Long-wavelength neutron interferometry using discrete optical elements is notoriously challenging due to stringent alignment and stability requirements. Here, we introduce a monolithic double-Laue neutron interferometer fabricated from a stack of commercial Bayfol HX photopolymer films. By recording holographic gratings simultaneously in multiple layers, we create a robust device that is inherently aligned, bypassing traditional stability problems. We demonstrate the device's function by observing the characteristic interference fringes in the diffracted intensity of both light and very cold neutrons. The interferometer is then used to perform in-situ characterization of the neutron beam's spectral profile, demonstrating its utility as a compact spectrometer. Our work establishes stacked holographic gratings as a simple, versatile, and powerful platform for matter-wave interferometry and metrology.

Nanoparticle-polymer composite gratings incorporating ultrahigh-refractive-index hyperbranched polymers as organic nanoparticles have demonstrated exceptional light optical properties, yet their potential for neutron diffraction applications remains unexplored. We report on the neutron optical properties of a holographically structured hyperbranched-polymer-dispersed nanocomposite grating at a quasi-monochromatic neutron wavelength of 2 nm. We show that neutron diffraction measurements performed at the SANS-I instrument of the Paul Scherrer Institute (Switzerland) reveal exceptionally high neutron scattering length density modulation amplitudes. These scattering length density modulation amplitudes are the highest reported to date. Very high neutron diffraction efficiency is expected with the use of thicker uniform gratings and longer neutron wavelengths, with low angular and wavelength selectivity constraints.

Photosensitive materials with ever-improving properties are of great importance for optical and photonics applications. Additionally, they are extremely useful for designing components for neutron optical devices. We provide an overview on materials that have been tested and successfully used to control beams of cold and very cold neutrons based on diffractive elements. Artificial gratings are generated and optimized for the specific application in mind. We discuss the needs of the neutron optics community and highlight the progress obtained during the last decade. Materials that have been employed so far along with their properties are summarized, outlining the most promising candidates for the construction of an interferometer for very cold neutrons.

We demonstrate exceptionally high slow-neutron diffraction efficiency (≈ 70% of transmitted intensity diffracted to the first order) from a holographic nanodiamond–polymer composite grating of only tens of micrometers thickness at the average neutron wavelength of 5.3 nm. By meticulous choice of materials for extreme refractive index modulation in a thin grating structure, we overcome typical wavelength and angular selectivity issues usually encountered when pursuing high diffraction efficiencies with a thick grating. This achievement paves the way for the implementation of flux-efficient diffractive elements, well-suited for polychromatic beams, and weakly collimated slow-neutron beams.

Ferromagnetic ferrofluids are synthetic materials consisting of magnetic nanoplatelets dispersed in an isotropic fluid. Their main characteristics are the formation of stable magnetic domains and the presence of macroscopic magnetization even in the absence of a magnetic field. Here, the authors report on the experimental observation of spontaneous stripe formation in a ferromagnetic ferrofluid in the presence of an oscillating external magnetic field. The striped structure is identified as elongated magnetic domains, which exhibit reorientation upon reversal of the magnetic field. The stripes are oriented perpendicular to the magnetic field and are separated by alternating flow lanes. The velocity profile is measured using a space-time correlation technique that follows the motion of the thermally excited fluctuations in the sample. The highest velocities are found in the depleted regions between individual domains and reach values up to several µm s-1 . The fluid in adjacent lanes moves in the opposite directions despite the applied magnetic field being uniform. The formation of bidirectional flow lanes can be explained by alternating rotation of magnetic nanoparticles in neighboring stripes, which indicates spontaneous breaking of the chiral symmetry in the sample.

During the last decade a number of volume holographic media have been investigated that could serve not only as diffractive optical elements (DOEs) for light but also for slow neutrons. In this contribution we discuss the light optical properties of a stack of two gratings separated by an optically inert slice recorded in a Bayfol HX photopolymer. While the refractive-index modulation of the gratings for light is remarkable, the corresponding neutron optical analogue is, so far, in the medium range of other materials investigated. We therefore aim at possible improvements which are discussed in this manuscript.

We report our latest results on holographic gratings based on nanoparticle-polymer composites (NPC) including nanodiamonds with large refractive index modulation amplitude for cold and very cold neutrons (1 nm < λ < 10 nm). Diamond has the best combined neutron optical properties: high coherent scattering length, low incoherent scattering and low absorption. These unique properties allowed us to create phase gratings with large refractive index modulation, high thermal and mechanical stability, and also exhibiting large area holograms compared to NPC gratings incorporating other types of nanoparticles. We discuss the measured light and neutron diffraction properties of nanodiamond NPC gratings. It is shown that the NPC gratings exhibit extremely large scattering length density modulation amplitudes and as a result high diffraction efficiencies for cold and very-cold neutrons. We also discuss possible applications of nanodiamond NPC gratings in neutron optics.

We experimentally characterize the positions of the diffraction maxima of a phase grating on a screen, for laser light at oblique incidence (so-called off-plane diffraction or conical diffraction). We discuss the general case of off-plane diffraction geometries and derive basic equations for the positions of the diffraction maxima, in particular for their angular dependence. In contrast to previously reported work (Jetty et al. in Am J Phys 80:972, 2012), our reasoning is solely based on energy- and momentum conservation. We find good agreement of our theoretical prediction with the experiment. A detailed discussion of the diffraction maxima positions, the number of diffraction orders, and the diffraction efficiencies is provided. We assess the feasibility of an experimental test of the phenomenon for neutron matter waves.

We experimentally demonstrate how to accurately retrieve the refractive index profile of photonic structures by standard diffraction experiments and use of the rigorous coupled-wave analysis in the multi-wave coupling regime, without the need for taking any auxiliary data. In particular, we show how the phases of the Fourier components of a periodic structure can be fully recovered by deliberately choosing a probe wavelength of the diffracting radiation much smaller than the lattice constant of the structure. In the course of our demonstration, we accurately determine the slight asymmetry of the structure of nanocomposite phase gratings by light and neutron diffraction measurements.

Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 × 10−5 and 1.85 × 10−4 Å−1. It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered.

This paper reports imaging of objects with slow neutrons, specifically very cold neutrons and cold neutrons, at Institut Laue Langevin, using novel, permanent magnet (Nd2Fe14B) compound refractive lenses (MCRL) with a large 2.5 cm bore diameter. The MCRL focuses and images spin-up neutrons and defocuses spin-down neutrons via a large, radial magnetic field gradient. A single lens neutron microscope, composed of an MCRL objective lens with 2-fold magnification, was tested using very cold (slow) neutrons at 45 angstrom wavelength. One-to-one imaging was obtained using 16.7 angstrom polarized neutrons. The magnetic field gradient of the MCRL was measured by raster-scanned pencil beams on D33. Finally, a compound neutron microscope was realized using an MCRL condenser lens, which provided increased illumination of objects, and an MCRL as objective lens to produce 3.5-fold magnification.

In the second part of our presentations we discuss the results of diffraction experiments from nanodiamond-polymer composite gratings performed with slow neutrons, i.e., at wavelengths longer than a nanometer. One goal of our investigations is to develop flexible, handy, low cost neutron diffractive optical elements (gratings) which can be tailored to serve as mirrors, two-port beamsplitters, multiport beamsplitters, polarizing beamsplitters or even can be assembled to form an interferometer. Basically three adjustable multiplicative parameters are decisive for the performance, i.e., the reflectivity or diffraction efficiency, of such gratings: the wavelength of the neutrons, the thickness and the neutron scattering density modulation of the grating. While the _rst is solely determined by the application one has in mind, the second parameter can be adjusted during the production process of the sample or by tilting the grating about an axis parallel to the grating vector, thus increasing the effective thickness. The third parameter, however, can only be tuned via the production process of the gratings but offers an enormous flexibility due to a variety of nanoparticles and the polymeric host materials at hand. For neutrons the important criteria are to design gratings having high coherent scattering length density modulation while avoiding incoherent scattering and absorption at the same time. For interferometric purposes an ideal grating will have high reflectivity and low angular selectivity. Here, we show first results obtained with nanodiamond-polymer composite gratings and outline potential ways to improvements.

Suspensions of magnetic nanoplatelets in isotropic solvents are very interesting examples of ferrofluids. It has been shown that above a certain concentration ΦNI such suspensions form a ferromagnetic nematic phase, which makes this system a unique example of a dipolar fluid. The formation of a nematic phase is driven by anisotropic electrostatic and long-range dipolar magnetic interactions. Here, we present studies of the evolution of short range positional and orientational magnetic order in suspensions with volume fractions below and above ΦNI, using small angle neutron scattering (SANS). The results show that in the absence of an external magnetic field, short range positional and orientational order already exist at relatively low volume fractions. Polarized SANS revealed that the contribution of ferromagnetic ordering to the formation of the nematic phase is significant. The ferromagnetic correlations can be qualitatively explained by a simple model, which takes into account anisotropic screened electrostatic and dipolar magnetic interactions.

It is well known that in standard diffaction experiments only the amplitudes of structural Fourier components are recovered but phase information is lost. This problem is known as the ’phase problem’ in crystallography. In this contribution, we point out how the phase problem of diffraction can be solved in some particular cases by employing multi-wave interference. In the experimental situation described here, we were able to determine the form of the refractive-index profile of a 1-D nanocomposite holographic grating by using a multi-wave coupling analysis of the measured angular dependence of the diffraction efficiencies for a number of diffraction orders.

We investigate the applicability of polymer-ionic liquid composites as optical elements for light, as well as for slow neutrons. The gratings are recorded using two-beam mixing and are characterized experimentally based on their diffraction properties. We produced a set of samples differing in their thickness, ranging from 10 m - 100 m . We demonstrate that it is possible to prepare transmission gratings with a lattice constant of Λ = 480 n m , resulting in thick gratings for light, as well as neutrons. The presented samples show low optical losses in the Vis-UV spectrum and exhibit refractive index modulations of about 10 - 3 at λ = 543 n m . However, further improvements have to be made to obtain efficient neutron optical components.

Nanocomposites enable us to tune parameters that are crucial for use of such materials for neutron-optics applications. By careful choice of properties such as species (isotope) and concentration of contained nanoparticles, diffractive optical elements for long-wavelength neutrons are feasible. Nanocomposites for neutron optics have so far been tested successfully in protonated form, containing high amounts of 1H atoms, which exhibits rather strong neutron absorption and incoherent scattering. At a future stage of development, chemicals containing 1H could be replaced by components containing more favorable isotopes, such as 2H or 19F. In this note, we present results of Monte-Carlo simulations of the transmissivity of various nanocomposite materials for thermal and very-cold neutron spectra. Our simulation results for deuterated and fluorinated nanocomposite materials predict the losses due to absorption and scattering to be as low as 2%, as well as the broadening of the beam cross section to be negligible.

Photopolymerizable nanoparticle-polymer composite (NPC) is a photonic nanocomposite material consisting of photopolymer uniformly dispersed with nanoparticles (e.g., SiO 2 and ZrO 2 ). The distribution of dispersed nanoparticles can be manipulated holographically by light. This technique, the so-called holographic assembly of nanoparticles in polymer, enables us to perform the single step formation of large area photonic lattice structures for photonic applications such as holographic data storage, holographic diffractive elements and nonlinear optics. Furthermore, we showed that holographic NPC gratings could control slow-neutron (cold and very cold neutron) beams for neutron interferometer. Here we demonstrate for the first time the use of nanodiamonds (NDs), an intriguing allotrope of carbon, in NPCs to construct holographic NPC gratings with very large refractive index modulation amplitudes (Δn) and thus to efficiently control light and slow-neutron beams. This is possible because NDs have very high bulk refractive index at optical wavelengths and very large coherent and very small incoherent scattering cross sections with low absorption at slow-neutron wavelengths.