Practical measurements of pH in the marine environment have as their usual objective the assessment of acid-base speciation. In order for accurate results to be obtained, the three pH scales in common use must be coupled each with its corresponding acid-base dissociation constant. For consistency in marine studies, it is desirable that a single procedure be selected and used by all marine scientists.

Book Review: The Holy Reich: Nazi Conceptions of Christianity, 1919-1945 Get access Robert G. Bates Robert G. Bates Oxford Brookes University Search for other works by this author on: Oxford Academic Google Scholar German History, Volume 22, Issue 3, July 2004, Pages 489–491, https://doi.org/10.1177/026635540402200322 Published: 01 July 2004

This document deals with definitions, procedures and terminology for the quantity pH which is of wide interest for chemists, biologists and engineers. It is the result of discussions since 1977 within IUPAC and related discussions in other international bodies. It constitutes in the definition of pH scales a compromise which recognises the advantages of both the previously endorsed multistandard approach and that based on the definition of a single standard with associated operational standards.

We have investigated the variations in the potentials of sodium-selective glass-membrane electrodes in various concentrations of albumin. These protein solutions serve as a simple model for measurements of electrolytes in whole blood, plasma, or serum with such an electrode. The results indicate that albumin-sodium binding and variations in liquid-junction potentials are of negligible importance. Mostly, the effect of albumin on the sodium glass-electrode potential is attributable to variations in the activity of sodium, determined by the water content of the solutions. We have calculated apparent fractional protein volumes in albumin solutions from measurements of sodium glass-electrode potential and find they compare well with the classical McLean-Hastings formulation. Our results indicate the need to correct experimentally determined potentiometric electrolyte concentrations for protein volumes.

The stand a rd pH values or th e solutio n or potass ium hyd rogen phtha la te (mo la lil y 0.05 mol kg-I) have bee n red ele rmin ed ove r Ihe le mpe ralure range 0 to 60 °C, us ing S RM l 8Se1.Ext e ns ive meas ure me nts we re made or th e e mr or ce ll s or Ih e Iype Pd; H2(g, 1 a lm)J KH phlhal ale (rn = 0.05), KCI (ml JA gC I;Ag wh ere m.KCI was 0.015, O.OJ., or 0.005 mol kg-I, rrom whi c h va lues or th e acidil y run cti on p(a ,"Ycl) we re derived.The pH conve nti o n d efin es Yel in Ihe ra nge or ionic stre ngths 0 to 0 . 1 mo l kg-I a nd pe rmits co nvenlio nal va lu es or paH 10 be obl a in ed.According to NBS procedures, I)(lH ror se lected re re re nce so luli ons is idenlifi ed wilh Ih e s landard pH(S) in the ope ra ti onal de finiti o n or p H. The new va lues, give n in te rm s or Ihe the rm ody na mi c tempe ralure ( 7') b y 2073.44 pH(S) = --7'--13.3270+ 0.0451997' -3.4846 X 1O-' {' d irre r, on the average, by 0.003 unil rro m th e res ults based on th e 1944 data or Hamer and Acree .

I. INTRODUCTION AND SCOPE The term 'ion-selective electrodes' is applied to a range of membrane electrodes which respond selectively toward one (or several) ionic species in the presence of others. The less-preferred term 'ion-specific' is not favored1 because these electrodes are rarely specific in their response to one ionic species over others, although this is a desirable property sought by the designer of new electrodes. The description membrane is used here in its broadest sense to denote a thin section of electrically conducting material separating two solutions and across which a potential develops. Often the term membrane has associated with it the notion of permeability to a species present in the flanking solutions. However, although this is undoubtedly true with certain porous biological and synthetic membranes, the actual mechanism of electrical conduction in general varies with the type of membrane material; indeed it may change within it.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTpK values for D2O and H2OR. G. Bates , Robinson R. A. , and Covington A. K. Cite this: J. Chem. Educ. 1967, 44, 11, 635Publication Date (Print):November 1, 1967Publication History Received3 August 2009Published online1 November 1967Published inissue 1 November 1967https://doi.org/10.1021/ed044p635RIGHTS & PERMISSIONSArticle Views209Altmetric-Citations5LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (264 KB) Get e-Alerts Get e-Alerts

Report, of Ad Hoc Committee on Acid-Base Methodology Get access S. R. Gambino, M.D., S. R. Gambino, M.D. Chairman Search for other works by this author on: Oxford Academic Google Scholar P. Astrup, M.D., P. Astrup, M.D. Search for other works by this author on: Oxford Academic Google Scholar R. G. Bates, PH.D., R. G. Bates, PH.D. Search for other works by this author on: Oxford Academic Google Scholar E. J. M. Campbell, PH.D., M.D., E. J. M. Campbell, PH.D., M.D. Search for other works by this author on: Oxford Academic Google Scholar F. P. Chinard, M.D., F. P. Chinard, M.D. Search for other works by this author on: Oxford Academic Google Scholar G. G. Nahas, M.D., PH.D., G. G. Nahas, M.D., PH.D. Search for other works by this author on: Oxford Academic Google Scholar O. Siggaardandersen, M.D., PH.D., O. Siggaardandersen, M.D., PH.D. Search for other works by this author on: Oxford Academic Google Scholar R. Winters, M.D. R. Winters, M.D. Search for other works by this author on: Oxford Academic Google Scholar American Journal of Clinical Pathology, Volume 46, Issue 3, 1 September 1966, Pages 376–381, https://doi.org/10.1093/ajcp/46.3.376 Published: 01 September 1966 Article history Received: 30 October 1965 Published: 01 September 1966

Annals of the New York Academy of SciencesVolume 133, Issue 1 p. 259-267 REPORT OF THE AD HOC COMMITTEE ON METHODOLOGY S. R. Gambino Chairman, S. R. Gambino ChairmanSearch for more papers by this authorP. Astrup, P. AstrupSearch for more papers by this authorR. G. Bates, R. G. BatesSearch for more papers by this authorE. J. M. Campbell, E. J. M. CampbellSearch for more papers by this authorF. P. Chinard, F. P. ChinardSearch for more papers by this authorG. G. Nahas, G. G. NahasSearch for more papers by this authorO. Siggaard-Andersen, O. Siggaard-AndersenSearch for more papers by this authorR. Winters, R. WintersSearch for more papers by this author S. R. Gambino Chairman, S. R. Gambino ChairmanSearch for more papers by this authorP. Astrup, P. AstrupSearch for more papers by this authorR. G. Bates, R. G. BatesSearch for more papers by this authorE. J. M. Campbell, E. J. M. CampbellSearch for more papers by this authorF. P. Chinard, F. P. ChinardSearch for more papers by this authorG. G. Nahas, G. G. NahasSearch for more papers by this authorO. Siggaard-Andersen, O. Siggaard-AndersenSearch for more papers by this authorR. Winters, R. WintersSearch for more papers by this author First published: April 1966 https://doi.org/10.1111/j.1749-6632.1966.tb50732.xCitations: 15AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Citing Literature Volume133, Issue1Current Concepts of Acid-Base MewsurementApril 1966Pages 259-267 RelatedInformation

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInterpretation of Potentiometric Titrations of Weak Acids in Methanol-Water Solvents.K. C. Ong, R. A. Robinson, and R. G. BatesCite this: Anal. Chem. 1964, 36, 10, 1971–1972Publication Date (Print):September 1, 1964Publication History Published online1 May 2002Published inissue 1 September 1964https://pubs.acs.org/doi/10.1021/ac60216a025https://doi.org/10.1021/ac60216a025research-articleACS PublicationsRequest reuse permissionsArticle Views126Altmetric-Citations22LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

R. G. Bates, V. E. Bower, R. G. Canham and J. E. Prue, Trans. Faraday Soc., 1959, 55, 2062 DOI: 10.1039/TF9595502062

The purity of two preparations of benzoic acid, t hree of oxali c acid , a nd Lhree of poLas~ium hydrogen phthalate has been compa red by a prec ise determination of t he eq ui valence of each substanc0 with t he same solid r eference base, sodium carbonate, t he on ly requ irements for which were t hat its composition be uniform a nd remain co nstant t hrouo-h out t he seri es of measu rements . The inflectio n point in each t itration was dete rmined "'by a dif-rerent ial po tentiometri? .method u t ili zing two hydr ogen electrodes. The procedure, which gives a degree of preCl RlOn greater than has prev iously been r eported for acidimetric determ inations is described in detail. When abo ut 0.06 eq uiva len t of acid was used in each t it rat ion th~ reproducibili ty atta in able was better t ha n 0.002 percent. The fa ilure of t he inflection poin t and the equiva lcnce poin t to coin cide exactly has been consid er ed in evaluating t he reliabili ty of the proced ure. The pur'i ty of one of t he samples of benzoic ac id , as determined in dependently from accurate measurements of t he freezin g point, was 99.997 mole percen t . S ino-I e crysta ls of benzoic ac id g rown from a melt of t his materia l were selected as a refe rence'" ac id a nd were rega rded La have a puri ty of JOO.OOO p ercent. I n te rm s of t his reference fL preparaLion of p otass ium hydrogen ph t ha latc co nsis t ing of opticall y perfect crystals wa~ fou nd to have a puri ty of 100.000 perce nt . The method is ad a ptab le to a variety of ac ids a lld bases and hence, provides fL n addi t iona l cr iterion of puri ty for t hese subs ta nces. '

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMeasurement of Effect of Dilution upon pHR. G. BatesCite this: Anal. Chem. 1954, 26, 5, 871–874Publication Date (Print):May 19, 1954Publication History Published online1 May 2002Published inissue 19 May 1954https://pubs.acs.org/doi/10.1021/ac60089a018https://doi.org/10.1021/ac60089a018research-articleACS PublicationsRequest reuse permissionsArticle Views1420Altmetric-Citations10LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

Am Beispiel der Pikrinsäure wird gezeigt, wie man mit Hilfe optischer Messungen auch zu der thermodynamischen Aziditätskonstante von recht starken Säuren (pK ≈ 0) kommen kann.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMold Growth and pH of Tartrate Buffer SolutionsR. G. BatesCite this: Anal. Chem. 1951, 23, 5, 813–814Publication Date (Print):May 15, 1951Publication History Published online1 May 2002Published inissue 15 May 1951https://pubs.acs.org/doi/10.1021/ac60053a048https://doi.org/10.1021/ac60053a048research-articleACS PublicationsRequest reuse permissionsArticle Views82Altmetric-Citations2LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDefinitions of pH Scales.Roger G. BatesCite this: Chem. Rev. 1948, 42, 1, 1–61Publication Date (Print):February 1, 1948Publication History Published online1 May 2002Published inissue 1 February 1948https://pubs.acs.org/doi/10.1021/cr60131a001https://doi.org/10.1021/cr60131a001research-articleACS PublicationsRequest reuse permissionsArticle Views1177Altmetric-Citations65LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts