Antarctic ice cores have provided valuable insights into the intricate interplay between dust and climate dynamics in the Southern Hemisphere. However, until now, a continuous and quantitative record detailing the origin of dust during the last deglaciation is lacking. In this study, we utilized a novel database comprising 207 Rare Earth Element (REE) patterns obtained from dust and fine sediment/soil fractions collected from well-known potential source areas (PSA) in the Southern Hemisphere. By combining this comprehensive dataset of REE patterns, we developed a robust statistical model to best match the REE patterns measured in the Epica Dronning Maud Land (EDML) ice core in East Antarctica. Among the 398 samples analyzed in the EDML core, 386 have been un-mixed with statistical significance. When coupled with data on total atmospheric deposition, our findings enable the first quantification of the dust flux from the various PSA reaching the EDML region between 7,000 and 27,000 years before present (kyr BP). Our results unveil that, despite a substantial decrease in atmospheric deposition at the onset of deglaciation around 18,000 years ago, the dust composition remained relatively uniform throughout the Last Glacial Maximum (LGM, 18-27 kyr BP) and Heinrich Stadial 1 (HS1, between 14.7-18 kyr BP). During this period, approximately 68% of the total dust deposition was coming from Patagonian sources, with the remaining contributions originating from Australia (14-15%), Southern Africa (~9%), New Zealand (~3-4%), and Puna-Altiplano (~2-3%). A significant shift in dust provenance occurred around 14.5 kyr BP, marked by a drop in Patagonian contribution to below 50%, while low-latitude PSAs increased their contributions, accounting for 21-23% from Southern Africa, 13-21% from Australia, and ~4-10% from Puna-Altiplano. We propose that this shift is linked to enduring alterations in the hydrology of Patagonian rivers, including Atlantic-Pacific drainage reversals and the decline of braided planform, along with the sudden submersion of the Patagonian shelf. Indeed, between 15 and 14.0 kyr BP, the PAT shelf surface area was halved and by ∼13 kyr BP, it had shrunk by 70% from to its former maximum glacial expansion, with most of the PAT shelf south of 40°S submerged. The drastic reduction of the area subjected to aeolian deflation coupled with the reduction of fine sediment supply of eastern plains in PAT induced an overall decline in dust emission from Patagonian sources. Our finding emphasizes an important feedback between dust composition in Southern Hemisphere and eustatic sea level during the Last Glacial-Interglacial Transition. The early Holocene dust composition reveals heightened variability, with a prevalent contribution from Patagonia at ~50%. Post 11.5 kyr BP, as Puna-Altiplano experienced persistent aridity, our records demonstrate a noticeable increase in dust contribution. Leveraging a comprehensive coverage of both local and distal PSA, our statistical model, based on REE patterns, provides a straightforward and cost-effective method for tracing dust sources in ice cores.

Epica Dome C (EDC) ice core is invaluable and highly-resolved record of Earth’s climate. Within the database of climate proxies in deep ice core, quantifying the contribution of the various sources of dust has been very challenging and, so far, no continuous record of dust provenance has been established. Here, we developed an algorithm that combines the REE patterns from a large database (from 207 sediments/soils in well-known Potential Source Areas - PSA - in the Southern Hemisphere) to fit the REE patterns measure in EDC data[1]. Complemented by Monte Carlo simulations to account for analytical uncertainties and by evaluation of goodness-of-fit, our model quantifies the respective contribution of the dust sources (regrouped by large PSA like Patagonia, Africa, S-E Australia, New Zealand and Puna-Altiplano) deposited in EDC ice core between 2.9 and 33.7 kyr at a centennial resolution.Our provenance record reveals that a major shift in dust provenance occurred at ~14.5-kyr BP during which the contribution of Patagonia (PAT – the main supplier of dust of the Last Glacial Maximum -LGM) declined from ̴55% to 35% (% of total dust deposition) while African dust (SAF) became more prevalent from ̴20% during LGM to ̴40% after 14.5 kyr BP. As a matter of fact, the main supplier of dust in EDC during the Holocene is Southern Africa. We ascribe this abrupt shift to (i) long-lasting changes in the hydrology and of Patagonian rivers and (ii) to a sudden acceleration of sea-level rise between 14 and 15 kyr BP that submerged vast swathes of Patagonian continental shelf, triggering a decline in PAT dust supply to Antarctica. In turn, this induced a steep increase – in relative term - of SAF dust contribution in EDC.Importantly,our record for EDC is very much consistent with our previous results for Epica Dronning Maud Land (EDML)[2] ice core showing the exact same shift (PAT for SAF dust) between 14 and 15 kyr BP. Yet, compared to EDML, EDC record shows generally larger contribution for SAF and lower PAT dust which seems logical considering the respective localization of EDML and EDC. Our results for EDC thus confirms the relationship between dust composition and eustatic sea level and also highlight the importance of African dust deposition in the Southern Indian ocean and in the adjacent sector of the Southern Ocean since 14 kyr. Our tracing method using REE patterns offers a new, high-resolution tool for the reconstruction of atmospheric paleo-circulation and paleoclimate in the Southern Hemisphere.[1]Gabrielli et al., (2010), Quaternary Science Review 29, 1-2.[2]Vanderstraeten et al., (2023), Science of the Total Environment 881, 16345

Northwest Africa transitioned from a wet/vegetated landscape toward drier/sparser conditions sometime between the late-Pliocene and the late-Pleistocene. However, our understanding of the precise timing and nature of this transition is hampered by a paucity of paleo-records which bridge these two intervals. Here we report new plant-wax isotope as well as dust and opal flux records from the relatively brief interval similar to 1.1-1.0 million years ago (Ma) to evaluate the astronomical timescale controls of Northwest African hydroclimate and vegetation during the Mid-Pleistocene Transition (MPT) and, in context with published records, the drivers of long-term climate and ecological trends over the Plio-Pleistocene. The tempo and amplitude of the Northwest African monsoon rainfall swings closely track low latitude insolation forcings over the last 5 Ma. However, we demonstrate that a pronounced mean state decline in monsoon strength likely occurred following the MPT most likely instigated by increasing Atlantic meridional sea surface temperature gradients or declines in the strength of the meridional overturning circulation. The northward extent of vegetation does not track changes in monsoon strength over the Plio-Pleistocene and thus may be more strongly influenced by changes in monsoon rainfall extent or ecosystem disturbances. Progressively diminished dust fluxes following a decline in monsoon strength after 1.0 Ma is consistent with reduced production and subsequent depletion of fine-grained sediments in the Sahara. Synchroneity between dust and opal fluxes across timescales suggests nutrient delivery to the surface ocean via dust plays a key role in marine primary productivity off the coast of Northwest Africa. Northwest African monsoon intensity declined substantially sometime between 1.0 and 0.5 Ma Rainfall penetration or disturbances may be more consequential than monsoon strength for ecosystem biogeography over 105-106 years Sedimentary dust and opal fluxes drop following monsoon intensity decline, linking dust production, dust flux, and marine productivity

Epica Dome C (EDC) ice core is invaluable and highly-resolved record of Earth’s climate. Within the database of climate proxies in deep ice core, quantifying the contribution of the various sources of dust has been very challenging and, so far, no continuous record of dust provenance has been established. Here, we developed an algorithm that combines the REE patterns from a large database (from 207 sediments/soils in well-known Potential Source Areas - PSA - in the Southern Hemisphere) to fit the REE patterns measure in EDC data[1]. Complemented by Monte Carlo simulations to account for analytical uncertainties and by evaluation of goodness-of-fit, our model quantifies the respective contribution of the dust sources (regrouped by large PSA like Patagonia, Africa, S-E Australia, New Zealand and Puna-Altiplano) deposited in EDC ice core between 2.9 and 33.7 kyr at a centennial resolution. Our provenance record reveals that a major shift in dust provenance occurred at ~14.5-kyr BP during which the contribution of Patagonia (PAT – the main supplier of dust of the Last Glacial Maximum -LGM) declined from   ̴55% to 35% (% of total dust deposition) while African dust (SAF) became more prevalent from   ̴20% during LGM to   ̴40% after 14.5 kyr BP. As a matter of fact, the main supplier of dust in EDC during the Holocene is Southern Africa. We ascribe this abrupt shift to (i) long-lasting changes in the hydrology and of Patagonian rivers and (ii) to a sudden acceleration of sea-level rise between 14 and 15 kyr BP that submerged vast swathes of Patagonian continental shelf, triggering a decline in PAT dust supply to Antarctica. In turn, this induced a steep increase – in relative term - of SAF dust contribution in EDC. Importantly,our record for EDC is very much consistent with our previous results for Epica Dronning Maud Land (EDML)[2] ice core showing the exact same shift (PAT for SAF dust) between 14 and 15 kyr BP. Yet, compared to EDML, EDC record shows generally larger contribution for SAF and lower PAT dust which seems logical considering the respective localization of EDML and EDC. Our results for EDC thus confirms the relationship between dust composition and eustatic sea level and also highlight the importance of African dust deposition in the Southern Indian ocean and in the adjacent sector of the Southern Ocean since 14 kyr. Our tracing method using REE patterns offers a new, high-resolution tool for the reconstruction of atmospheric paleo-circulation and paleoclimate in the Southern Hemisphere. [1]Gabrielli et al., (2010), Quaternary Science Review 29, 1-2. [2]Vanderstraeten et al., (2023), Science of the Total Environment 881, 16345

Natural mineral dust are composed of reactive species affecting directly or indirectly the global climate through aerosol-radiation-cloud-chemistry interactions. They are also efficient suppliers of organic or inorganic components that can influence the primary productivity in oceans, such as the Austral Ocean.The present study attempts to solve the puzzle of the origin (the potential source areas - PSA) of dust deposition in East Antarctica (EA). We combine analyses of size, shape, mineralogy, geochemistry (trace element, and especially REE data), as well as strontium (Sr), neodymium (Nd) and lead (Pb) isotopes, performed on modern snow dust samples collected along a ~200km transect in the Dronning Maud Land area (from the Belgian Station Princess Elisabeth Antarctica to the coast). A statistical mixing model was specifically developed to fit the Rare Earth Elements (REE) patterns of Antarctic dust samples (Vanderstraeten et al., 2023) by combining REE profiles from PSA in Southern South America (Patagonia, Puna-Altiplano plateau), Southern Africa (Namibia, SAF), Australia and New-Zealand. In addition to REE, PSA isotopic compositions of Sr, Nd and Pb were analysed (Gili et al., 2022), specifically in 30 samples from the Namibian coast where an evident lack of analyzed samples was detected in the literature data collection.The atmospheric particles mainly show a submicronic size (> 98% of particles < 5μm, n=2500) and angular shape. SEM-EDS observations suggest spatial variations in mineralogy, reflecting the influence of input from the local Sør Rondanes mountains for the inland sites (Fe-Mg silicate > 50 %) and distal source’ input at the coast (predominance of aluminosilicates and quartz, with <20% of Fe-Mg silicates). The REE profiles and the Sr, Nd and Pb isotopic variability observed in present-day dust depositions at the EA coast, as it was demonstrated for the Holocene interglacial depositions (at Vostok and EDC; Gili et al., 2022) in East Antarctica and the South Atlantic Ocean, can be related to the contributions of two main PSAs: Southern South America, dominated by the major contribution of Patagonia and important percentage of the Puna–Altiplano Plateau, in combination with Southern Africa in response to the plausible transport by the strong Berg Winds. This work presents an innovative and multi-proxy approach for the identification of potential dust source contributions in the Southern Hemisphere, and East Antarctica in particular, which provides major implications for the reconstruction of atmospheric circulation and implications on climate evolution. Vanderstraeten et al., (2023), Science of the Total Environment, 881, 163450; http://dx.doi.org/10.1016/j.scitotenv.2023.163450Gili et al., (2022), Nature Communications earth & environment, 3 :129 ; https://doi.org/10.1038/s43247-022-00464

Antarctic ice cores have provided valuable insights into the intricate interplay between dust and climate dynamics in the Southern Hemisphere. However, until now, a continuous and quantitative record detailing the origin of dust during the last deglaciation is lacking. In this study, we utilized a novel database comprising 207 Rare Earth Element (REE) patterns obtained from dust and fine sediment/soil fractions collected from well-known potential source areas (PSA) in the Southern Hemisphere. By combining this comprehensive dataset of REE patterns, we developed a robust statistical model to best match the REE patterns measured in the Epica Dronning Maud Land (EDML) ice core in East Antarctica. Among the 398 samples analyzed in the EDML core, 386 have been un-mixed with statistical significance. When coupled with data on total atmospheric deposition, our findings enable the first quantification of the dust flux from the various PSA reaching the EDML region between 7,000 and 27,000 years before present (kyr BP). Our results unveil that, despite a substantial decrease in atmospheric deposition at the onset of deglaciation around 18,000 years ago, the dust composition remained relatively uniform throughout the Last Glacial Maximum (LGM, 18-27 kyr BP) and Heinrich Stadial 1 (HS1, between 14.7-18 kyr BP). During this period, approximately 68% of the total dust deposition was coming from Patagonian sources, with the remaining contributions originating from Australia (14-15%), Southern Africa (~9%), New Zealand (~3-4%), and Puna-Altiplano (~2-3%). A significant shift in dust provenance occurred around 14.5 kyr BP, marked by a drop in Patagonian contribution to below 50%, while low-latitude PSAs increased their contributions, accounting for 21-23% from Southern Africa, 13-21% from Australia, and ~4-10% from Puna-Altiplano. We propose that this shift is linked to enduring alterations in the hydrology of Patagonian rivers, including Atlantic-Pacific drainage reversals and the decline of braided planform, along with the sudden submersion of the Patagonian shelf. Indeed, between 15 and 14.0 kyr BP, the PAT shelf surface area was halved and by ∼13 kyr BP, it had shrunk by 70% from to its former maximum glacial expansion, with most of the PAT shelf south of 40°S submerged. The drastic reduction of the area subjected to aeolian deflation coupled with the reduction of fine sediment supply of eastern plains in PAT induced an overall decline in dust emission from Patagonian sources. Our finding emphasizes an important feedback between dust composition in Southern Hemisphere and eustatic sea level during the Last Glacial-Interglacial Transition. The early Holocene dust composition reveals heightened variability, with a prevalent contribution from Patagonia at ~50%. Post 11.5 kyr BP, as Puna-Altiplano experienced persistent aridity, our records demonstrate a noticeable increase in dust contribution. Leveraging a comprehensive coverage of both local and distal PSA, our statistical model, based on REE patterns, provides a straightforward and cost-effective method for tracing dust sources in ice cores.

Mineral dust aerosol concentrations in the atmosphere varied greatly on glacial–interglacial timescales. The greatest changes in global dust activity occurred in response to changes in orbital parameters (which affect dust emission intensity through glacial activity) and the lifetime of dust in the atmosphere (caused by changes in the global hydrological cycle). Long-term changes in the surface dust deposition rate are registered in geological archives such as loess, peats, lakes, marine sediments, and ice. Data provided by these archives are crucial for guiding simulations of dust and for better understanding the natural global dust cycle. However, the methods employed to derive paleo-dust deposition rates differ markedly between archives and are subject to different sources of uncertainty. Here, we present Paleo±Dust, an updated compilation of bulk and <10 µm paleo-dust deposition rates with quantitative 1σ uncertainties that are inter-comparable among archive types. Paleo±Dust incorporates a total of 285 pre-industrial Holocene (pi-HOL) and 209 Last Glacial Maximum (LGM) dust flux constraints from studies published until December 2022, including, for the first time, peat records. We also recalculate previously published dust fluxes to exclude data from the last deglaciation and thus obtain more representative constraints for the last pre-industrial interglacial and glacial end-member climate states. Based on Paleo±Dust, the global LGM:pi-HOL ratio of <10 µm dust deposition rates is 3.1 ± 0.7 (1σ). We expect Paleo±Dust to be of use for future paleoclimate dust studies and simulations using Earth system models of high to intermediate complexity. Paleo±Dust is publicly accessible at https://doi.org/10.1594/PANGAEA.962969 (Cosentino et al., 2024).

Antarctic ice cores have revealed the interplay between dust and climate in the Southern Hemisphere. Yet, so far, no continuous record of dust provenance has been established through the last deglaciation. Here, using a new database of 207 Rare Earth Element (REE) patterns measured in dust and sediments/soils from well-known potential source areas (PSA) of the Southern Hemisphere, we developed a statistical model combining those inputs to provide the best fit to the REE patterns measured in EPICA Dronning Maud Land (EDML) ice core (E. Antarctica). Out of 398 samples measured in the EDML core, 386 samples have been un-mixed with statistical significance. Combined with the total atmospheric deposition, we quantified the dust flux from each PSA to EDML between 7 and 27 kyr BP. Our results reveal that the dust composition was relatively uniform up until 14.5 kyr BP despite a large drop in atmospheric deposition at ∼18 kyr with a large contribution from Patagonia yielding ∼68 % of total dust deposition. The remaining dust was supplied from Australia (14-15 %), Southern Africa (∼9 %), New Zealand (∼3-4 %) and Puna-Altiplano (∼2-3 %). The most striking change occurred ∼14.5 kyr BP when Patagonia dropped below 50 % on average while low-latitude PSA increased their contributions to 21-23 % for Southern Africa, 13-21 % for Australia and ∼ 4-10 % for Puna-Altiplano. We argue that this shift is linked to long-lasting changes in the hydrology of Patagonian rivers and to sudden acceleration of the submersion of Patagonian shelf at 14.5 kyr BP, highlighting a relationship between dust composition and eustatic sea level. Early Holocene dust composition is highly variable, with Patagonian contribution being still prevalent, at ∼50 % on average. Provided a good coverage of local and distal PSA, our statistical model based on REE pattern offers a straightforward and cost-effective method to trace dust source in ice cores.

Savanna ecosystems were the landscapes for human evolution and are vital to modern Sub-Saharan African food security, yet the fundamental drivers of climate and ecology in these ecosystems remain unclear. Here we generate plant-wax isotope and dust flux records to explore the mechanistic drivers of the Northwest African monsoon, and to assess ecosystem responses to changes in monsoon rainfall and atmospheric pCO2. We show that monsoon rainfall is controlled by low-latitude insolation gradients and that while increases in precipitation are associated with expansion of grasslands into desert landscapes, changes in pCO2 predominantly drive the C3/C4 composition of savanna ecosystems.

Mineral dust deposition characteristics are poorly constrained, even in the Northeastern Tropical Atlantic Ocean, which is immediately downwind of the Saharan desert and the largest marine repository of aeolian dust in the world. Here, we report on a 2‐year (March 2013–February 2015) time series of deposited dust on the Senegalese margin. This record enables us to document the chemical variability (major elements) of the settling Saharan dust (<30 µm silicate fraction, i.e., carbonate‐free) at a resolution varying from one week to one day, along with the deposition flux. This continuous time series reveals a greater geochemical diversity than previously reported, particularly during the dry winter‐spring season when continental trade winds sweep across vast regions of West Africa at low atmospheric levels before reaching the sampling site. By contrast, during major deposition events, which make up for most of the yearly flux, our record shows that Saharan dust chemical composition displays much narrower ranges. Trajectory analyses indicate that these relatively well‐defined chemical signatures are due to the limited number of provenance sectors involved during major deposition occurrences. The chemical characterization of the dust deposited during these events, hence, allows identifying the major element fingerprint of the related source regions, the most important one being a sizable area at the border of Algeria and Mali including the Tanezrouft desert north of the Taoudeni basin. Also, since these major events are associated with major Saharan outbreaks, they provide estimations of the prevailing elemental signatures for Saharan dust impacting the Northeastern Tropical Atlantic Ocean.

Compositions of mineral dust in ice cores serve as tracers of paleo-atmospheric circulation patterns, providing linkages between sources and sinks. Here we document the geochemical makeup of dust reaching continental West Antarctica, on late Holocene samples from the Siple Dome A ice core (spanning -1030-1800 C.E). The Nd-Sr isotope signature is unusual for Antarctic ice core dust samples. Siple Dome data are characterized by low Nd isotope ratios (as low as epsilon Nd = -16.3) along with low Sr isotope ratios (highest Sr-87/Sr-86 = 0.7102) compared with other Antarctic dust signatures. A well-defined inverse correlation between Sr-Nd isotope ratios indicates two primary mixing sources. The low 8Nd-values indicate involvement of ancient (Archean-to-early Proterozoic) continental crust, as either the direct source or as a precursor of the source, and the low Sr-values require low Rb/Sr ratios that often reflect high-grade metamorphism. The known Antarctic terrane with these characteristics is parts of Enderby Land, nearly at the opposite end of Antarctica. The isotopic signature of the second end-member is compatible with West Antarctic volcanoes or Patagonia in South America. The Sr-Nd isotopes and trace element abundances are also chemically compatible with mixing between volcanic material from Gaussberg, a small lamproite volcano in Kaiser Wilhelm II Land in coastal East Antarctica whose source is ancient lithospheric mantle, with dust from Patagonia or material from West Antarctic volcanoes. We assess these potential mixing scenarios and conclude that Siple Dome's unusual geochemical signature can best be explained by a mixture of Patagonian dust and a Gaussberg-like source, with additional minor contributions from old eroded Archean-to-early Proterozoic bedrock sources such as those in Enderby Land. Moreover, Siple Dome dust compositions are distinct from dust deposited on Taylor and Clark Glaciers in the McMurdo Dry Valleys of the western Ross Sea, precluding the Dry Valleys as a late Holocene dust source to this region of the eastern Ross Sea. (C) 2021 Elsevier Ltd. All rights reserved.

On glacial to interglacial time scales, northern Africa fluctuated between arid to hyperarid states and much wetter conditions called African Humid Periods (AHP). These AHP are characterized by a major transformation of the Saharan hydrological cycle, favoring the development of vast fluvial networks, tropical flora and fauna in a region previously hyperarid. In the present-day context of global warming, it is crucial to understand the environmental mechanisms and responses associated with these dramatic swings between two extreme climatic states in order to improve the climatic projections. Numerous studies have been focused on the last AHP, which occurred at the beginning of the Holocene and corresponds to a period when insolation - governed by precession – and obliquity both reached their maximum almost synchronously, thus complicating the distinction of their respective roles. The study of older AHP corresponding to different orbital configurations is likely to provide some answers. However, finding climatic archives allowing the reconstruction of past changes in the Saharan hydrological cycle on longer timescales remains challenging (e.g., discontinuity of continental archives, preservation of tracers…). In this study, we propose to circumvent this difficulty by studying the Saharan dust deposited in marine sediments of the northeastern Atlantic tropical ocean. In fact, past modifications of Saharan dust deposited off West Africa can provide precious information on changes in environmental conditions in their source areas (aridity, weathering), as well as on changes in the characteristics of their atmospheric transport (pathways and strength). Here, we present a unique high-resolution (1 sample/200yrs) multi-proxy characterization of the dust deposited continuously through the last 240ka - a period punctuated by eight AHP - in the marine core MD03-2705 (18°05N; 21°09W; 3085 mbsl) retrieved from a bathymetric dome, 300 meters above the surrounding seafloor. Considering this particular environmental setting, the terrigenous fraction in this record is assumed to be predominantly of eolian origin. We combine the 230Th-normalized dust flux1 together with grain-size distribution, clay mineralogy and geochemical compositions in order to explore changes in the Saharan hydroclimate and atmospheric circulation over North Africa on millennial to orbital timescales, with a particular focus on the mechanisms associated with the recurrence of the AHP. 1Skonieczny et al., 2019 – Science Advances 5 (1) - eaav1887