The single crystals of lead-free Na0.5Bi0.5TiO3 were grown using the Czochralski method. The energy gaps determined from X-ray photoelectron spectroscopy (XPS) and optical measurements were approximately 2.92 eV. The current-voltage characteristics, depolarization current, dc (σdc) and ac (σac) electrical conductivity, and Seebeck coefficient of the crystals were investigated. The frequency/temperature-dependent electrical properties were also measured and analyzed through complex impedance spectroscopy. An overlapping reversible insulator-metal transition (resistive switching) on nanoscales, caused by the electric field, was detected. Most of these properties were measured for the first time. The activation energy values determined from the conductivity data, the imaginary part of the electric impedance and the modulus indicate that the relaxation process in the high-temperature range is attributable to both single and double ionized oxygen vacancies, in combination with the hopping of electrons between Ti4+ and Ti3+. P-type electrical conductivity was also found. These discoveries create new possibilities of reducing the electrical conductivity of NBT and improving the process of effectively poling this material. Our results indicate the possibility of tuning the material properties by intentionally creating non-stoichiometry/structural defects (oxygen vacancies, cation excess and cation deficiency).

High-quality and large-size single crystals of lead-free Na0.5Bi0.5TiO3 were grown using the Czo-chralski technique. The crystals had pure perovskite structure with rhombohedral symmetry and were translucent in the visible and near infrared spectral ranges recorded in the interval 350-1050 nm. The energy gaps determined from the X-ray photoelectron spectroscopy (XPS) and optical measurements were approximately 2.92 eV. The current-voltage characteristics, depolarization current, dc (σdc) and ac (σac) electrical conductivity, and Seebeck coefficient of the crystals were investigated. The frequency/temperature-dependent electrical properties were also measured and analyzed through complex impedance spectroscopy. An overlapping reversible insulator-metal transition (resistive switching) on nanoscales, caused by the electric field, was detected. This was the first time that most of these investigations were performed for this material. The following conductivity mechanisms of NBT single crystals were identified: (i) quasi-free electron and hole conduction and hopping-charges mechanism at low temperatures, (ii) small polaron conductivity in the middle temperature range, and (iii) a significant contribution of the oxygen vacancies to conductivity in the high temperature range. The activation energy values determined from the conductivity data, the imaginary part of the electric impedance and the modulus indicate that the relaxation process in the high-temperature range is attributable to both single and double ionized oxygen vacancies, in combination with the hopping of electrons between Ti4+ and Ti3+. P-type electrical conductivity was also found. These discoveries create new possibilities of reducing the electrical conductivity of NBT and improving the process of effectively poling this material. The density of the electronic states was investigated using an ab initio method. The energy gap cal-culated for NBT (R3c) was 2.8 eV, and is well comparable to those determined from XPS and optical measurements. Our results indicate the possibility of tuning material properties by inten-tionally creating non-stoichiometry/structural defects (oxygen vacancies, cation excess and cation deficiency).

Lead-free Ba1−xSrxTiO3 (BST) (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.45) ceramics were successfully prepared via the solid-state reaction route. A pure perovskite crystalline structure was identified for all compositions by X-ray diffraction analysis. The basic phase transition temperatures in these ceramics were studied over a wide temperature range. A change in symmetry from a tetragonal to cubic phase was detected, which was further proven by phonon anomalies in composition/temperature-dependent Raman spectra. The incorporation of Sr2+ into BaTiO3 (BT) lead to a shift in the phase transitions to lower temperatures, suppressing the ferroelectric properties and inducing relaxor-like behavior. Therefore, it was reasonable to suppose that the materials progressively lack long-range ordering. The initial second-harmonic generation (SHG) measurements demonstrated that the cubic phase of BST ceramics is not purely centrosymmetric over a wide temperature interval. We discussed the possible origin of the observed effects, and showed that electric field poling seems to reconstruct the structural ordering destroyed by the introduction of Sr2+ to BT. In the first approximation, substitution of Sr for larger Ba simply reduced the space for the off-central shift in Ti in the lattice and hence the domain polarization. A-site cation ordering in BST and its influence on the density of electronic states were also explored. The effect of doping with strontium ions in the BST compound on the density of electronic states was investigated using ab initio methods. As the calculations showed, doping BT with Sr2+ atoms led to an increase in the bandgap. The proposed calculations will also be used in the subsequent search for materials optimal for applications in photovoltaics.

Flaring episodes in blazars represent one of the most violent processes observed in extra-galactic objects. Studies of such events shed light on the energetics of the physical processes occurring in the innermost regions of blazars, which cannot otherwise be resolved by any current instruments. In this work, we present some of the largest and most rapid flares captured in the optical band in the blazars 3C 279, OJ 49, S4 0954+658, TXS 1156+295 and PG 1553+113. The source flux was observed to increase by nearly ten times within a timescale of a few weeks. We applied several methods of time series analysis and symmetry analysis. Moreover, we also performed searches for periodicity in the light curves of 3C 279, OJ 49 and PG 1553+113 using the Lomb-Scargle method and found plausible indications of quasi-periodic oscillations (QPOs). In particular, the 33- and 22-day periods found in 3C 279, i.e. a 3:2 ratio, are intriguing. These violent events might originate from magnetohydrodynamical instabilities near the base of the jets, triggered by processes modulated by the magnetic field of the accretion disc. We present a qualitative treatment as the possible explanation for the observed large amplitude flux changes in both the source-intrinsic and source-extrinsic scenarios.

Intense outbursts in blazars are among the most extreme phenomena seen in extragalactic objects. Studying these events can offer important information about the energetic physical processes taking place within the innermost regions of blazars, which are beyond the resolution of current instruments. This work presents some of the largest and most rapid flares detected in the optical band from the sources 3C 279, OJ 49, S4 0954+658, Ton 599, and PG 1553+113, which are mostly TeV blazars. The source flux increased by nearly ten times within a few weeks, indicating the violent nature of these events. Such energetic events might originate from magnetohydrodynamical instabilities near the base of the jets, triggered by processes modulated by the magnetic field of the accretion disc. We explain the emergence of flares owing to the injection of high-energy particles by the shock wave passing along the relativistic jets. Alternatively, the flares may have also arisen due to geometrical effects related to the jets. We discuss both source-intrinsic and source-extrinsic scenarios as possible explanations for the observed large amplitude flux changes.

The first Global e-Competition on Astronomy and Astrophysics was held online in September-October 2020 as a replacement for the International Olympiad on Astronomy and Astrophysics, which was postponed due to the COVID-19 pandemic. Despite the short time available for organisation, 8 weeks, the competition was run successfully, with 325 students from over 42 countries participating with no major issues. The feedback from the participants was positive and reflects the ways in which such events can boost interest in astronomy and astronomy education. With online activities set to become more prevalent in the future, we present an overview of the competition process, the challenges faced, and some of the lessons learned, aiming to contribute to the development of best practices for organizing online competitions.

The behavior of Ba1-xSrxTiO3 ceramics (x = 0, 0.3, 0.4 and 0.45) in both unpoled and poled states was studied using XRD, SEM, DSC and dielectric methods. The ceramics exhibit pure perovskite structure with tetragonal symmetry for x = 0, 0.3 and 0.4 and pseudocubic for x = 0.45. It was found that the substitution of SrTiO3 to BaTiO3 significantly influences the properties under investigation, leading to a shift of phase transitions and weakness of the dielectric and ferroelectric properties. This suggests that the effects are mainly due to the differences in ionic size between dopant and host ions and to the more covalent nature of the A-O bond following Sr2+ addition and that the former effect is predominant. It was shown that prior electric field poling decreases the disorder introduced by Sr modification through reinforced domains/polar regions ordering.

The phase transitions of unpoled and poled Na0.5Bi0.5TiO3 (NBT) single crystals were studied using structural, hysteresis loops, polarizing-microscope, dielectric, mechanical (the first measurement), thermal expansion strain and calorimetric measurements. It was found that phase transitions in NBT are first-order and clearly demonstrate ferroelastic aspects. Both rhombohedral-tetragonal and tetragonal-cubic transformations are accompanied by a softening of mechanical properties like in improper ferroelastic transitions. It was concluded that the difference in the internal friction between unpoled/poled states and between [001]c/[111]c poled states can be associated with a difference in the density of mobile ferroelastic twin walls in these states.

Ba1-xSrxTiO3 (BST) (x = 0, 0.1 and 0.2) ceramics were prepared by the solid-state reaction method and their structural, thermal and dielectric behavior was studied. The increasing concentration of Sr2+ ions leads to shift of Tc toward lower temperature. The results obtained are discussed in terms of microstructural/structural effects of Sr2+ incorporation into BaTiO3. It is shown that E-poling influences the properties under investigation. This includes modification of local structure, dielectric response and temperature of phase transformations. This could be the result of improvement by the electric field of the polarization ordering, previously disordered by the introduction of Sr2+ to BaTiO3.

Context. Recent results for asteroid rotation periods from the TESS mission showed how strongly previous studies have underestimated the number of slow rotators, revealing the importance of studying those targets. For most slowly rotating asteroids (those with P > 12 h), no spin and shape model is available because of observation selection effects. This hampers determination of their thermal parameters and accurate sizes. Also, it is still unclear whether signatures of different surface material properties can be seen in thermal inertia determined from mid-infrared thermal flux fitting. Aims. We continue our campaign in minimising selection effects among main belt asteroids. Our targets are slow rotators with low light-curve amplitudes. Our goal is to provide their scaled spin and shape models together with thermal inertia, albedo, and surface roughness to complete the statistics. Methods. Rich multi-apparition datasets of dense light curves are supplemented with data from Kepler and TESS spacecrafts. In addition to data in the visible range, we also use thermal data from infrared space observatories (mainly IRAS, Akari and WISE) in a combined optimisation process using the Convex Inversion Thermophysical Model. This novel method has so far been applied to only a few targets, and therefore in this work we further validate the method itself. Results. We present the models of 16 slow rotators, including two updated models. All provide good fits to both thermal and visible data.The obtained sizes are on average accurate at the 5% precision level, with diameters found to be in the range from 25 to 145 km. The rotation periods of our targets range from 11 to 59 h, and the thermal inertia covers a wide range of values, from 2 to <400 J m−2 s−1∕2 K−1, not showing any correlation with the period. Conclusions. With this work we increase the sample of slow rotators with reliable spin and shape models and known thermal inertia by 40%. The thermal inertia values of our sample do not display a previously suggested increasing trend with rotation period, which mightbe due to their small skin depth.

This paper presents the results of a combined spectroscopic and photometric study of 20 contact binary systems: HV Aqr, OO Aql, FI Boo, TX Cnc, OT Cnc, EE Cet, RWCom, KR Com, V401 Cyg, V345 Gem, AK Her, V502 Oph, V566 Oph, V2612 Oph, V1363 Ori, V351 Peg, V357 Peg, Y Sex, V1123 Tau and W UMa, which was conducted in the frame of the W UMa Project. Together with 51 already covered by the project and an additional 67 in the existing literature, these systems bring the total number of contact binaries with known combined spectroscopic and photometric solutions to 138. It was found that mass, radius and luminosity of the components follow certain relations along the MS and new empirical power relations are extracted. We found that 30 per cent of the systems in the current sample show extreme values in their parameters, expressed in their mass ratio or fill-out factor. This study shows that, among the contact binary systems studied, some have an extremely low mass ratio (q < 0.1) or an ultra-short orbital period (Porb < 0.25 d), which are expected to show evidence of mass transfer progress. The evolutionary status of these components is discussed with the aid of correlation diagrams and their physical and orbital parameters compared to those in the entire sample of known contact binaries. The existence of very short orbital periods confirms the very slow nature of the merging process, which seems to explain why their components still exist as MS stars in contact configurations even after several Gyr of evolution.

In this study, we independently test the presence of an exoplanet around the binary KIC 9472174, which is composed of a red dwarf and a pulsating type B subdwarf. We also present the results of our search for Jupiter-mass objects orbiting near to the eclipsing binary KIC 7975824, which is composed of a white dwarf and type B subdwarf, and the pulsating white dwarf KIC 8626021. The goal is to test analytical techniques and prepare the ground for a larger search for possible substellar survivors on tight orbits around post-common envelope binaries and stars at the end of their evolution, that is, extended horizontal branch stars and white dwarfs. We, therefore, mainly focus on substellar bodies orbiting these stars within the range of the host's former red-giant or asymptotic-giant phase envelopes. Due to the methods we use, the quest is restricted to single-pulsating type B subdwarf and white dwarf stars and short-period eclipsing binaries containing a white dwarf or a subdwarf component. Results. Based on the three objects studied in this paper, we demonstrate that these methods can be used to detect giant exoplanets orbiting around pulsating white dwarf or type B subdwarf stars as well as short-period binary systems, at distances which fall within the range of the former red-giant envelope of a single star or the common envelope of a binary. Using our analysis techniques, we reject the existence of a Jupiter-mass exoplanet around the binary KIC 9472174 at the distance and orbital period previously suggested in the literature. We also found that the eclipse timing variations observed in the binary might depend on the reduction and processing of the Kepler data. The other two objects analyzed in this work do not have Jupiter mass exoplanets orbiting within 0.7 - 1.4 AU from them, or larger-mass objects on closer orbits (the given mass limits are minimum masses).

Results of high-cadence multi-colour observations of 121 pre-main sequence stars available from the northern hemisphere are presented. The aim of this survey was to detect transit-like signatures caused by occultation of these young stars and their accretion-induced hot spots by close-in planets and/or dusty clumps. Although none planetary transits were detected, our data allow to determine rotational periods for some T Tauri stars, characterise accretion processes operating in classical T Tauri-type stars in time scales ranging from a few minutes to days, as well as the large-scale dips caused by dusty warped discs.

Astronomical Olympiads and similar competitions for high-school students have been run in some countries for more than half a century, and last year marked the tenth anniversary of the largest such competition with global reach, the International Olympiad on Astronomy and Astrophysics. The effect of these has been to reach out to a large number of school students who might not otherwise have considered astronomy as a subject; help maintain a high, guided standard of astronomy education even in countries where astronomy is not (or no longer) on the curriculum; and to encourage those students who participate to strive harder and pursue astronomy further by giving them goals to aim for, rewarding their efforts with medals, recognition and participation in the international events in interesting locations and, above all, showing them that there are many other students just like them both in their own country and around the world. Many of the students go on to careers in astronomy education or research. We believe that Astronomy Olympiads are a very valuable element in the astronomy education framework which can be used to further the common goal of sustaining and growing the astronomical community.

Crystals of PbTiO3 and 0.9PbTiO(3)-0.1(Na0.5Bi0.5)TiO3 were obtained by the flux growth method whereas crystals of (Na0.5Bi0.5)TiO3 were growth by the Czochralski method. Raman spectroscopy and polarized light microscopy were performed at room temperature. The Raman spectra of 0.9PbTiO(3)-0.1(Na0.5Bi0.5)TiO3 shown significant changes comparing to the base materials PbTiO3 and (Na0.5Bi0.5)TiO3. A domain structure was investigated by use polarized light microscopy. Dielectric permittivity measurements were carried out in the temperature range from 20 degrees C to 550 degrees C and a frequency from 1 kHz to 1 MHz. These showed higher dielectric permittivity for the crystals 0.9PbTiO(3) -0.1(Na0.5Bi0.5)TiO3 than the source materials PbTiO3 and (Na0.5Bi0.5)TiO3. The high value of dielectric constant makes it possible to applied 0.9PbTiO(3) -0.1(Na0.5Bi0.5)TiO3 as efficient dielectric medium in a capacitors. The small size of the domain structure with the easy possibility of switching by application of an external electric field, give opportunities to apply these materials to FRAM memory applications. Moreover, the high sensitivity of these materials to the surrounding gases e.g. ammonia, chlorine, hydrogen, etc., allows the construction of sensor devices.

We present results derived from a monitoring program of a sample of FR-II type radio quasars. The variabilities detected in their densely covered light curves, which have being gathered over a period of more than 9 years, are analyzed with statistical methods (LSP and WWZ). We found no statistically significant, strictly coherent periodicities in our data.