Liquid phase separation using aqueous biphasic systems (ABS) is widely used in industrial processes for the extraction, separation and purification of macromolecules. Using water as the single solvent, a wide variety of solutes have been used to induce phase separation including polymers, ionic liquids or salts. For each system, polymer-polymer, polymer-ionic liquid, polymer-salt or salt-salt, different driving forces were proposed to induce phase separation. Specifically, for polymer-salt systems, a difference in solvation structure between the polymer-rich and the salt-rich was proposed, while other reports suggested that a large change in enthalpy and entropy accompanied the phase separation. Here, we reinvestigated the PEG/K2HPO4/H2O systems using a combination of liquid-phase nuclear magnetic resonance (NMR) and high-resolution Raman spectroscopies, coupled with injection microcalorimetry. Both NMR and Raman reveal a decreased water concentration in the PEG-rich phase, with nonetheless no significant differences observed for both 1H chemical shift or OH stretching vibrations. Hence, both PEG- and salt-rich phases exhibit similar water solvation properties, which is thus not the driving force for phase separation. Furthermore, NMR reveals that PEG interacts with salt ions in the PEG-rich solution, inducing a downfield shift with increasing salt concentration. Injection microcalorimetry measurements were carried out to investigate any effect due to enthalpy change during mixing. Nevertheless, these measurements indicate very small enthalpy changes when mixing PEG- and salt-rich solutions in comparison with that previously recorded for salt-salt systems or associated with mixing of two solvents. Hence, our study discards any large change of enthalpy as the origin for phase separation of PEG/K2HPO4 systems, in addition to large difference in solvation properties. We reinvestigated the PEG/K2HPO4/H2O systems using a combination of liquid-phase nuclear magnetic resonance and high-resolution Raman spectroscopies, coupled with injection microcalorimetry.

Interfaces in heavy metal (HM) - antiferromagnetic insulator (AFI) heterostructures have recently become highly investigated and debated systems in the effort to create spintronic devices that function at terahertz frequencies. Such heterostructures have great technological potential because AFIs can generate sub-picosecond spin currents which the HMs can convert into charge signals. In this work we demonstrate an optically induced picosecond spin transfer at the interface between AFIs and Pt using time-domain THz emission spectroscopy. We select two antiferromagnets in the same family of fluoride cubic perovskites, KCoF 3 and KNiF 3 , whose magnon frequencies at the centre of the Brillouin zone differ by an order of magnitude. By studying their behaviour with temperature, we correlate changes in the spin transfer efficiency across the interface to the opening of a gap in the magnon density of states below the Néel temperature. Our observations are reproduced in a model based on the spin exchange between the localized electrons in the antiferromagnet and the free electrons in Pt. Through this comparative study of selected materials, we are able to shine light on the microscopy of spin transfer at picosecond timescales between antiferromagnets and heavy metals and identify a key figure of merit for its efficiency: the magnon gap. Our results are important for progressing in the fundamental understanding of the highly discussed physics of the HM/AFI interfaces, which is the necessary cornerstone for the designing of femtosecond antiferromagnetic spintronics devices with optimized characteristics.

The effect of symmetry on the resonance spectra of antiferromagnetically coupled oscillators has attracted new interest with the discovery of symmetry-breaking induced anti-crossings. Here, we experimentally characterise the resonance spectrum of a synthetic antiferromagnet Pt/CoFeB/Ru/CoFeB/Pt, where we are able to independently tune the effective magnetisation of the two coupled magnets. To model our results we apply the mathematical methods of group theory to the solutions of the Landau Lifshitz Gilbert equation. This general approach, usually applied to quantum mechanical systems, allows us to identify the main features of the resonance spectrum in terms of symmetry breaking and to make a direct comparison with crystal antiferromagnets.

Synthetic antiferromagnetic particles with perpendicular magnetic anisotropy offer a highly desirable platform for use in fluidic applications. This work illustrates their high level of switching field tunability and demonstrates the ability to use particle design to overcome unfavorable hysteretic changes during patterning to manufacture functional, low switching field nanodisks. This makes them ideal candidates for lab-on-chip technologies such as microfluidic sorting or detection devices.

We performed temperature-dependent optical pump - THz emission measurements in Y3Fe5O12 (YIG)|Pt from 5 K to room temperature in the presence of an externally applied magnetic field. We study the temperature dependence of the spin Seebeck effect and observe a continuous increase as temperature is decreased, opposite to what is observed in electrical measurements where the spin Seebeck effect is suppressed as 0K is approached. By quantitatively analysing the different contributions we isolate the temperature dependence of the spin-mixing conductance and observe features that are correlated to the bands of magnon spectrum in YIG.

All-optical helicity-dependent switching in ferromagnetic layers has revealed an unprecedented route to manipulate magnetic configurations by circularly polarized femtosecond laser pulses. In this work, rare-earth free synthetic ferrimagnetic heterostructures made from two antiferromagnetically exchange coupled ferromagnetic layers are studied. Experimental results, supported by numerical simulations, show that the designed structures enable all-optical switching which is controlled, not only by light helicity, but also by the relative Curie temperature of each ferromagnetic layer. Indeed, through the antiferromagnetic exchange coupling, the layer with the larger Curie temperature determines the final orientation of the other layer and so the synthetic ferrimagnet. For similar Curie temperatures, helicity-independent back switching is observed and the final magnetic configuration is solely determined by the initial magnetic state. This demonstration of electrically-detected, optical control of engineered rare-earth free heterostructures opens a novel route toward practical opto-spintronics.

The magnetic interfacial Dzyaloshinskii-Moriya interaction (DMI) in multilayered thin films can lead to chiral spin states, which are of paramount importance for future spintronic technologies1,2. Interfacial DMI typically manifests as an intralayer interaction, mediated via a paramagnetic heavy metal in systems lacking inversion symmetry3. Here we show that, by designing synthetic antiferromagnets with canted magnetization states4,5, it is also possible to observe direct evidence of the interfacial interlayer DMI at room temperature. The interlayer DMI breaks the symmetry of the magnetic reversal process via the emergence of non-collinear spin states, which results in chiral exchange-biased hysteresis loops. The spin chiral interlayer interactions reported here are expected to manifest in a range of multilayered thin-film systems, opening up as yet unexplored avenues for the development and exploitation of chiral effects in magnetic heterostructures6-8.

Magnetic interfacial Dzyaloshinskii-Moriya interaction (DMI) in multi-layered thin films can lead to exotic chiral spin states, of paramount importance for future spintronic technologies. Until now, interfacial DMI has been reported as an intralayer interaction, mediated via a paramagnetic heavy metal in systems lacking inversion symmetry. Here, we show how, by designing synthetic antiferromagnets with canted magnetization states, it is also possible to observe interface interlayer-DMI. This manifests in our structures as a room temperature in-plane biased hysteresis loop controlled by the magnetization direction of an interlayer-coupled perpendicularly magnetized layer. We further show how this interlayer chiral exchange bias can be reversed by simple external magnetic field sequences, and its magnitude tuned by the magnetic thickness of the layers. This work opens an unexplored avenue for the development of new spin chiral textures in multi-layered thin film systems.

Magnetic interfacial Dzyaloshinskii-Moriya interaction (DMI) in multi-layered thin films can lead to exotic chiral spin states, of paramount importance for future spintronic technologies. Until now, interfacial DMI has been reported as an intralayer interaction, mediated via a paramagnetic heavy metal in systems lacking inversion symmetry. Here, we show how, by designing synthetic antiferromagnets with canted magnetization states, it is also possible to observe interface interlayer-DMI. This manifests in our structures as a room temperature in-plane biased hysteresis loop controlled by the magnetization direction of an interlayer-coupled perpendicularly magnetized layer. We further show how this interlayer chiral exchange bias can be reversed by simple external magnetic field sequences, and its magnitude tuned by the magnetic thickness of the layers. This work opens an unexplored avenue for the development of new spin chiral textures in multi-layered thin film systems.

Using out-of-plane magnetized layers, a lateral shift register made from discrete elements is demonstrated. By carefully designing the in-plane shape of the elements which make up the shift register, both the position of nucleation of new domains and the coercivity of the element can be controlled. The dipole field from a neighboring element, placed tens of nanometers away, creates a bias field on the nucleation site, which can be used to create a NOT gate. By chaining these NOT gates together, a shift register can be created where data bits consisting of neighboring layers with aligned magnetization are propagated synchronously under a symmetric applied magnetic field. The operation of a 16 element shift register is shown, including field coupled data injection.

We demonstrate the effectiveness of out-of-plane magnetized magnetic microdiscs for cancer treatment through mechanical cell disruption under an applied rotating magnetic field. The magnetic particles are synthetic antiferromagnets formed from a repeated motif of ultrathin CoFeB/Pt layers. In - vitro studies on glioma cells are used to compare the efficiency of the CoFeB/Pt microdiscs with Py vortex microdiscs. It is found that the CoFeB/Pt microdiscs are able to damage 62 ± 3% of cancer cells compared with 12 ± 2% after applying a 10 kOe rotating field for one minute. The torques applied by each type of particle are measured and are shown to match values predicted by a simple Stoner-Wohlfarth anisotropy model, giving maximum values of 20 fNm for the CoFeB/Pt and 75 fNm for the Py vortex particles. The symmetry of the anisotropy is argued to be more important than the magnitude of the torque in causing effective cell destruction in these experiments. This work shows how future magnetic particles can be successfully designed for applications requiring control of applied torques.

The Ruderman-Kittel-Kasuya-Yosida (RKKY) coupling between two magnetic layers leads to many important technological applications. Here, the interaction between changing antiferromagnetic RKKY coupling and domain structure is studied in a sample consisting of two 5 nm thick CoFeB layers separated by a wedge of Cu up to 4 nm thick. Magnetic reversal occurs via the propagation of a zigzag domain wall front along the wedge. The modification of domain patterns created in the reversal of a coupled layers in the presence of antiferromagnetic RKKY coupling and coupling gradients is demonstrated. Firstly, the coupling leads to a smaller amplitude of the zigzag wall, which is aligned perpendicular to the easy axis, followed by elongation of the walls at higher coupling strength. The antiferromagnetic RKKY coupling, while not strong enough to cause antiparallel alignment of the layers, is argued to lead to coupling between the spins in the domain walls in the two layers, lowering their energy and driving the reversal behavior of the film.

Canted magnetization is obtained in ultrathin, antiferromagnetically coupled magnetic bilayers with thicknesses around the spin reorientation transition. The canting angle is controlled by both the magnetic layer thickness and interlayer coupling strength, which are tuned independently. Hysteresis loops are obtained, where magnetization components parallel and transverse to the applied field are measured, and analyzed by comparison to micromagnetic simulations. This enables the canting angle to be extracted and the behavior of the individual layers to be distinguished. Two types of canted systems are obtained with either single-layer reversal or complex, coupled two-layer reversal, under moderate external magnetic fields. Controlling the magnetization canting and reversal behavior of ultra-thin layers is relevant for the development of magnetoresistive random-access memory and spin-torque oscillator devices.

The magnetic reversal of epitaxial Fe/Cr/Fe trilayer samples grown on GaAs is studied. In wedged samples both long and short period coupling oscillations associated with Ruderman-Kittel-Kasuya-Yosida (RKKY) coupling in Cr are seen in the easy axis saturation fields. By using vector vibrating sample magnetometry and both longitudinal and transverse magneto-optical Kerr effect magnetometry we are able to determine the exact reversal path of both the magnetic layers. Changes in the reversal behavior are seen with sub-monolayer changes of the thickness of the Cr interlayer. The two main reversal paths are described in terms of whether the reversal is dominated by bilinear RKKY coupling, which leads to an antiparallel state at remanence or by biquadratic coupling which leads to a 90 degree alignment of layers at remanence. The changing reversal behaviour is discussed with respect to the possibility of using such systems for multilayer memory applications and, in particular, the limits on the required accuracy of the sample growth.

Summary form only given. All-optical switching (AOS) has been observed in ferromagnetic (FM) layers and synthetic ferrimagnetic heterostructures [1-4]. In this work, we use anomalous Hall effect (AHE) measurements to demonstrate controlled helicity-dependent switching in synthetic ferrimagnetic heterostructures. The two FM layers are engineered to have different Curie temperatures Tc1 (fixed) and Tc2 (variable). We show that irrespective of whether Tc2 is higher or lower than Tc1, the final magnetic configuration of the heterostructure is controlled by using the laser polarization to set the magnetic state of the FM layer with the highest Tc. All samples were grown on glass substrates at room temperature by DC magnetron sputtering. Two sets of samples were prepared. The first set are single FM layers with layer composition Ta (3 nm)/Pt (4 nm)/FM1(2)/Pt capping (4 nm), where FM1 = Co (0.6 nm) is a Co layer and FM2 = CoFeB (tCoFeB)/Pt(0.4 nm)/ CoFeB (tCoFeB) (0.2 ≤ tCoFeB ≤ 0.6 nm) is a composite CoFeB layer where both CoFeB layers are ferromagnetically coupled and act as a single layer. FM1 and FM2 were used to produce the second set of synthetic ferrimagnetic samples with layer structure Ta (3 nm)/Pt (4 nm)/FM1/Pt (0.4 nm)/Ru (0.9 nm)/Pt (0.4 nm)/FM2/Pt capping (4 nm). The Ru layer provides the antiferromagnetic RKKY interlayer exchange coupling between the adjacent FM1 and FM2 layers while the Pt layers on either side of the Ru layer can tune the strength of the coupling and stabilize their perpendicular anisotropy [5]. To study the AOS, we use a Ti: sapphire fs-laser with a wavelength of 800 nm and a pulse duration of 43 fs. A quarter-wave plate is used to create a circularly polarized [right(σ+) and left-handed (σ-)] beam. We first measured the magnetic properties of the FM1 and FM2 layers using vibrating sample magnetometry (VSM). All FM samples show full remanence in perpendicular hysteresis loops at room temperature (not shown). The temperature-dependent magnetization scans (not shown) give a Curie temperature Tc1 of 524 K for FM1. For FM2, increasing tCoFeB increases its Curie temperatureTc2. At tCoFeB = 0.5 nm, Tc2 - Tc1. Hall crosses are patterned by optical lithography and ion milling. The width of the current carrying wire is - 5 um, giving a DC current density of - 6 x 109 A/m2 during the measurement. Figure 1(a) shows the resulting perpendicular Hall hysteresis loop of the synthetic ferrimagnetic sample with tCoFeB = 0.2 nm. At remanence, the stable magnetic configurations are the two antiparallel orientations of FM1 and FM2 [State I and II in Fig. 1(a)]. To study the AOS, we swept the laser beam with a power of 0.45 mW and a speed of 1 μm/sec across the Hall cross, and the corresponding Hall voltage was constantly monitored. In Fig. 1(b), we show the normalized Hall voltage, VHall, as a function of the laser beam position x for both beam polarizations σ+ and σ-. The initial magnetic configuration was State I. When the beam is at the center of the cross (position B), both beam polarizations give VHall - 0. As the beam leaves the cross (position C), the σbeam changes the magnetic configurations from State I to State II (FM1 magnetization pointing down), while the system reverts to State I using the σ+ beam. Changing the initial configuration from State I to State II results in the same final magnetic configurations, determined by the laser beam polarizations (not shown). Similar results (not shown) were obtained for samples with tCoFeB ≤ 0.4 nm. However, at tCoFeB = 0.6 nm, the σbeam results in the final magnetic configurations with FM2 magnetization pointing down (State I) and the σ+ beam results in the State II configuration, suggesting that the final state is determined by the beam polarization acting on the layer with the highest Tc. Figure 2(a) shows the perpendicular Hall hysteresis loops of the synthetic ferrimagnetic sample with tCoFeB = 0.5 nm (Tc of both FM layers are identical). Similar to the sample with tCoFeB = 0.2 nm, the two antiparallel states are stable at remanence. We performed laser sweeping measurement with State I as the initial magnetic state. In Fig. 2(b), we show the corresponding variation of VHall as a function of x. Similarly, VHall - 0 when the beam is at the center of the cross (position B). However, as the laser beam leaves the cross (position C), both polarizations σ+ and σresult in reverting to the initial magnetic state I. Changing the initial state to State II (not shown) results in reverting to State II after the beam sweep. The final state is independent of the beam polarization and solely determined by the initial state. These results clarify the all-optical switching behaviours in synthetic ferrimagnetic heterostructures, providing a pathway toward opto-spintronics devices made of complex magnetic multilayers and capable of all-optical control of magnetic configurations.

Magnetic kink solitons are used as a probe to experimentally measure the layer-by-layer coercivity and interlayer coupling strength of an antiferromagnetically coupled perpendicularly magnetized Co multilayer. The magnetic response is well described by a nearest neighbor Ising macrospin model. By controlling the position of one, two or three solitons in the stack using globally applied magnetic fields, we successfully probe the switching of individual buried layers under different neighboring configurations, allowing us to access individual layer's characteristic parameters. We found the coercivity to increase dramatically up the multilayer, while the interlayer coupling strength decreased slightly. We corroborate these findings with scanning transmission electron microscopy images where a degrading quality of the multilayer is observed. This method provides a very powerful tool to characterize the quality of individual layers in complex multilayers, without the need for depth-sensitive magnetic characterization equipment.

Magnetic solitons in antiferromagnetic superlattices can be used for vertical data transfer of information. In this chapter, we introduce this concept and summarise recent results of our group where controlled soliton nucleation and propagation was achieved.

Magnetic particles that can be precisely controlled under a magnetic field and transduce energy from the applied field open the way for innovative cancer treatment. Although these particles represent an area of active development for drug delivery and magnetic hyperthermia, the in vivo anti-tumor effect under a low-frequency magnetic field using magnetic particles has not yet been demonstrated. To-date, induced cancer cell death via the oscillation of nanoparticles under a low-frequency magnetic field has only been observed in vitro. In this report, we demonstrate the successful use of spin-vortex, disk-shaped permalloy magnetic particles in a low-frequency, rotating magnetic field for the in vitro and in vivo destruction of glioma cells. The internalized nanomagnets align themselves to the plane of the rotating magnetic field, creating a strong mechanical force which damages the cancer cell structure inducing programmed cell death. In vivo, the magnetic field treatment successfully reduces brain tumor size and increases the survival rate of mice bearing intracranial glioma xenografts, without adverse side effects. This study demonstrates a novel approach of controlling magnetic particles for treating malignant glioma that should be applicable to treat a wide range of cancers.

Raw VSM data used to generate the figures of the paper entitled" Systematic layer-by-layer characterization of multilayers for three-dimensional data storage and logic", as well as the figures in the supplementary material file. The data is presented in 2 columns, column 1 is the applied field in Oe, column 2 is the magnetization (reduced units). For Figure S1, the third column is the derivative of col 2 with respect to the applied field (col 1).

Magnetic solitons in multilayered synthetic antiferromagnets (SAFs) have been recently proposed as data carriers for vertical data transfer, constituting a promising approach for 3D spintronic systems. Here, the nucleation and propagation of solitons in CoFeB/Ru SAFs are investigated under external magnetic fields by magnetooptical Kerr effect (MOKE), magnetoresistance (MR), and polarized neutron reflectivity (PNR) measurements. By comparing MOKE and MR measurements with macrospin simulations, the key steps of the mechanism behind soliton nucleation, triggered by the surface spin-flop transition and involving the switching of several layers, are determined. PNR confirms this scenario, and proves the correct propagation of solitons, with their expulsion leading to data inversion (NOT gate functionality). Additionally, the structure of solitons after nucleation is determined, finding them to be achiral under external magnetic fields.