ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCyclic voltammetric studies of the pH dependence of copper(II) reduction in acidic aqueous nitrate and perchlorate solutionsJames L. Anderson and Irving. ShainCite this: Anal. Chem. 1976, 48, 9, 1274–1282Publication Date (Print):August 1, 1976Publication History Published online1 May 2002Published inissue 1 August 1976https://pubs.acs.org/doi/10.1021/ac50003a007https://doi.org/10.1021/ac50003a007research-articleACS PublicationsRequest reuse permissionsArticle Views601Altmetric-Citations26LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRate-controlled adsorption of product in stationary electrode polarographyMatthew H. Hulbert and Irving. ShainCite this: Anal. Chem. 1970, 42, 2, 162–171Publication Date (Print):February 1, 1970Publication History Published online1 May 2002Published inissue 1 February 1970https://doi.org/10.1021/ac60284a020RIGHTS & PERMISSIONSArticle Views182Altmetric-Citations52LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (997 KB) Get e-Alerts Get e-Alerts

AbstractDie Theorie der Polarographie mit stationärer Elektrode wird in bezug auf das System Oxidationsstufe + ne ⇌ Reduktionsstufe ⇌ Reduktionsstufe (ads), in dem auf die reversible Ladungsübertragung eine geschwindigkeitskontrollierte Adsorption‐Desorption des Produkts der Elektrodenreaktion folgt, betrachtet.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudy of the chemical reaction preceding reduction of cadmium nitrilotriacetic acid complexes using stationary electrode polarographyMark S. Shuman and Irving. ShainCite this: Anal. Chem. 1969, 41, 13, 1818–1825Publication Date (Print):November 1, 1969Publication History Published online1 May 2002Published inissue 1 November 1969https://pubs.acs.org/doi/10.1021/ac60282a015https://doi.org/10.1021/ac60282a015research-articleACS PublicationsRequest reuse permissionsArticle Views86Altmetric-Citations35LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

SUMMARY Solid-state operational amplifiers, a diode gate, and flip-flop circuits have been used to construct a versatile signal generator for electroanalytical experiments, especially cyclic voltammetry. The unit produces ramp and hold signals, single-cycle triangular waves, and multicycle triangular waves, with independently selectable initial potential, anodic and cathodic limit potentials, and hold potential. The scan rates available range from 0.2 mV/sec to 1000 V/sec.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffects of adsorption of electroactive species in stationary electrode polarographyRobert H. Wopschall and Irving. ShainCite this: Anal. Chem. 1967, 39, 13, 1514–1527Publication Date (Print):November 1, 1967Publication History Published online1 May 2002Published inissue 1 November 1967https://pubs.acs.org/doi/10.1021/ac50156a018https://doi.org/10.1021/ac50156a018research-articleACS PublicationsRequest reuse permissionsArticle Views1939Altmetric-Citations600LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption characteristics of the methylene blue system using stationary electrode polarographyRobert H. Wopschall and Irving. ShainCite this: Anal. Chem. 1967, 39, 13, 1527–1534Publication Date (Print):November 1, 1967Publication History Published online1 May 2002Published inissue 1 November 1967https://pubs.acs.org/doi/10.1021/ac50156a019https://doi.org/10.1021/ac50156a019research-articleACS PublicationsRequest reuse permissionsArticle Views751Altmetric-Citations104LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption effects in stationary electrode polarography with a chemical reaction following charge transferRobert H. Wopschall and Irving. ShainCite this: Anal. Chem. 1967, 39, 13, 1535–1542Publication Date (Print):November 1, 1967Publication History Published online1 May 2002Published inissue 1 November 1967https://pubs.acs.org/doi/10.1021/ac50156a020https://doi.org/10.1021/ac50156a020research-articleACS PublicationsRequest reuse permissionsArticle Views397Altmetric-Citations87LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

Stripping analysis techniques were extended to the study of mixed Co-Zn amalgams in hanging mercury drop electrodes. The composition of the intermetallic compound and the equilibria- involved in the amalgam phase were investigated. Rapid and convenient methods were developed using data from anodic stationary electrode polarograms of the mixed amalgams. The results confirmed previous work, and indicated that the intermetallic compound is CoZn, in equilibrium with Co2 and Zn2 with K = [Co2]/[Zn2].[CoZn]2 = 2 (Rel. S.D., 20%).

