Silver electrodes which require no supporting grid and have a porosity graded structure were fabricated by combining silver powder of uniform mesh size with a plasticizer and pore forming additives. The proportions of these materials are selected to give a uniform doughlike mixture which is rolled and then sintered. Porosity control is achieved by controlled decomposition of the plasticizer and pore forming additives. Multilayered graded porosity electrodes are assembled by a combination of sintering and compaction. Performance data based on cycling tests and coulombic efficiencies demonstrated that these electrodes are comparable to conventional silver electrodes and the absence of the grid is not a limiting factor.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory of Stationary Electrode Polarography for a Multistep Charge Transfer with Catalytic (Cyclic) Regeneration of the Reactant.D. S. Polcyn and Irving. ShainCite this: Anal. Chem. 1966, 38, 3, 376–382Publication Date (Print):March 1, 1966Publication History Published online1 May 2002Published inissue 1 March 1966https://pubs.acs.org/doi/10.1021/ac60235a003https://doi.org/10.1021/ac60235a003research-articleACS PublicationsRequest reuse permissionsArticle Views320Altmetric-Citations55LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMultistep Charge Transfers in Stationary Electrode Polarography.D. S. Polcyn and Irving. ShainCite this: Anal. Chem. 1966, 38, 3, 370–375Publication Date (Print):March 1, 1966Publication History Published online1 May 2002Published inissue 1 March 1966https://pubs.acs.org/doi/10.1021/ac60235a002https://doi.org/10.1021/ac60235a002research-articleACS PublicationsRequest reuse permissionsArticle Views737Altmetric-Citations232LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTELECTROLYSIS WITH CONSTANT POTENTIAL: EFFECT OF DIFFUSION COEFFICIENTS ON REVERSIBLE REACTIONS AT A SPHERICAL ELECTRODEIrving Shain and Daniel S. PolcynCite this: J. Phys. Chem. 1961, 65, 9, 1649–1651Publication Date (Print):September 1, 1961Publication History Published online1 May 2002Published inissue 1 September 1961https://pubs.acs.org/doi/10.1021/j100905a517https://doi.org/10.1021/j100905a517research-articleACS PublicationsRequest reuse permissionsArticle Views46Altmetric-Citations5LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts