We report on asymmetrically shaped Fano resonances in Al0.2Ga0.8N/GaN-based quantum cascade structures. In order to observe this type of resonance in electro-luminescence, a spectrally narrow feature must interact with a broad, quasi-continuous emission. While the narrow waveform is provided by the GaN-based LO-phonon at 92 MeV (13.5 µm, 741 cm−1), the broad peak consists of overlapping inter-subband transitions between several higher-order excited states ranging from 80 to 300 MeV and the ground state. Through the interference of these spectrally dissimilar peaks, a typical, asymmetric Fano line shape is generated.
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In the present article, we propose a monolithically integrated Michelson interferometer using a λ = 4 µm InGaAs/InAlAs quantum cascade laser as the light source. By using simple fringe detection and a four-point interpolation on each fringe, we will be able to detect minimal object displacements of 500 nm—corresponding to 25% of half the laser emission wavelength. Such an interferometric photonic integrated circuit has interesting applications for precision computerized numerical controlled machines. Since the industrial standard of such machines currently consists of glass-based linear encoders with a resolution of 5 µm, our interferometer-based system will enable an improvement of at least one order of magnitude.
In this study, we report on the ultra-short lifetime of excited intersubband electrons in a 38 Å wide AlGaN/GaN-based quantum well. The rapid decay of these charge carriers occurs due to a resonance between the relevant intersubband transition energy and the size of the GaN-based LO-phonon at 92 meV. Based on the experimentally observed Lorentz-shaped intersubband emission peak with a spectral width of roughly 6 meV (48 cm−1) respecting the Fourier transform limit, a very short lifetime, namely 111 fs, could be calculated. By comparing this lifetime to the existing literature data, our value confirms the potential high-speed capability of III-nitride-based optoelectronics.
We describe an all-optical method to achieve—prior to further advanced processing steps—a perfect match of the relevant wavelength-sensitive parameters of an InGaN/GaN semiconductor distributed feedback laser. Instead of permanently etching and epitaxially over-growing a waveguide-based diffraction grating for the definition of an index-coupled distributed feedback laser, we suggest here—by employing a powerful ultraviolet pump laser—a non-permanent, photoinduced generation of an optical diffraction grating. The resulting complex refractive index modulation then forms a gain-coupled distributed feedback laser. Such an approach has the advantage of remaining flexible as long as possible—both in terms of the correct grating period and the ideal coupling constant. This flexibility is maintained until the definitive etch and the epitaxial over-growth of the diffraction grating are completed. Such devices can—like their dye laser counterparts in the early seventies—also be used as ultra-broadly tunable single-mode sources.
We propose the use of an n-doped periodic AlN/GaN quantum cascade structure for the optical up-conversion of multiple near-infrared (near-IR) photons into deep-ultraviolet (deep-UV) radiation. Without applying an external bias voltage, the active region of such a device will (similar to an un-biased quantum cascade laser) resemble a sawtooth-shaped inter-subband structure. A carefully adjusted bias voltage then converts this sawtooth pattern into a ‘quantum-stair’. Illumination with λ = 1.55 µm radiation results in photon absorption thereby lifting electrons from the ground state of each main well into the first excited state. Three additional GaN quantum wells per period then provide by LO-phonon-assisted tunneling a diagonal transfer of these electrons towards the ground level of the neighboring period. From there, the next near-infrared (near-IR) photon absorption, electron excitation, and partial relaxation takes place. After 12 such absorption, transfer, and relaxation processes, the excited electrons have gained a sufficiently high amount of energy to undergo in the final AlN-based p-type contact layer an electron-hole band-to-band recombination. By employing this procedure, multiple near-IR photons will be up-converted to produce deep-UV radiation. Since for a wavelength of 1.55 µm very powerful near-IR pump lasers are readily available, such an up-conversion device will (even at a moderate overall conversion efficiency) potentially result in an equal or even higher output power than the one of an AlN-based p-n-junction light-emitting diode. The proposed structures are therefore very interesting for applications such as ultra-high-resolution photolithography or printing, water purification, medical equipment disinfection, white light generation, or the automotive industry.
An optically activated, enhancement mode heterostructure field effect transistor is proposed and analytically studied. A particular feature of this device is its gate region, which is made of a photovoltaic GaN/AlN-based superlattice detector for a wavelength of 1.55 µm. Since the inter-subband transition in this superlattice does normally not interact with TE-polarized (or vertically incoming) radiation, a metallic second-order diffraction grating on the transistor gate results in a re-orientation of the light into the horizontal direction—thus providing the desired TM-polarization. Upon illumination of this gate, efficient inter-subband absorption lifts electrons from the ground to the first excited quantized state. Due to partial screening of the strong internal polarization fields between GaN quantum wells and AlN barriers, this slightly diagonal transition generates an optical rectification voltage. Added to a constant electrical bias, this optically produced gate voltage leads to a noticeable increase of the transistor’s source-drain current. The magnitude of the bias voltage is chosen to result in maximal transconductance. Since such a phototransistor based on high-bandgap material is a device involving only fast majority carriers, very low dark and leakage currents are expected. The most important advantage of such a device, however, is the expected switching speed and, hence, its predicted use as an optical logic gate for photonic computing. In the absence of a p-n-junction and thus of both a carrier-induced space charge region, and the parasitic capacitances resulting thereof, operation frequencies of appropriately designed, sufficiently small phototransistors reaching 100 GHz are envisaged.
The effect of hydrostatic pressure on optical transitions in InGaN/GaN multiple quantum wells (MQWs) has been studied. Photoluminescence (PL) and photomodulated transmission (PT) measurements were performed under applied pressure to examine the pressure dependence of optical transitions associated with confined states in MQWs. The PL emission from the MQWs was found to shift linearly to higher energy with applied pressure but exhibit a significantly weaker pressure dependence compared to epilayer samples with similar bandgap energies. Similar pressure coefficients obtained by PT measurements rule out the possibility of PL resulting from deep localized states. We show that the difference in the compressibility of InGaN and of GaN induces a tensile strain in the compressively strained InGaN well layers that partially compensates the applied hydrostatic pressure. This mechanical effect is the primary factor for the smaller pressure dependence of the optical transitions in the InGaN/GaN MQWs. At pressure above 100 kbar, the PL signal in MQWs samples is quenched, indicating that the carriers involved in the radiative recombination processes in the well layers originate primarily from the adjacent GaN layers.
We present a GaN-based quantum-cascade device whose inter-subband emission shows strong electron-phonon interaction. To generate the luminescence, an external electrical field - which partially screened the internal polarization - had to be applied. In low intensity spectra, a pattern of secondary peaks occurs. Each side-peak is separated from its fundamental inter-subband transition by a characteristic phonon energy, which shifts with applied field at the same rate as the main transition. At high intensity, there exists resonance between the 92 meV LO-phonon and the vertical inter-subband transition. A strong electrical field of >1 MV cm(-1) reduced via QCSE the transition energy from 230 meV to 80 meV. Additionally, the low active region doping necessitated large operating voltages. Besides the emission of mid-infrared radiation, the elevated voltage generated lots of phonons. At an electrical field of 1.02 MV cm(-1), the frequency-shifted inter-subband luminescence became resonant with the LO-phonon. The effects of this resonance will be discussed.
Electrical performance and defect characterization of vertical GaN P-i-N diodes before and after irradiation with 2.5 MeV protons and neutrons is investigated. Devices exhibit increase in specific on-resistance following irradiation with protons and neutrons, indicating displacement damage introduces defects into the p-GaN and n- drift regions of the device that impact on-state device performance. The breakdown voltage of these devices, initially above 1700 V, is observed to decrease only slightly for particle fluence <; 1013 cm-2. The unipolar figure of merit for power devices indicates that while the on-resistance and breakdown voltage degrade with irradiation, vertical GaN P-i-Ns remain superior to the performance of the best available, unirradiated silicon devices and on-par with unirradiated modern SiC-based power devices.
There is a great interest in wide-bandgap semiconductor devices and most recently in monolithic GaN structures for power electronics applications. In this paper, vertical p-n diodes fabricated on pseudobulk low defect density (10(4)-10(6) cm(-2)) GaN substrates are discussed. Homoepitaxial low-pressure metal organic chemical vapor deposition growth of GaN on its native substrate and being able to control and balance the n-type Si doping with background C impurity has allowed the realization of vertical device architectures with drift layer thicknesses of 6 to 40 mu m and net carrier electron concentrations of 4 x 10(15) to 2.5 x 10(16) cm(-3). This parameter range is suitable for applications requiring breakdown voltages (BVs) of 600 V-4 kV with a proper edge termination strategy. Measured devices demonstrate near power device figure of merit, that is, differential specific on-resistance (R-sp) of 2 m Omega cm(2) for a BV of 2.6 kV and 2.95 m Omega cm(2) for a 3.7-kV device, respectively. The improvement in the substrate quality over the last few years has resulted in the fabrication of diodes with areas as large as 16 mm(2), with BVs exceeding 700 V and pulsed (100 mu s) currents of 400 A. The structures fabricated are utilized to study in detail the temperature dependency of I-V characteristics, impact ionization and avalanche characteristics, and extract (estimate) modeling parameters such as electron mobility in the GaN c-direction (vertical) and hole minority carrier lifetimes. Some insight into device reliability is also provided.
We present electro-modulated absorption and electro-luminescence measurements on chirped AlGaN/GaN-based multi-quantum well inter-subband structures grown by metal-organic vapour phase epitaxy. The absorption signal is a TM-polarized, 70 meV wide feature centred at 230 meV. At medium injection current, a 58meV wide luminescence peak corresponding to an inter-subband transition at 1450 cm(-1) (180 meV) is observed. Under high injection current, we measured a 4 meV wide structure peaking at 92.5 meV in the luminescence spectrum. The energy location of this peak is exactly at the longitudinal optical phonon of GaN. (C) 2014 AIP Publishing LLC.
Vertical diodes with breakdown voltages up to 2.6kV have been fabricated on bulk GaN substrates. The measured figures-of-merit of these devices show performance near the theoretical limit of GaN. These vertical GaN diodes exhibit robust avalanche breakdown behavior with a positive temperature coefficient. System-level performance advantages have been demonstrated in power conversion applications. Statistical data have been collected from thousands of devices. Initial reliability tests have been completed.
Vertical diodes have been fabricated on low defect density bulk GaN substrates. The devices demonstrate performance near theoretical limits for on-state resistance at a given rated breakdown voltage, based on GaN material properties. Breakdown voltage up to 3.7 kV has been measured. Measurements reveal robust avalanche breakdown, critical in an inductive circuit environment. Measurement of switching transients (5-25A) indicates the lack of minority carrier storage and low capacitances resulting in very low switching losses for the devices.
Luminescence in the near band-edge spectral region of Mg-doped GaN films grown by metalorganic chemical vapor deposition has been studied at liquid-helium temperatures. Radiative transitions at 3.37 and 3.416 eV were observed to evolve in cathodoluminescence spectra during electron-beam irradiation at 5 kV. The intensity of the 3.37 eV peak correlates monotonically with the resistivity of the films. By annealing the films in N2 and N2/H2 atmospheres, the 3.37 and 3.416 eV transitions are shown to be related to hydrogen.
Experimental and theoretical evidence is presented for oxygen DX centers in AlxGa1−xN. As the aluminum content increases, Hall effect measurements reveal an increase in the electron activation energy, consistent with the emergence of a deep DX level from the conduction band. Persistent photoconductivity is observed in Al0 39Ga0. 61N:O at temperatures below 150 K after exposure to light, with an optical threshold energy of 1.3 eV, in excellent agreement with first-principles calculations. Unlike oxygen, silicon does not exhibit DX-like behavior, in agreement with previous theoretical predictions.
Gax In1 − x Pepilayers grown under a range of growth conditions by organometallic vapor phase epitaxy (OMVPE) on GaAs substrates have been studied in the electron microscope. The results show the presence of an ordering of the group III sublattice parallel to some of the {111} planes. Dark-field images directly reveal ordered domains of different orientations that appear not to be perfect, but contain many planar defects parallel to the growth surface.