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory of Stationary Electrode Polarography for a Multistep Charge Transfer with Catalytic (Cyclic) Regeneration of the Reactant.D. S. Polcyn and Irving. ShainCite this: Anal. Chem. 1966, 38, 3, 376–382Publication Date (Print):March 1, 1966Publication History Published online1 May 2002Published inissue 1 March 1966https://pubs.acs.org/doi/10.1021/ac60235a003https://doi.org/10.1021/ac60235a003research-articleACS PublicationsRequest reuse permissionsArticle Views320Altmetric-Citations55LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

The electroreduction of cobalt (II) from solutions containing pyridine was investigated with stationary electrode polarography at a hanging mercury drop electrode using both single-scan and cyclic experiments. Scan rates ranged from 50 mVsec to 110 Vsec, and from the variation of the peak potential and the peak current function, ip/Vv, (where ip is the peak current, and v the rate of voltage scan) with scan rate, the reduction appeared to involve a reversible charge transfer followed by an extremely rapid chemical reaction in the amalgam to form a species not electroactive in the same potential range. This product appears to be a dimer or higher cobalt aggregate dissolved in the mercury. It is reoxidized at a potential about 1 V anodic of the reduction wave. This irreversible anodic wave was made the basis of a stripping analysis procedure for the determination of trace quantities of cobalt.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMultistep Charge Transfers in Stationary Electrode Polarography.D. S. Polcyn and Irving. ShainCite this: Anal. Chem. 1966, 38, 3, 370–375Publication Date (Print):March 1, 1966Publication History Published online1 May 2002Published inissue 1 March 1966https://pubs.acs.org/doi/10.1021/ac60235a002https://doi.org/10.1021/ac60235a002research-articleACS PublicationsRequest reuse permissionsArticle Views737Altmetric-Citations232LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrolysis with Constant Potential. Diffusion Currents for the Formation of an Amalgam at a Hanging Mercury Drop Electrode.W. G. Stevens and Irving. ShainCite this: Anal. Chem. 1966, 38, 7, 865–867Publication Date (Print):June 1, 1966Publication History Published online1 May 2002Published inissue 1 June 1966https://pubs.acs.org/doi/10.1021/ac60239a017https://doi.org/10.1021/ac60239a017research-articleACS PublicationsRequest reuse permissionsArticle Views64Altmetric-Citations12LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrolysis with Constant Potential. Diffusion Currents of Metal Species Dissolved in Spherical Mercury ElectrodesWilliam G. Stevens and Irving ShainCite this: J. Phys. Chem. 1966, 70, 7, 2276–2280Publication Date (Print):July 1, 1966Publication History Published online1 May 2002Published inissue 1 July 1966https://doi.org/10.1021/j100879a032RIGHTS & PERMISSIONSArticle Views60Altmetric-Citations23LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (477 KB) Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrode Potential Gradients and Cell Design in Controlled Potential Electrolysis Experiments.J. E. Harrar and Irving. ShainCite this: Anal. Chem. 1966, 38, 9, 1148–1158Publication Date (Print):August 1, 1966Publication History Published online1 May 2002Published inissue 1 August 1966https://doi.org/10.1021/ac60241a008Request reuse permissionsArticle Views455Altmetric-Citations23LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExperimental Verification of an ECE Mechanism for the Reduction of p-Nitrosophenol, Using Stationary Electrode Polarography.R. S. Nicholson and Irving. ShainCite this: Anal. Chem. 1965, 37, 2, 190–195Publication Date (Print):February 1, 1965Publication History Published online1 May 2002Published inissue 1 February 1965https://pubs.acs.org/doi/10.1021/ac60221a003https://doi.org/10.1021/ac60221a003research-articleACS PublicationsRequest reuse permissionsArticle Views1016Altmetric-Citations128LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSimplified Use of Transfer Functions in Analysis of Operational Amplifier Electroanalytical InstrumentationIrving. Shain, Jackson E. Harrar, and Glenn L. BoomanCite this: Anal. Chem. 1965, 37, 13, 1768–1769Publication Date (Print):December 1, 1965Publication History Published online1 May 2002Published inissue 1 December 1965https://pubs.acs.org/doi/10.1021/ac60232a038https://doi.org/10.1021/ac60232a038research-articleACS PublicationsRequest reuse permissionsArticle Views57Altmetric-Citations4LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts