In this study, the effect of temperature, water quality, and the impact of an intense typhoon event on change in 137Cs concentration in the water of agricultural and forested rivers near the Fukushima Daiichi nuclear power plant (Japan) was evaluated using monthly stationary observations obtained under baseflow conditions 2.8-10.6 years after the nuclear accident in 2011. The dissolved 137Cs concentration fluctuated seasonally with water temperature in all rivers, and the increase in dissolved 137Cs concentration for unit increase in temperature was higher in forested rivers than in agricultural rivers. The relationship between water temperature and the apparent distribution coefficient of 137Cs well followed the van 't Hoff equation in the two agricultural rivers, where the enthalpy of reaction was estimated as-15.6 and-19.6 kJ mol-1. The van 't Hoff equation was not well followed for a forested river, where the suspended solids mainly comprised organic matter, suggesting that the dominant process determining dissolved 137Cs concentrations in forested rivers is not only water temperature effect on ion exchange, but rather the input of 137Cs and K+ (competing with 137Cs for exchange sites on mineral particles) into the water phase via litter leaching. Suspended solids concentrations in agricultural rivers correlated negatively with 137Cs concentrations in suspended solids, suggesting an increased proportion of coarse particles or the input of soils with low 137Cs concentration from decontaminated agricultural land. At some sites, 137Cs concentrations in dissolved form and in suspended solids were reduced sharply in association with the passage of Typhoon Hagibis in October 2019, suggesting that Typhoon Hagibis caused large-scale surface erosion that removed the source of 137Cs.
The odors of five types of vegetables (potato, cabbage, broccoli, onion, and Welsh onion) exhibiting rot symptoms caused by seven bacterial pathogens ( Pectobacterium carotovorum subsp. carotovorum , Erwinia persicina , Pseudomonas marginalis pv. marginalis , Pseudomonas viridiflava , Xanthomonas campestris pv. campestris , Burkholderia gladioli , and Burkholderia cepacia ) were analyzed using gas chromatography-mass spectrometry (GC-MS). A total of 39 compounds were detected across these samples, with each vegetable-pathogen combination exhibiting a distinct profile of microbial volatile organic compounds (mVOCs). These findings suggest that, in principle, phytopathogens can be discriminated based on olfactory information derived from their metabolites.
