Описан простой способ прогнозной оценки выхода детонационных наноалмазов, учитывающий массовое содержание элементов в углеродсодержащем взрывчатом веществе общей формулы CaHbNcOd. Установлена эмпирическая зависимость содержания детонационных наноалмазов в полупродукте синтеза наноалмазов — алмазной шихте в зависимости от содержания углерода в молекулах взрывчатых веществ. Приведены зависимости выхода детонационных наноалмазов от содержания химических элементов в исходной системе, позволяющие давать количественные прогнозные оценки выхода детонационных наноалмазов. A simple method of predictive estimation of the yield of detonation nanodiamonds is described, which takes into account the mass fractions of elements in the carbon-containing explosive with a general formula CaHbNcOd. An empirical dependence of the content of detonation nanodiamonds in the semi-product of nanodiamond synthesis (diamond charge mixture) on the fraction of carbon in molecules of explosives is derived. The yield of detonation nanodiamonds is presented as a function of the fractions of chemical elements in the initial system, which makes it possible to give quantitative predictions of the yield of detonation nanodiamonds.
Powders of boron-doped and phosphorous-doped detonation nanodiamond and sintered pellets made of non-doped nanodiamond powders were studied by the electron magnetic resonance and X-ray diffraction methods. The possibility of doping of the detonation nanodiamond crystal by boron and phosphorous was demonstrated. The possibility to use these methods for diagnostics of the doped diamond nanocrystals during shock-wave synthesis has been established.