Vehicle integrated photovoltaics (VIPV) is gathering attention by researchers and industry alike to help in decarbonization of transport industry. While PV panels have been integrated to the vehicles to support auxiliary functions, their wide scale implementation is limited by their size, weight and rigidity. In this work we present a proof-of-concept method to produce bi-facial PV panels with fibre-glass reinforced composite fabric (GRCF) using vacuum resin infusion process. These modules are specifically designed for integrating with an electric car and to be used as a power source to charge the batteries. Mini modules are fabricated using two interdigitated back contact solar cells sandwiched between layers of GRCF sheets. The modules are prepared by drawing the resin under a suitable vacuum through the different GRCF layers and allowing the resin to cure at room temperature. The modules are prepared at room temperature without using a stringer or laminator. Three different metal end-strips are used to assess their performance in the finally prepared module. The modules are subjected to the damp-heat test to analyse the degradation in the modules and the suitability of the fabrication process. Results show that resistance losses and optical losses play a vital role in the final losses resulting from degradation of the modules. Finally, we have shown in this work that it is possible to fabricate such modules using low-cost technology. By fine tuning and scaling-up the process, it is possible to produce modules of any size which could further help in the rapid integration of c-Si PV modules in vehicles.
Transparent conductive aluminum-doped zinc oxide (AZO) films were investigated as potential recombination layers for perovskite/silicon tandem solar cells, comparing the results of atomic layer deposition (ALD) and magnetron sputtering (MS) on vertically aligned silicon nanowire (SiNW) scaffolds. Conformality and thickness control were examined by cross-sectional SEM/TEM and profilometry, revealing fully conformal ALD coatings with tunable thicknesses (40–120 nm) versus tip-capped, semi-uniform MS films (100–120 nm). Optical transmission measurements on glass substrates showed that both 120 nm ALD and MS layers exhibit interference maxima near 450–500 nm and 72–89% transmission across 800–1200 nm; the thinnest ALD films reached up to 86% near-IR transparency. Four-point probe analysis demonstrated that ALD reduces surface resistance from 1150 Ω/□ at 40 nm to 245 Ω/□ at 120 nm, while MS layers achieved 317 Ω/□ at 120 nm. These results delineate the balance between conformality, transparency, and conductivity, providing design guidelines for AZO recombination interfaces in next-generation tandem photovoltaics.
In this work, we present a new graphene-based sensor designed to monitor a set of photovoltaic panels on a sound-absorbing screen in terms of their potential mechanical damage. The innovative design of the photovoltaic module and consequently its sound-reflecting and sound-absorbing parameters play a vital role. The light transmittance of the sensor layer composed of graphene flakes in a cellulose matrix, confirmed by optical studies, allows its use directly over the photovoltaic cells. All the sensors are interconnected with metallic connections to reduce their internal resistance on larger surfaces. The sensor state is monitored through the resistance value as a zero-one operation/damaged response. Two sensor damage, scenarios, repetitive scratching, and cutting-out were described. The sensor measurements were performed in the potential ranging from 2.1 to 51.1 V, and the current response allowed to calculate the total resistance. The change in sensor resistance ranged between 9.3 and 24.1%, depending on the damaged area. The resistance for the scratched surface oscillated between 25 and 26 Ω, whereas the cut-out surface showed values more than 1.5 times higher. The proposed sensor based on graphene, cellulose, and ethylene–vinyl acetate allows the registration of immediate information about the destruction or theft of a power node.
The article presents the results of a SnO2 layer deposition, selected for its properties to function as either a recombination layer or an electron transporting material (ETM) layer in a potential silicon/perovskite tandem solar cell. The layer was deposited using an atomic layer deposition (ALD) method to ensure uniform coverage on the rough surface of etched silicon nanowires. The deposition process was monitored using test samples on glass by assessing surface roughness with an atomic force microscopy method and a total transmission through UV-VIS spectroscopy. The test layers were further characterised to estimate thickness using ellipsometry. The target layers, deposited on the porous surface of etched silicon nanowires, were examined using high-resolution scanning electron microscopy and transmission electron microscopy to evaluate the material microstructure, layer adhesion to the substrate, and the accuracy of ALD deposition on highly porous structures.
Silicon nanowires (SiNWs) fabricated by Ag-assisted metal-assisted chemical etching (MACE) exhibit excellent light-trapping performance, yet their fragile high-aspect-ratio morphology severely limits reliable metallization in photovoltaic devices. Conventional electrode deposition methods often fail on dense SiNW arrays due to poor mechanical stability of the nanowire tips, leading to delamination, inhomogeneous coverage, and high contact resistance. In this work, we introduce a maskless laser-based truncation technique that selectively shortens MACE-derived SiNWs to controlled residual heights of 300–500 nm exclusively within the regions intended for electrode formation, while preserving the full nanowire morphology in active areas. A detailed parametric study of laser power, scanning speed, and pulse repetition frequency allowed the identification of an optimal processing window enabling controlled tip melting without damaging the nanowire roots or the crystalline silicon substrate. High-resolution SEM imaging confirms uniform planarization, well-preserved structural integrity, and the absence of subsurface defects in the laser-processed tracks. Optical reflectance measurements further demonstrate that introducing 2% and 5% truncated surface fractions—corresponding to the minimum and maximum metallized front-grid coverage in industrial Si solar cells—results in only a minimal reflectance increase, preserving the advantageous the light-trapping behavior of the SiNW texture. The proposed laser truncation approach provides a clean, scalable, and industrially compatible route toward creating electrode-ready surfaces on nanostructured silicon, enabling reliable metallization while maintaining optical performance. This method offers strong potential for integration into silicon photovoltaics, photodetectors, and nanoscale electronic and sensing devices.
This article introduces a zinc metal layer structure integrated into a standard photovoltaic (PV) module, potentially serving a double purpose: as a light reflecting and re-directing diffuser, increasing the PV module overall efficiency, offering anodic protection of Ag/Sn interface against corrosion within the PV module structure. The ethylene-vinyl acetate (EVA) cross-linking degree and peel force measurements were carried out to check the quality of the encapsulation process for the modified modules. Finally, the electrical series resistance of PV modules was measured showing that the modified PV module almost maintained its initial series resistance after exposure to damp-heat conditions of 85 degrees C, 85% relative humidity for 1000 h, while the unmodified PV module increased its resistance by 5% under the same conditions.
This article introduces a laboratory-scale concept and research on photovoltaic (PV) modules designed for building integrated photovoltaics (BIPV) market, with enhanced architectural aesthetics and no protective glass. The proposed concept involves replacing a typical glass protective and load-bearing element of PV modules with an ethylene tetrafluoroethylene (ETFE) foil while using an aluminium sheet as a load-bearing element in the system. To further enhance the visual appeal of the solution, special modifications were proposed to the geometry of the front security foil. To confirm the feasibility of the proposed concept for mass production, critical tests were conducted on the material system and the process of modifying the surface of the ETFE foil. These tests included evaluating adhesion strength between layers, optical transmission coefficients, and electrical parameters of the developed PV modules. Additionally, the effect of the ETFE film modification on the formation of micro-cracks in solar cells was also investigated.
Zinc oxide layers on soda-lime glass substrates were fabricated using the sol-gel method and the dip-coating technique. Zinc acetate dihydrate was applied as the precursor, while diethanolamine as the stabilizing agent. This study aimed to determine what effect has the duration of the sol aging process on the properties of fabricated ZnO films. Investigations were carried out with the sol that was aged during the period from 2 to 64 days. The sol was studied using the dynamic light scattering method to determine its distribution of molecule size. The properties of ZnO layers were studied using the following methods: scanning electron microscopy, atomic force microscopy, transmission and reflection spectroscopy in the UV-Vis range, and the goniometric method for determination of the water contact angle. Furthermore, photocatalytic properties of ZnO layers were studied by the observation and quantification of the methylene blue dye degradation in an aqueous solution under UV illumination. Our studies showed that ZnO layers have grain structure, and their physical–chemical properties depend on the duration of aging. The strongest photocatalytic activity was observed for layers produced from the sol that was aged over 30 days. These layers have also the greatest porosity (37.1%) and the largest water contact angle (68.53°). Our studies have also shown that there are two absorption bands in studied ZnO layers, and values of optical energy band gaps determined from positions of maxima in reflectance characteristics are equal to those determined using the Tauc method. Optical energy band gaps of the ZnO layer fabricated from the sol aged over 30 days are EgI = 4.485 eV and EgII = 3.300 eV for the first and second bands, respectively. This layer also showed the highest photocatalytic activity, causing the pollution to degrade 79.5% after 120 min of UV irradiation. We believe that ZnO layers presented here, thanks to their attractive photocatalytic properties, may find application in environmental protection for the degradation of organic pollutants.
This paper presents research on the deposition of an indium tin oxide (ITO) layer which may act as a recombination layer in a silicon/perovskite tandem solar cell.ITO was deposited by magnetron sputtering on a highly porous surface of silicon etched by the metal-assisted etching method (MAE) for texturing as nano and microwires.The homogeneity of the ITO layer and the degree of coverage of the silicon wires were assessed using electron microscopy imaging techniques.The quality of the deposited layer was specified, and problems related to both the presence of a porous substrate and the deposition method were determined.The presence of a characteristic structure of the deposited ITO layer resembling a "match" in shape was demonstrated.Due to the specificity of the porous layer of silicon wires, the ITO layer should not exceed 80 nm.Additionally, to avoid differences in ITO thickness at the top and base of the silicon wire, the layer should be no thicker than 40 nm for the given deposition parameters.
Commercially available photovoltaic (PV) modules typically consist of individual silicon half-cut cells that are electrically interconnected. This interconnection method results in gaps between the cells, which do not contribute to the overall PV output power. One approach to enhance the cell-to-module power ratio is the placement of white, diffuse reflecting plastic material within these gaps. Conventionally, the process of generating reflective patterns involves several discrete steps, including film deposition, resist patterning, etching, and resist stripping. This study presents an innovative single-step procedure for the direct deposition of zinc reflective patterns onto glass substrates using laser-induced backward transfer (LIBT) and a nanosecond pulsed laser system. The process successfully produced lines and squares, demonstrating its versatility in achieving diverse geometric patterns under ambient atmospheric pressure and room temperature conditions. The evaluation of the transferred patterns included an examination of geometric dimensions and surface morphology using a 3D microscope and scanning electron microscopy (SEM) analysis at the air/Zn interface. Additionally, the thickness of the zinc film and its adhesion to the glass substrate were quantified. The angular reflectance at a wavelength of 660 nm for both the glass/Zn and air/Zn interfaces was measured.
The solar module output power is the power generated by all individual cells in their specific electrical circuit configuration, multiplied by the cell-to-module power ratio. The cell-to-module power ratio thus reflects the sum of the losses and gains produced by the structure of the module. The biggest process change in module design during the last few years was the introduction of half cells. Another important trend is the use of bifacial cells to build bifacial modules. These two trends increase parts of the module that correspond to the intercell gaps, and the light does not meet the cell in its path. This part of the radiation is therefore not used efficiently. Scientific efforts focus on the texturing surface of covering glass and cells, and the introduction of narrower ribbons and encapsulation materials with improved UV performance, etc. The concept of a diffusor that actively redirects light from the intercell space into the cell was proposed in the past, in the form of a micro-structured prismatic film, but this is not applicable for bifacial modules. The conclusion is that losses caused by the incidence of light on the areas of the photovoltaic panel not covered with solar cells yet are to be explored further. A sawtooth-shaped reflecting diffusor placed between cells is proposed. This article addresses the issue in a novel way, primarily because the theoretical range of the optimum sawtooth profile is defined. In the experimental part of the study, the possibility of producing such a profile directly on glass using a CO2 laser is demonstrated. The theoretical model enables discrimination between advantageous and disadvantageous sawtooth profiles. As a proof of concept, minimodules based on the optimum parameters were built and tested for their electrical performance. The result confirms that the proposed sawtooth-shaped reflecting diffusor placed between cells creates cell-to-module power gain. The proposed laser technology can be incorporated into existing production lines, and can increase the output of any photovoltaic technology, including and beyond silicon.
This work aims at assessment of TiO2 as the main layer component for self-cleaning layers in photovoltaic panels. TiO2 (derived from titanium (IV) butoxide or titanium (IV) isopropoxide) without and with silver was examined to find titania suitable microstructure and optical properties. For this purpose silver amounts ranging from 0.1 to 1% were used for 3 separate chemical methods of modification. Microstructure of powders was characterized by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) with X-ray energy dispersion spectroscopy. Three techniques: spin-coating, doctor blade, and spray-coating were used to deposit TiO2 and TiO2–Ag layers on glass and silicon solar cells. The photocatalytic activity of TiO2 and TiO2–Ag were investigated in the presence of methylene blue. Concentration of dye, amount of silver, type of TiO2 with Ag modification and stability over time were analysed towards the best photocatalytic properties. Finally, TiO2 layers which were used to coat a new type of photovoltaic modules had marginal influence on photovoltaic parameters.
Cuprorivaite, also known as Egyptian blue (EB), CaCuSi4O10, has been utilized as an important blue pigment for thousands of years. It shows a 430–800 nm broad excitation band and an intense 910–920 nm near-infrared (NIR) emission peak at room temperature. The application that motivates the current research is for luminescent solar concentrator (LSC) usage. Current technology for this purpose relies on high near-infrared reflectance. This article addresses the investigation of the relationship between dispersing methods and photoluminescence (PL) intensity. Mechanical grinding methods investigated in the study were: horizontal bead mill, exfoliation and three-roll mill. The initial aim of the study was to verify if the proposed methods do not damage PL. To the surprise of the authors, three-roll mill treatment enhanced PL by nearly 50% without altering the morphology of the powder. An X-ray diffraction study suggested slight alterations in the crystal lattice.
The aim of the paper was to determine the morphology of the layers and the microstructure of the transition zone present in the proposed tandem solar structure. The bottom-silicon solar cell plays a double role: first as a highly porous non-reflecting material, and second as a scaffold for top-perovskite cell. In the presented solution, the use of a porous layer made of (e.g., TiO2) is excluded in favor of chemically etched wires on the silicon surface. The porous layer of silicon consists of nano- and microwires etched with metal assisted etching (MAE). The perovskite layer is introduced by a two-step chemical method into the spaces between the wires to fully fill them and intentionally form an additional capping layer at the same time. To examine the structure made in this way, advanced microscopic methods were used including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning transmission electron microscopy (STEM), also in high resolution.
In recent years, a great importance has been given to hybrid systems of energy generators and energy storages. This article presents the results of our research aimed at checking the possibility of connecting a photovoltaic (PV) module and a lithium-ion battery (LIB), using a simplified control module towards a cheap and efficient system. The photovoltaic modules based on crystalline silicon solar cells, tempered glass as the front layer and ethylene-vinyl acetate (EVA) copolymer as encapsulation material are the most popular type in the industry. The disadvantage of such module type is the high weight of about 15 kg/m2. The weight of PV module used in the presented energy storage system is twice as small. This new type of PV module is based on treated poly(methyl methacrylate) (PMMA) as back sheet; high transparent foil as front sheet. Changing glass layer to PMMA requires additional modification of the lamination process parameters and EVA polymer type. For this reason, an EVA polymer with reduced crosslinking temperature was used in most cases; the voltage obtained from solar panels is significantly different from the one required by battery system. Hence, voltage converters (step-up or step-down) are needed. The use of a voltage stabilizing converter (which is a kind of electrical buffer) between the solar cell and lithium-ion battery can in some cases replace the battery overcharge protection system. However, an indispensable element is the system protecting the battery from excessive discharge. The voltage converter permits direct connection between the electricity storage and power supply, which current-voltage parameters do not match. The converter’s task is to change the value of current and voltage in a way that meets the requirements of the powered receiver, minimizing power losses, increasing the whole system efficiency. Photovoltaic parameters of the energy storage systems were examined in laboratory and real conditions.
Purpose The photovoltaic modules with front glass as a protective layer are the most popular type in the industry, but for some applications it can be considered as too heavy. One of the approaches is to laminate the cells using PMMA [Poly(methyl methacrylate)] as the front layer. This polymer has good mechanical strength and optical properties but exhibits low adhesion to lamination foil. To increase adhesion between these two materials, PMMA surface treatment may be required. Design/methodology/approach To examine the PMMA treatment influence on the sample, adhesion samples' surfaces were modified by grinding and laser cutting. Also two types of PMMA available in the market were tested, namely, smooth and satin types. The quality of lamination was determined using two methods, namely, tear test with recorded maximal tear force achieved for the samples, and environment chamber tests, in which the system resistance against the cyclic temperature variation was evaluated. Findings Additional treatment of the PMMA surface lead to increased adhesion of the lamination foil used. Ethylene-vinyl acetate foil in the PMMA system is sensitive to temperature variation, which can lead to system delamination, whereas polyvinyl butyral foil exhibits better environmental performance and even its adhesion to PMMA is lower. Originality/value This paper presents atypical surface modification methods that contributed to higher adhesion of lamination systems in glass-free solar modules. Glass front sheet and polymeric backsheet were replaced with PMMA. As the adhesion mechanism in the PMMA-lamination foil system differs from that in the traditional glass system, different PMMA surface treatments need to be evaluated.
Purpose The purpose of this paper is to investigate the behavior of interconnections between solar cells in a glass-free solar modules. As glass weight can be a limitation, it is still interesting to investigate other types of systems, especially when the glass was replaced with a polymeric front sheet. Such systems can be more sensitive for the solar cell interconnection ribbon fatigue. Design/methodology/approach To examine this effect, the set of glass-based and glass-free modules were prepared using various ribbon thickness and treatment concerning its stretching or curving before lamination. Furthermore, additional reinforcement of the connection between the ribbon and the solar cell was proposed. The prepared modules were exposed to the cyclic temperature variation in the environment chamber. The number of cycles after which the interconnection maintains its conductivity was noted. Findings Changing the outer layers into more elastic ones requires additional care for the ribbon treatment because interconnections become more sensitive for a system relative displacement. To secure interconnection before fatigue an additional curving of ribbon between solar cells can be introduced whereas the best results were obtained for a system with aluminum plate laminated as an interlayer. Originality/value The paper presents a new system of a glass-free solar module based on epoxy-glass fiber composite as a backsheet. The glass front sheet was replaced with an elastic, transparent polymer. Such construction can be used in a system where the glass weight is a limitation. As glass has a structural function in traditional modules and limits fatigues of interconnections the proposed system requires additional ribbon treatment to preserve long module life-span.
In this study a two-step short wet etching was implemented for the black silicon formation.The proposed structure consists of two steps.The first step: wet acidic etched pits-like morphology with a quite new solution of lowering the texturization temperature and second step: wires structure obtained by a metal assisted etching (MAE).The temperature of the process was chosen due to surface development control and surface defects limitation during texturing process.This allowed to maintain better minority carrier lifetime compared to etching in ambient temperature.On the top of the acidic texture the wires were formed with optimized height of 350 nm.The effective reflectance of presented black silicon structure in the wavelength range of 300-1100 nm was equal to 3.65%.