer a powerful constraint for photochemical models. Ozone is also expected to be anti-correlated to water vapour, the source of hydrogen radicals HOx. At high latitudes in winter, the absence of H2O prevents the production of HOx and the chemical lifetime of ozone may increase up to several days. In these conditions, the ozone column abundance usually reaches its largest values of the Martian year and ozone turns into a measurable tracer of the polar vortex dynamics. The Imaging Ultraviolet Spectrograph (IUVS) is one of nine science instruments aboard the Mars Atmosphere and Volatile and Evolution (MAVEN) spacecraft. In the apoapse imaging phase, the spacecraft motion carries the IUVS lines-of-sight across the Martian disk while the scan mirror is used to make transverse swaths. This observation mode allows mapping the ozone vertically-integrated column from its signature in the solar ultraviolet flux backscattered by the surface and the atmosphere. This paper will present an overview of the first year of ozone mapping by IUVS. We will describe in particular the last Mars northern winter (2015) when the largest ozone columns have been observed since the beginning of the MAVEN mission. The data will be compared to prior Earth-based observations and to the SPICAM and MARCI ozone datasets. We will also test our quantitative understanding of the Martian ozone by comparing the IUVS observations to our three-dimensional model with photochemistry.