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1Design of Inclusion-Compounds - Systematic Structural Modification of the Hexa-Host Molecule Hexakis(Benzylthiomethyl)Benzene

ADU HARDY,DD MACNICOL,S SWANSON,DR WILSON

AbstractDie Tendenz zur Bildung von Einschlußverbindungen (EB) wird für die Hexa‐(mercaptomethyl)‐benzol‐Derivate (Ia) (Darstellung früher beschrieben), (Ib) und (Ic) untersucht.

1980JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2（1980）引用：28

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2Crystal and Molecular Structure of a Novel Hexa-Host Inclusion Compound with Squalene As Guest

A FREER,CJ GILMORE,DD MACNICOL,DR WILSON

An X-ray study of the adduct formed by hexakis (p-t-butylphenylthiomethyl)benzene (I) with squalene (II) establishes the first example of channel-type inclusion behaviour for a hexahost molecule, the guest triterpene (II) being observed in a novel conformation controlled by host-guest interactions.

1980Tetrahedron Letters（1980）引用：12

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3ChemInform Abstract: HEXAKIS(BENZYLTHIOMETHYL)BENZENE: STRUCTURE OF THE 1,4‐DIOXANE CLATHRATE AND PROPERTIES OF RELATED HOSTS

A. D. U. HARDY,D. D. MACNICOL,S. SWANSON,D. R. WILSON

AbstractZu Untersuchungen über Einschlußverbindungen mit Dioxan werden aus Hexakis‐(brommethyl)‐benzol (I) die Substitutionsprodukte (II) hergestellt und diese in die entsprechenden Clathrate übergeführt.

1979Chemischer Informationsdienst

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4ChemInform Abstract: A NEW APPROACH FOR THE DESIGN OF INCLUSION COMPOUNDS

A. D. U. HARDY,D. D. MACNICOL,D. R. WILSON

AbstractAls Analoga zu den Hexameren von Phenol, Chinol u.a. hyd.roxyaromatischen Verbindungen, die zur Bildung von Einschlußverbindungen befähigt sind, wurden die hexasubstituierten Benzole (I) und (II) dargestellt (die Darstellungsvorschriften werden mitgeteilt; der zentrale Kohlenstoff‐Sechsring entspricht der aus den 6 O‐Atomen über H‐Brücken gebildeten Einheit der hexameren Clathratbildner).

1979Chemischer Informationsdienst

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5Hexakis(benzylthiomethyl)benzene: Structure of the 1,4-Dioxan Clathrate and Properties of Related Hosts

ADU HARDY,DD MACNICOL,S SWANSON,DR WILSON

The synthesis of the first chiral hexa-host molecule (III) is described: an X-ray analysis of the acetic acid adduct of (III) allows the first direct observation of dimeric acetic acid.

1978Tetrahedron Letters（1978）引用：6

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6Clathrates and molecular inclusion phenomena

D. D. MacNicol,J. J. McKendrick,D. R. Wilson

1978CHEMICAL SOCIETY REVIEWS（1978）引用：228

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7X-Ray Crystal Structure of the Novel Bis-Quaternary Dispiro System Obtained from the Reaction of Morpholine with Hexakis(bromomethyl)benzene

ADU HARDY,DD MACNICOL,DR WILSON

In contrast to the six-fold substitution of hexakis(bromomethyl)benzene (Ia) by aniline to give the hexa-amine (Ib), reaction of (Ia) with morpholine occurs with dispiro-annelation yielding (II); the structure of this novel product was deduced spectroscopically and its detailed molecular geometry was determined by X-ray crystallography.

1977JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS（1977）引用：7

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8Synthesis and Properties of the Inclusion Compound 2-Phenyl-3-p-(2,2,4-trimethylchroman-4-yl)phenylquinazolin-4(3h)-one; Use of Quartets in the Crystal Structure Determination of the Methylcyclohexane Clathrate

CJ GILMORE,ADU HARDY,DD MACNICOL,DR WILSON

AbstractDie Umsetzung der Dianin′‐ schen‐Verbindung (I) mit dem Chinazolin (II) in einer Suspension von NaH in Bis ‐ (2‐methoxy‐äthyl)äther ergibt das Addukt (III), das nach 51/2 ‐stündigem Erhitzen in die Titelverbindung (IVa) übergeht.

1977Chemischer Informationsdienst（1977）引用：10

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9Crystal Structure of a Clathrate Formed by a Mercapto-Analogue of Dianin's Compound

ADU HARDY,DD MACNICOL,JJ MCKENDRICK,DR WILSON

An X-ray diffraction analysis of the CCl4 clathrate of the mercapto-host (II) is described; a key feature of the host structure is the linking of the SH groups of six molecules of (II) by SH ⋯ S hydrogen bonds, such that the sulphur atoms form a near-planar hexagon.

1977JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS（1977）引用：10

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10Crystal and Molecular Structure of a ‘Hexa-Host’ Inclusion Compound

DD MACNICOL,ADU HARDY,DR WILSON

WE recently suggested1, and found experimental support for1,2, a totally new concept for the design of inclusion compounds. Using this design concept we prepared a series of host compounds based on a hexa-substituted benzene ring (I), and we now report the results of the first X-ray structural study on one of these compounds.

1977Nature（1977）引用：63

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11ChemInform Abstract: GUEST SELECTIVITY PROPERTIES OF THE HEXA‐HOST INCLUSION COMPOUNDS

DD MACNICOL,DR WILSON

AbstractDie hexasubstituierten Benzole (I) bilden Einschluß‐additionsverbindungen mit Xylolen, wobei aus 0‐, p‐ und o‐, m‐Xylol‐Gemischen bevorzugt nur ein Isomeres mit dem hexasubstituierten Benzol kristallisiert.

1977CHEMISTRY & INDUSTRY（1977）

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12ChemInform Abstract: SYNTHESIS AND PROPERTIES OF THE INCLUSION COMPOUND 2‐PHENYL‐3‐P‐(2,2,4‐TRIMETHYLCHROMAN‐4‐YL)PHENYLQUINAZOLIN‐4(3H)‐ONE, USE OF QUARTETS IN THE CRYSTAL STRUCTURE DETERMINATION OF THE METHYLCYCLOHEXANE CLATHRATE

C. J. GILMORE,A. D. U. HARDY,D. D. MACNICOL,D. R. WILSON

1977Chemischer Informationsdienst

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13New Strategy for the Design of Inclusion Compounds:Discovery of the ‘Hexa-Hosts’

DD MACNICOL,DR WILSON

D. D. MacNicol and D. R. Wilson, J. Chem. Soc., Chem. Commun., 1976, 494 DOI: 10.1039/C39760000494

1976JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS（1976）引用：70

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14Discovery of a New Inclusion Compound: 3-P-(2,2,4-trimethylchroman-4-yl)-phenyl-2-phenyl-4(3h)-quinazolinone

ADU HARDY,DD MACNICOL,DR WILSON

Chemischer InformationsdienstVolume 5, Issue 52 Heterocyclic Compounds ChemInform Abstract: DISCOVERY OF A NEW INCLUSION COMPOUND, 3-P-(2,2,4-TRIMETHYLCHROMAN-4-YL)-PHENYL-2-PHENYL-4(3H)-QUINAZOLINONE A. D. U. HARDY, A. D. U. HARDYSearch for more papers by this authorD. D. MACNICOL, D. D. MACNICOLSearch for more papers by this authorD. R. WILSON, D. R. WILSONSearch for more papers by this author A. D. U. HARDY, A. D. U. HARDYSearch for more papers by this authorD. D. MACNICOL, D. D. MACNICOLSearch for more papers by this authorD. R. WILSON, D. R. WILSONSearch for more papers by this author First published: December 31, 1974 https://doi.org/10.1002/chin.197452305Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume5, Issue52December 31, 1974 RelatedInformation

1974JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS（1974）引用：4

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