The anisotropy of anhysteretic remanent magnetization (AARM) provides a powerful, nondestructive means of assessing magnetic fabrics. It is widely applied to infer strain and emplacement conditions in sedimentary, volcanic, and intrusive rocks. AARM is generally represented by a symmetric second-rank tensor describing its orientation, strength, and shape. AARM, however, departs from a tensorial shape when the number of grains carrying each directionally imparted anhysteretic remanence (ARM) varies with ARM orientation – a condition that arises when the alternating field (AF) over which the ARM is imparted does not fully activate the sample. Experimental data from a highly anisotropic ignimbrite sample, together with multiparticle modeling, show that such partial activation produces non-tensorial AARMs. Although this behavior complicates tensor analysis, non-tensorial AARM can reveal superimposed fabrics, provided that users can apply AF and ARM in a broad range of orientations. This article presents theoretical models that demonstrate non-tensorial behavior and explains how to utilize these properties to discern superimposed fabrics in natural samples.

Megathrust shear zones are the main fluid transport pathways during the seismic cycle and play a key role in controlling physicochemical alteration. Defining fluid-rock interaction in wall rocks provides evidence for unraveling the hydrogeology of shear zones and their link to active fluid circulation. We analyzed the variation in concentration, grain size and assemblages of magnetic minerals in the wall rocks of a shallow megathrust (the Sestola Vidiciatico shear zone) where no evidence of high-frictional heating has been recorded. The Sestola Vidiciatico shear zone preserves evidence of active fluid circulation and stress-switch during the last brittle phases of the Early to Middle Miocene subduction of the Adriatic plate beneath the frontal prism of the European plate. Magnetic properties indicate low bulk heat transfer during the seismic cycle. Changes in magnetic mineral concentrations highlight iron depletion from clay minerals and dissolution of iron-oxides for interaction with exotic fluids during the coseismic phase. The relative distribution of Fe-oxides and goethite suggests migration of Fe-enriched fluids along fractures during the coseismic/postseismic phase, followed by precipitation for interaction with local fluids. Subsequent alteration and weathering of magnetic minerals, accompanied by the formation of hematite and maghemite, are related to partial oxidation during the interseismic phase. Heterogeneity in magnetic mineral distribution supports active fluid circulation during repeated seismic events and/or exhumation. Rock magnetic characterization of wall rocks in exhumed megathrust represents a promising tool to better understand the role of fluid migration and redox conditions during seismic cycles in subduction zones.

The study of sedimentary magnetism in the intermontane Tarom Basin (northern Iran) offers insights into local paleoenvironmental conditions during global middle-late Miocene climate changes and the topographic growth triggered by the Arabia-Eurasia continental collision. Rock magnetic results reveal that the similar to 16.2 to similar to 10-9 Ma coarse-grained deposits at the basin's southern margin present a homogenous magnetic mineral assemblage, reflecting sediment provenance. Conversely, the similar to 13.2 to similar to 7.6 Ma, fine-grained deposits in the basin's depocenter include alternating playa-lake and lacustrine deposits, recording dry, evaporative conditions, leading to hematite formation in a low-temperature oxidizing environment, and wetter conditions that preserve the original detrital signal, respectively. Time series analyses show cyclicity in different period bands for magnetic susceptibility, but precession and obliquity cycles can hardly be resolved in the record. Comparison with deep-sea oxygen isotope data suggests that from similar to 13.2 to similar to 10.8 Ma environmental conditions likely mirrored global climatic forcing, with lacustrine and playa-lake deposits associated with increased and decreased global temperature, respectively. At similar to 10.8 Ma, the basin likely recorded the Tortonian Thermal Maximum with the establishment of a lacustrine system. From similar to 10.4 Ma, the magnetic susceptibility signal departed from the global climate record, possibly due to basin margin (western Alborz and Tarom mountains) and regional (Anatolian-Iranian plateau) topographic growth, accompanied by increased precipitation seasonality, focused rainfall and augmented erosion rates. Finally, we suggest that before similar to 10.8 Ma, the Hadley cells expanded northward, leading to a trade-dominated system with moist air masses sourced from the Caspian, while from similar to 10.8 Ma, westerlies dominance progressively prevailed.

AbstractHigh‐temperature Raman spectroscopy offers a cost‐effective alternative to extensive infrastructure and sensitive instrumentation for investigating nanolite crystallization in undercooled volcanic melts, a key area of interest in volcanology. This study examined nanolite formation in anhydrous andesite melts in situ at high temperatures, identifying distinct Raman peaks at 310 and 670 cm−1 appearing above the glass transition temperature. The initial amorphous glass remained stable up to 655°C, beyond which Fe‐Ti‐oxide nanolites progressively formed at higher temperatures, as also confirmed by complementary XRD analysis. The evolution of the 310 cm−1 peak depends only on the magnitude of nanolite crystallization, while the intensity of the 670 cm−1 peak is temperature‐dependent and challenging to observe above 500°C. Complementary low‐temperature rock‐magnetic analyses confirmed Fe‐Ti‐oxide nanocrystallization with nanolites around 20 nm in diameter. The study tested lasers of different wavelengths (from 355 to 514 nm) and found the green laser to be the most effective for collecting spectra at both room and high temperature. However, above 720°C, black body radiation significantly hinders Raman observation with the green laser when using a non‐confocal setup and analyzing poorly transparent samples. If higher temperature measurements are desired, switching to a confocal setup and using lower wavelength lasers should be considered. This research offers a protocol for studying nanolite formation and melt dynamics at high temperatures, providing a foundation for future studies of volcanic processes.

The past similar to 200 million years of Earth's geomagnetic field behavior have been recorded within oceanic basalts, many of which are only accessible via scientific ocean drilling. Obtaining the best possible paleomagnetic measurements from such valuable samples requires an a priori understanding of their magnetic mineralogies when choosing the most appropriate protocol for stepwise demagnetization experiments (either alternating field or thermal). Here, we present a quick, and non-destructive method that utilizes the amplitude-dependence of magnetic susceptibility to screen submarine basalts prior to choosing a demagnetization protocol, whenever conducting a pilot study or other detailed rock-magnetic characterization is not possible. We demonstrate this method using samples acquired during International Ocean Discovery Program Expedition 391. Our approach is rooted in the observation that amplitude-dependent magnetic susceptibility is observed in basalt samples whose dominant magnetic carrier is multidomain titanomagnetite (similar to TM60-65, (Ti0.60-0.65Fe0.35-0.40)Fe2O4). Samples with low Ti contents within titanomagnetite or samples that have experienced a high degree of oxidative weathering do not display appreciable amplitude dependence. Due to their low Curie temperatures, basalts that possess amplitude-dependence should ideally be demagnetized either using alternating fields or via finely-spaced thermal demagnetization heating steps below 300 degrees C. Our screening method can enhance the success rate of paleomagnetic studies of oceanic basalt samples. Oceanic basalts are ideal recorders of the Earth's magnetic field. To decipher magnetic histories recorded in rocks, paleomagnetists need to isolate the magnetization directions and intensities within rocks by one of two possible methods. One method typically involves progressively heating the samples to high temperatures. The other method involves exposing samples to alternating magnetic fields with increasing peak field intensities. Both of these methods are ultimately destructive to the original magnetization preserved within rocks. However, without knowledge of a given rock's magnetic mineralogy, randomly choosing thermal or alternating field demagnetization methods may result in high failure rates. We developed a pre-screening method to help decide which cleaning method will likely be more successful for a given sample based on low-field magnetic susceptibility measurements. These measurements do not affect the original magnetic information recorded in a rock, thereby permitting subsequent paleomagnetic studies on the same sample. Our technique can be performed as rapidly as 2 min per sample, is non-destructive, and does not require complicated sample preparation. Paleomagnetic studies utilize either alternating field or thermal demagnetization, but it is difficult to choose the best protocol a priori Amplitude-dependence of magnetic susceptibility measurements permits preliminary magnetic mineralogy characterization in submarine basalts Rapid amplitude-dependence measurements may aid in deciding upon the best demagnetization protocol for submarine basalt samples

The Paleocene lavas from Dianzhong Formation (E 1 d) in Linzhou basin of southern Lhasa terrane are a key target for paleomagnetic investigations into the timing and paleolatitude of the initial India‐Asia collision. Controversy exists, however, on whether these rocks preserve a primary remanent magnetization. Here we reanalyze previously published thermal demagnetization data and report detailed rock magnetic results and petrographic observations of these rocks. We find that the original magnetic carrier, a magmatic multidomain Ti‐poor titanomagnetite, underwent significant grain size reduction and was variably reacted to single‐domain maghemite and nano‐hematite. Such strong alteration may have resulted from successive hydrothermal events: a first event related to the ∼52 Ma dike intrusions into the E 1 d that accompanied a massive ignimbrite eruption deposited above the E 1 d producing heating up to 300°C; and a secondary event related to the 42–27 Ma southward overthrusting of the basin, heating the E 1 d up to 130–145°C. Unblocking/inversion temperature spectra of the authigenic maghemite and nano‐hematite overlap with those of the titanomagnetite, implying that the primary remanence of the E 1 d lavas has been contaminated or replaced by thermoviscous and chemical remanent magnetizations. Thus the isolated characteristic remanent magnetization from these rocks, whether slightly or completely altered, cannot be considered primary and should not be used for paleolatitudinal determination. Our study confirms that hydrothermal alteration can seriously jeopardize the remanence carried by titanomagnetite and thus should be tested for paleomagnetic investigations of rock units from tectonically active areas.

SUMMARY A detailed rock magnetic study was conducted on ash samples collected from different products erupted during explosive activity of Mount Etna, Italy, in order to test the use of magnetic properties as discriminating factors among them, and their explosive character in particular. Samples include tephra emplaced during the last 18 ka: the benmoreitic Plinian eruptions of the Pleistocene Ellittico activity from marine core ET97-70 (Ionian Sea) and the basaltic Holocene FG eruption (122 BC), the Strombolian/Phreatomagmatic/sub-Plinian eruptions (namely, the Holocene TV, FS, FL, ETP products and the 1990, 1998 eruptions) collected from the slope of the volcano, and the Recent explosive activity (lava fountains referred to as ‘Ash Rich Jets and Plumes’, or ARJP) that occurred in the 2001–2002 period, related to flank eruptions. Mössbauer spectrometry informs that a single magnetic mineral dominates the three groups, which are characterized by variable magnetic grain sizes and composition. Detailed rock-magnetic investigations, ranging from low temperature to high temperature remanence and susceptibility experiments, indicate that the more explosive products of the Plinian eruptions and ARJP activity tephra, are characterized by oxidized Ti-rich titanomagnetites, with dominant Curie Temperatures between 230 and 330 °C. The FG and ARJP tephra are also characterized by contrasting, yet overall higher, coercivity distributions and higher magnetizations and susceptibilities, including below room temperature. In contrast, most of the Strombolian/sub-Plinian eruptions have a magnetic signature dominated by less coercive magnetite and/or Ti-poor titanomagnetite. Magnetic differences observed between the Late Pleistocene and Holocene FG Plinian eruptions can be attributed to the different composition of the former eruptions, which were fed by more evolved magmas, whereas geochemical variations characterizing the products erupted in the last few decades can be responsible for the differences between the Holocene and recent Strombolian/sub-Plinian products. Importantly, detailed magnetic investigation of sideromelane and tachylite clasts, the two end members of the juvenile fraction extracted from the ash of the most explosive products, determines that the tachylite fraction is responsible for the magnetic signature of the Plinian FG and ARJP tephra, and is attributed to the intense fragmentation that characterizes these activities, likely resulting from undercooling processes. Moreover, the abundant superparamagnetic grains associated with these eruptive styles are believed to represent the nanolite fraction responsible for the increasing viscosity of these magmas, and to be responsible for their explosive character. The distinctive magnetic properties that characterize the tachylite-bearing tephra, representative of the fragmentation process that distinguishes the most explosive activities, provides a useful magnetic tool that can complement traditional volcanological investigations.

South American Jurassic/Cretaceous rocks has been troubled by elongated virtual geomagnetic pole (VGP) distributions, while many discordant poles from the Carboniferous to the Triassic have also been recognized, rendering the South American apparent polar wonder path (APWP) problematic. We have conducted a paleomagnetic study of the sedimentary Permo-Carboniferous Itararé Group rocks within the state of São Paulo, Brazil, including three intruding mafic sills that are attributed to Early Cretaceus magmatic activity. The site-mean VGP distributions obtained from the sedimentary rocks define elongations that include the VGPs of the mafic intrusions, and are interpreted as remagnetization paths toward the directions characteristic of the sills. These interpretations are supported by extensive rock-magnetic data that provide a viable mechanism for the secondary magnetizations. Careful analysis of the paleomagnetic data of the sedimentary rocks enables isolation of a primary VGP distribution that is consistent with the reference Carboniferous pole position. Analysis of other Carboniferous to Triassic South American paleomagnetic VGPs reveals that the majority of these data are also elongated: regardless of the age of the rocks, the elongations dominantly intersect at the location of the Late Cretaceous reference pole, and a second location similar to the intersection of the VGP elongations of some Jurassic/Cretaceous rock formations, and also coincides with the cusp of the debated loop in the Carboniferous-Triassic APWP. Based on multiple lines of evidence, we interpret the elongations and their intersections to reflect remagnetizations that occurred as a result of the widespread magmatism associated with the opening of the South Atlantic. We suggest that the extent of the remagnetizations is formation-specific, and that other rock-formations should be carefully re-evaluated.

Devastating seismic events occur mainly in subduction zones, and a significant percentage of them are intraslab earthquakes. The geologic record of these events holds valuable information that needs to be investigated for a comprehensive seismic risk assessment. Here we investigate pseudotachylytes formed in oceanic peridotites and that are interpreted to result from intraslab seismic rupture. Each vein has recorded the seismic slip direction and slip sense of a single coseismic shear‐heating event. The well‐preserved exposures, showing individual veins up to 7 m in length and about 3 cm in width, of Cima di Gratera, in the Schistes Lustrés ophiolitic units of Corsica, offer unparalleled opportunities to investigate intraslab rupture kinematics in mantle rocks. The principal ferromagnetic phase in these rocks is a Ti‐poor magnetite. We use the anisotropy of magnetic susceptibility (AMS) recorded in pseudotachylyte generation veins (bulk susceptibilities range from 600 to 20,000 × 10 −6 [SI] volume, with P ′ ranging from 1.05 to 2.5) to reconstruct the co‐seismic deformation parameters, that is, fault plane attitude, direction and sense of slip. These new results, internally consistent at the vein level, span across oblate and prolate symmetries and reveal that seismic deformation recorded in these veins was kinematically diverse and included mostly normal mechanisms acting along the same subduction zone. In addition, our investigations show that the magnetic fabric of peridotite‐hosted pseudotachylytes provides key information bearing on the complex dynamics of frictional melts at a unprecedently high spatial resolution.

The upper plate of the Arabia-Eurasia collision zone experienced orogen-perpendicular to orogen-parallel extension from 25-22 to 10-9 Ma. Although such an extension occurred during widespread collisional deformation, it is not clear if it is a local feature or if represents a major phase of upper plate extension. In this study we combine anisotropy of magnetic susceptibility (AMS) with fault kinematic analysis and sedimentologic data from 16.2- to 7.6-My-old deposits of the Upper Red Formation of the intermontane Tarom Basin (NW Iran). These strata present syndepositional, normal faults and offer the possibility to gain new insights into the spatial extent of such a Miocene extension. AMS data from the central and northern sectors of the basin document a tectonic fabric with a magnetic lineation parallel to the strike of the orogen, suggesting a compressional tectonic overprint. Conversely, the southern margin of the basin presents a purely sedimentary magnetic fabric despite a similar to NE-SW orogen-perpendicular extension. This suggests that basin formation was not driven by extensional tectonics. Rather, the normal faults are gravity instabilities induced as also documented by coeval landslide deposits. This allows concluding that the orogen-perpendicular extension observed in few sectors of the collision zone is not regionally pervasive and hence it is not controlled by large-scale processes. Combined, our results indicate that if orogen-parallel extension associated with tectonic denudation and metamorphic core complex development occurred in certain sectors of the collision zone (Takab complex), it must have ended before 19-16 Ma, when widespread upper plate contractional deformation started.

Titanomagnetites in mid‐ocean ridge basalt (MORB) experience variable post crystallization alterations associated with seafloor tectonic and environmental processes. Compared to low‐temperature oxidation, seafloor hydrothermal alteration is thought to be more destructive but its magnetic aftermaths are insufficiently documented. Here we present comprehensive rock magnetic and electron microscopic analyses of fresh and hydrothermally‐altered MORBs dredged from the Longqi and Yuhuang hydrothermal fields, Southwest Indian Ridge. We observe large variations in magnetic properties of fresh MORBs, originated from relative proportions of nano‐scale single‐domain to vortex state and micron‐scale vortex to multi‐domain state dendritic titanomagnetites. Progressive hydrothermal alteration produces secondary magnetite through recrystallization of exsolved and dissolved Fe from primary titanomagnetite. Exsolution is evident by a dual Verwey transition signature and coexisting Ti‐poor titanomagnetites and sphenes in partially chloritized basalts. A schematic model is proposed to explain the variations in magnetomineralogy and magnetic properties with progressive hydrothermal alteration. Intermediate hydrothermal alteration products retain a secondary chemical remanent magnetization (CRM) which is related to the long‐term magnetization variations in oceanic basalts. The established framework allows characterizing MORB hydrothermal alteration and ultimately contributes to resolving the complexity of seafloor magnetism.

Abstract Sedimentary rocks of the Itararé Group, deposited during the Late Paleozoic Ice Age in the Paraná Basin of South America, were collected throughout the state of São Paulo, Brazil, for an anisotropy of magnetic susceptibility (AMS) and rock‐magnetic study. A recent paleomagnetic study conducted on the same samples had determined that these rocks were largely remagnetized during the Cretaceous; however, rock‐magnetic experiments demonstrate that the AMS is dominantly carried by paramagnetic minerals and therefore is unaffected by the secondary magnetic overprints. AMS data are analyzed in terms of their shape and orientation, and according to the relationship between the q‐value (magnetic lineation/foliation) and the imbrication angle (β) of the minimum susceptibility axes with respect to bedding (q–β diagram). Using multiple lines of evidence, we demonstrate that AMS records primary sedimentary fabrics that reflect the depositional environments and paleocurrent conditions in which these rocks were deposited. The magnetic fabrics consistently record a SE‐NW paleocurrent orientation, with dominant direction of transport to the NW throughout the entire state of São Paulo, in agreement with ice flow and sediment transport directions reported from limited numbers of sites possessing sedimentary structures and ice‐kinematic indicators.

IMPLICATIONS FOR THE STRUCTURE OF THE SOLAR NEBULA R.R. Fu1, M.W.R. Volk1, Dario Bilardello2, Guy Libourel3,4, Geoffroy Lesur5, and Oren Ben Dor1,6 1Department of Earth and Planetary Sciences, Harvard University, Cambridge, MA USA. 2Department of Earth and Environmental Sciences, University of Minnesota, Minneapolis, MN, USA. 3Université Côte d'Azur, Observatoire de la Côte d’Azur, CNRS, Lagrange, Nice, France. 4Hawai’i Institute of Geophysics and Planetology, University of Hawai’i at Manoa, Honolulu, HI, USA. 5Univ. Grenoble Alpes, CNRS, IPAG, 38000 Grenoble, France. 6Department of Physics, Harvard University, Cambridge, MA, USA. (rogerfu@fas.harvard.edu).

Abstract Magnetic fields in the early solar system may have driven the inward accretion of the protoplanetary disk (PPD) and generated instabilities that led to the formation of planets and ring and gap structures. The Allende carbonaceous chondrite meteorite records a strong early solar system magnetic field that has been interpreted to have a PPD, dynamo, or impact‐generated origin. Using high‐resolution magnetic field imaging to isolate the magnetization of individual grain assemblages, we find that only Fe‐sulfides carry a coherent magnetization. Combined with rock magnetic analyses, we conclude that Allende carries a magnetization acquired during parent body chemical alteration at ~3.0–4.2 My after calcium aluminum‐rich inclusions in an >40 µT magnetic field. This early age strongly favors a magnetic field of nebular origin instead of dynamo or solar wind alternatives. When compared to other paleomagnetic data from meteorites, this strong intensity supports a central role for magnetic instabilities in disk accretion and the presence of temporal variations or spatial heterogeneities in the disk, such as ring and gap structures.

AbstractWe present new results on the conversion of pure, undoped synthetic ferrihydrite, wet‐annealed at pH 6.56 and 90°C without stabilizing ligands, to nanophase goethite, hematite, and an intermediate magnetic phase, nanophase maghemite. Our analyses included magnetic field and temperature‐dependent properties and characterization by powder X‐ray diffraction, Mössbauer spectra, and high‐resolution transmission electron microscopy. We sampled alteration products after 0.5 hr, and then in a geometric progression to 32 hr, yielding a detailed examination of the earliest alteration phases. There are many similarities to the latest studies of pure ferrihydrite alteration but with a significant difference: We observe early appearance of oriented nanophase goethite along with a soft magnetic contribution, while rhombohedral hematite crystals form later, as reported in previous studies. Our observations attest to the non‐uniqueness of the magnetic enhancement process and to its strong dependence on environmental conditions, with important implications for use of the hematite/goethite ratio as a paleoprecipitation proxy.

Magnetic, pXRD and Mossbauer metadata used in the cited study on alteration of synthetic ferrihydrite. All magnetic data was collected at the Institute for Rock Magnetism on a Quantum Design MPMS and comprises magnetic susceptibility (in-phase and out-of-phase) as a function of temperature (10-300K) and frequency (1-1000 Hz), hysteresis loops measured at 5K and 300 K, and magnetic remanence data (pTRM, temperature and AF demagnetized, the goethetite test) collected between 400 and 10 K.

One of the best magneto-optical claddings for optical isolators in photonic integrated circuits is sputter deposited cerium-doped terbium iron garnet (Ce:TbIG) which has a large Faraday rotation (approximate to-3500 degrees cm(-1) at 1550 nm). Near-ideal stoichiometry Ce + TbFe = 0.57 of Ce0.5Tb2.5Fe4.75O12 is found to have a 44 nm magnetic dead layer that can impede the interaction of propagating modes with garnet claddings. The effective anisotropy of Ce:TbIG on Si is also important, but calculations using bulk thermal mismatch overestimate the effective anisotropy. Here, X-ray diffraction measurements yield highly accurate measurements of strain that show anisotropy favors an in-plane magnetization in agreement with the positive magnetostriction of Ce:TbIG. Upon doping TbIG with Ce, a slight decrease in compensation temperature occurs which points to preferential rare-earth occupation in dodecahedral sites and an absence of cation redistribution between different lattice sites. The high Faraday rotation, large remanent ratio, large coercivity, and preferential in-plane magnetization enable Ce:TbIG to be an in-plane latched garnet, immune to stray fields with magnetization collinear to direction of light propagation.

Magnetic fabrics are powerful tools in structural geology and tectonic studies, because they provide a fast and efficient measurement of mineral alignment, which helps interpret a rock's (de)formation history. The magnetic fabric of remanence‐carrying minerals provides useful information when these grains record different deformation stages than the bulk minerals in a rock. When rocks contain several subpopulations of remanence‐carrying minerals, each of these potentially displays a distinct fabric. This can lead to complex remanence anisotropies, being a superposition of all subpopulations' individual anisotropies. Characterization of partial remanence anisotropies has been used to investigate changes in fabric with grain size. However, most studies still report one bulk remanence anisotropy tensor per sample, and it remains to be determined how commonly different populations of remanence‐carrying grains reflect different subfabrics. Based on a large sample collection including 93 specimens from different lithologies, we have investigated the coercivity dependence of anisotropy of (partial) anhysteretic remanent magnetization A(p)ARM. We find that the principal directions, degree, and shape of A(p)ARM are generally dependent on the coercivity window used to impart the anhysteretic remanent magnetizations (ARMs). Depending on the carrier minerals and their fabrics, ARM anisotropy can either increase or decrease when the ARMs are applied over larger coercivity windows. Additionally, the coercivity fraction that dominates the ARM anisotropy is not always the coercivity fraction that acquires the strongest mean ARM. This illustrates the complexity of characterizing remanence anisotropy, and highlights the importance of carefully choosing experimental parameters in A(p)ARM determination for both magnetic fabric and anisotropy correction studies.