The synthesis of new chloro containing substituted cyclopropanes is described.
ChemInformVolume 20, Issue 40 Isocyclic Compounds ChemInform Abstract: Synthesis of Some New Polysubstituted Cyclopropanes. F. GAUDEMAR-BARDONE, F. GAUDEMAR-BARDONE Univ. P. a. M. Curie, Lab. Synth. Organomet., 75230 Paris, FranceSearch for more papers by this authorM. MLADENOVA, M. MLADENOVA Univ. P. a. M. Curie, Lab. Synth. Organomet., 75230 Paris, FranceSearch for more papers by this authorM. GAUDEMAR, M. GAUDEMAR Univ. P. a. M. Curie, Lab. Synth. Organomet., 75230 Paris, FranceSearch for more papers by this author F. GAUDEMAR-BARDONE, F. GAUDEMAR-BARDONE Univ. P. a. M. Curie, Lab. Synth. Organomet., 75230 Paris, FranceSearch for more papers by this authorM. MLADENOVA, M. MLADENOVA Univ. P. a. M. Curie, Lab. Synth. Organomet., 75230 Paris, FranceSearch for more papers by this authorM. GAUDEMAR, M. GAUDEMAR Univ. P. a. M. Curie, Lab. Synth. Organomet., 75230 Paris, FranceSearch for more papers by this author First published: October 3, 1989 https://doi.org/10.1002/chin.198940143Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article. Volume20, Issue40October 3, 1989 RelatedInformation
The condensation of benzaldehyde and cyclohexanone with the bromozinc salt derived from γ-bromosenecioiˇc acid, in the presence of zinc, yield unsaturated hydroxyacids or lactones. The equilibration of the intermediary alcoxides is studied.
The title compounds are easily synthesized in good yields by reaction of the Reformatsky reagents derived from α-bromesters, α-bromocarboxamides, and α-bromonitriles with 2-acyl-3-phenyl(or 3-alkyl)-1,1-diethoxycarbonylcyclopropanes.
AbstractThe bicyclic lactones (III) and (V) are prepared by reacting the 2‐acyl‐1,1‐dicarboxycyclopropanes (I) and 2‐acyl‐1,1‐diethoxycarbonylcyclopropanes (IV) with the alkyl Grignard or allylzinc reagents (II).
La condensation des aldéhydes et des cétones avec le sel bromozincique issu de l'acide γ-bromocrotonique, en présence de zinc et dans le THF, conduit aux hydroxyacides ethyléniques “linéaires” et “ramifiés” attendus. Ces derniers, qui représentent les produits cinétiques de la réaction, s'équilibrent au stade alcoolate pour conduire, après hydrolyse, aux isomères “linéaires” thermodynamiquement plus stables, dont c'est une bonne préparation.
Synthese d'(acyl-1 dichloro-3,3)- et (alcene-2'yl-1 dichloro-3,3) propene-2 dicarboxylates-1,1 de diethyle
AbstractBenzalanilin reagiert mit den organometallischen Reagentien (I) unter Bildung der β‐Anilino‐ouß‐diphenyl‐propionsäuren (III), die als erythro/threo‐Gemische′anfallen.
AbstractDas aus dem Zinkbromid‐Salz (III) der γ‐Bromcrotonsäure (I) mit Zink hergestellte Reformatsky‐Reagens reagiert mit den Carbonylverbindungen (IV) zu den α‐ bzw. γ‐Substitutionsprodukten (VI) bzw. (V).
AbstractKetoxime (I) lassen sich nach zweifacher Metallierung an Aldimine (III) zu Azetidinderivaten (IV) addieren.
The preparation of bis(trimethylsilyl)butadienyl acetal (I) and bis(trimethylsilyl)methylbutadienyl acetal (II) is reported; compound I reacts with phenyl aldehyde and titanium chloride to give linear and branched isomers of hydroxyacids.
Chemischer InformationsdienstVolume 15, Issue 1 Preparative Organic Chemistry ChemInform Abstract: SILICON IN ORGANIC SYNTHESIS: AN IMPROVED 4-BROMINATION OF 2-ALKENOIC ACIDS M. BELLASSOUED, M. BELLASSOUEDSearch for more papers by this authorF. HABBACHI, F. HABBACHISearch for more papers by this authorM. GAUDEMAR, M. GAUDEMARSearch for more papers by this author M. BELLASSOUED, M. BELLASSOUEDSearch for more papers by this authorF. HABBACHI, F. HABBACHISearch for more papers by this authorM. GAUDEMAR, M. GAUDEMARSearch for more papers by this author First published: January 3, 1984 https://doi.org/10.1002/chin.198401135Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume15, Issue1January 3, 1984 RelatedInformation
AbstractDie Umsetzung der Silylester (I) von in γ‐Stellung bromierten α,β‐ungesättigten Carbonsäuren mit Zink und Aldehyden (II)in einer oder zwei Stufen führt zu unterschiedlichen Ergebnissen.
Organometallic compounds derived from thioamides RCH2CSN(R3)2 condense normally with aldehydes and saturated ketones. Condensation with 4-t-butyl-cyclohexanone leads predominantly to equatorial attack by the organometallic compound. These results suggest that the organometallic structure as RCHC(SM)N(R3)2.
The regiospecificity of Reformatsky reactions of γ-bromocrotonic and γ-bromosenecioic timethylsilyl esters are discussed. One-step reactions lead to a majority of α-substituted derivatives, while in two-step reactions, the γ-substituted products are obtained exclusively.
AbstractDie durch Umsetzung von Lithium‐ oder Chlormagnesium‐di‐(isopropyl)‐ amin (II) mit Thioamiden (I) erhaltenen metallorganischen Thioamid‐Derivate (III) bzw. (IV) reagieren mit Aldehyden oder Ketonen (V) zu den β‐Hydroxythioamiden (VI).
Chemischer InformationsdienstVolume 10, Issue 20 Preparative Organic Chemistry ChemInform Abstract: ADDITION OF ORGANOZINC COMPOUNDS FROM α-ACETYLENIC BROMIDES TO TRIPLE BONDS: SYNTHESIS OF β-ENYNES AND β-ENYNOLS M. BELLASSOUED, M. BELLASSOUEDSearch for more papers by this authorY. FRANGIN, Y. FRANGINSearch for more papers by this authorM. GAUDEMAR, M. GAUDEMARSearch for more papers by this author M. BELLASSOUED, M. BELLASSOUEDSearch for more papers by this authorY. FRANGIN, Y. FRANGINSearch for more papers by this authorM. GAUDEMAR, M. GAUDEMARSearch for more papers by this author First published: May 15, 1979 https://doi.org/10.1002/chin.197920108Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat No abstract is available for this article. References M. BELLASSOUED, Y. FRANGIN, M. GAUDEMAR, ADDITION OF ORGANOZINC COMPOUNDS FROM α-ACETYLENIC BROMIDES TO TRIPLE BONDS: SYNTHESIS OF β-ENYNES AND β-ENYNOLS, J. Organomet. Chem., 1979, 166, 1. DOI: 10.1016/S0022-328X(00)91413-X; 10.1016/S0022-328X(00)91413-X CASWeb of Science®Google Scholar Volume10, Issue20May 15, 1979 ReferencesRelatedInformation