We report on the effect of magnetic impurities on the microscopic superconducting (SC) properties of the kagome-lattice superconductor La(Ru1-xFex)3Si2 using muon spin relaxation/rotation. A strong suppression of the superconducting critical temperature Tc, the SC volume fraction, and the superfluid density was observed. We further find a correlation between the superfluid density and Tc which is considered a hallmark feature of unconventional superconductivity. Most remarkably, measurements of the temperature-dependent magnetic penetration depth lambda reveal a change in the low-temperature behavior from exponential saturation to a linear increase, which indicates that Fe doping introduces nodes in the superconducting gap structure at concentrations as low as x = 0.015. Our results point to a rare example of unconventional superconductivity in the correlated kagome lattice and accessible tunability of the superconducting gap structure, offering new insights into the microscopic mechanisms involved in superconducting order.
Electronic band structures in solids stem from a periodic potential reflecting the structure of either the crystal lattice or electronic order. In the stoichiometric ruthenate Ca3Ru2O7, numerous Fermi surface-sensitive probes indicate a low-temperature electronic reconstruction. Yet, the causality and the reconstructed band structure remain unsolved. Here, we show by angle-resolved photoemission spectroscopy, how in Ca3Ru2O7 a C-2-symmetric massive Dirac semimetal is realized through a Brillouin-zone preserving electronic reconstruction. This Dirac semimetal emerges in a two-stage transition upon cooling. The Dirac point and band velocities are consistent with constraints set by quantum oscillation, thermodynamic, and transport experiments, suggesting that the complete Fermi surface is resolved. The reconstructed structure-incompatible with translational-symmetry-breaking density waves-serves as an important test for band structure calculations of correlated electron systems.
Spontaneous symmetry breaking constitutes a paradigmatic classification scheme of matter. However, broken symmetry also entails domain degeneracy that often impedes identification of novel low symmetry states. In quantum matter, this is additionally complicated by competing intertwined symmetry breaking orders. A prime example is that of unconventional superconductivity and density-wave orders in doped cuprates in which their respective symmetry relation remains a key question. Using uniaxial pressure as a domain-selective stimulus in combination with x-ray diffraction, we unambiguously reveal that the fundamental symmetry of the charge order in the prototypical cuprate La$_{1.88}$Sr$_{0.12}$CuO$_4$ is characterized by uniaxial stripes. We further demonstrate the direct competition of this stripe order with unconventional superconductivity via magnetic field tuning. The stripy nature of the charge-density-wave state established by our study is a prerequisite for the existence of a superconducting pair-density-wave -- a theoretical proposal that clarifies the interrelation of intertwined quantum phases in unconventional superconductors -- and paves the way for its high-temperature realization.
By using mostly the muon-spin rotation/relaxation (μSR) technique, we investigate the superconductivity (SC) of Nb_5Ir_3-xPt_xO (x = 0 and 1.6) alloys, with T_c = 10.5 K and 9.1 K, respectively. At a macroscopic level, their superconductivity was studied by electrical resistivity, magnetization, and specific-heat measurements. In both compounds, the electronic specific heat and the low-temperature superfluid density data suggest a nodeless SC. The superconducting gap value and the specific heat discontinuity at T_c are larger than that expected from the Bardeen-Cooper-Schrieffer theory in the weak-coupling regime, indicating strong-coupling superconductivity in the Nb_5Ir_3-xPt_xO family. In Nb_5Ir_3O, multigap SC is evidenced by the field dependence of the electronic specific heat coefficient and the superconducting Gaussian relaxation rate, as well as by the temperature dependence of the upper critical field. Pt substitution suppresses one of the gaps, and Nb_5Ir_1.4Pt_1.6O becomes a single-gap superconductor. By combining our extensive experimental results, we provide evidence for a multiple- to single-gap SC crossover in the Nb_5Ir_3-xPt_xO family.
Electronic band structures in solids stem from a periodic potential reflecting the structure of either the crystal lattice or an electronic order. In the stoichiometric ruthenate Ca_3Ru_2O_7, numerous Fermi surface sensitive probes indicate a low-temperature electronic reconstruction. Yet, the causality and the reconstructed band structure remain unsolved. Here, we show by angle-resolved photoemission spectroscopy, how in Ca_3Ru_2O_7 a C_2-symmetric massive Dirac semimetal is realized through a Brillouin-zone preserving electronic reconstruction. This Dirac semimetal emerges in a two-stage transition upon cooling. The Dirac point and band velocities are consistent with constraints set by quantum oscillation, thermodynamic, and transport experiments, suggesting that the complete Fermi surface is resolved. The reconstructed structure – incompatible with translational-symmetry-breaking density waves – serves as an important test for band structure calculations of correlated electron systems.
M. Horio, Q. Wang, V. Granata, 3 K. P. Kramer, Y. Sassa, S. Jöhr, D. Sutter, A. Bold, L. Das, Y. Xu, R. Frison, R. Fittipaldi, 3 T. K. Kim, C. Cacho, J. E. Rault, P. Le Fèvre, F. Bertran, N. C. Plumb, M. Shi, A. Vecchione, 3 M. H. Fischer, and J. Chang Physik-Institut, Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland CNR-SPIN, I-84084 Fisciano, Salerno, Italy Dipartimento di Fisica ”E.R. Caianiello”, Università di Salerno, I-84084 Fisciano, Salerno, Italy Department of Physics, Chalmers University of Technology, SE-412 96 Göteborg, Sweden Center for X-ray Analytics, Swiss Federal Laboratories for Materials Science and Technology (Empa), Überlandstrasse 129, CH-8600 Dübendorf, Switzerland Diamond Light Source, Harwell Campus, Didcot, OX11 0DE, United Kingdom Synchrotron SOLEIL, Saint-Aubin-BP 48, F-91192 Gif sur Yvette, France Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland