Abstract. We present the first multi-model study of the Antarctic sea ice response to enhanced meltwater due to dynamic mass loss from the Antarctic ice sheet. This meltwater flux (and its future increase under global warming) is not included in the most recent state-of-the-art climate model simulations used in CMIP6, representing a missing source of freshwater to the Southern Ocean. Previous climate model simulations have shown a wide range of responses in Antarctic sea ice and climate when this missing meltwater is introduced. Here, we analyze a new suite of 11 models comprising 43 ensemble members to assess the response to 0.1 Sv of Antarctic meltwater input at the ocean surface, evenly distributed around the Antarctic coastline under pre-industrial control forcing. Antarctic sea ice area increases in all models. However, there is a wide range in the response, with annual mean increases ranging from 0.71 to 4.14 million km2. There is also substantial variation in both the spatial distribution and the time scale of the sea ice response. The intermodel spread in sea ice response is influenced by the model mean-state sea ice area and volume, the prevalence of open-ocean deep convection, and the mean-state stratification of the ocean. These findings highlight the importance of model mean-state biases in determining the response to a missing Antarctic meltwater boundary condition.

Frazil ice forms in supercooled water beneath ice shelves, where direct observations are needed to constrain ice–ocean heat and mass exchange. This study presents the design, testing, and initial deployment of a prototype optical frazil ice imaging system in McMurdo Sound, Antarctica, in 2022. Co-located acoustic measurements provided qualitative assessment under scattering conditions that limited quantitative acoustic retrieval. The optical system imaged frazil ice crystals in situ against the natural ocean background using a camera mounted within a deployment frame. Crystal sizes were derived using image-based analysis of calibrated 200 × 800 pixel images. Across two deployments, mean crystal diameters of 0.51 and 0.54 mm, and bulk concentrations of 2.6 × 10⁻⁸ and 2.2 × 10⁻⁸ m³ m⁻³, were obtained. These results demonstrate the potential of optical imaging for quantifying small frazil ice crystals in situations characterised by very low concentrations.

The increasing release of Antarctic meltwater represents one of the most profound, yet uncertain, consequences of global climate change. The absence of interactive ice sheets in state-of-the-art climate models prevents the direct calculation of ice-ocean feedbacks, leaving significant uncertainty in the global and regional consequences of meltwater discharge. This study leverages results from the Southern Ocean Freshwater Input from Antarctica (SOFIA) initiative to assess the ocean response to a 0.1 Sv meltwater perturbation and infer the feedback on ice shelf basal melting across 10 CMIP6 models. We analyze meltwater-induced temperature anomalies across distinct continental shelf regimes and compare them with SSP5-8.5 warming-induced anomalies. We then translate these anomalies into basal melt rates using a parameterization calibrated with a new observational climatology, which reveals strongly regional melt sensitivities that cannot be captured with an Antarctic-wide coefficient. Although the meltwater feedback is generally thought to amplify basal melting, our results demonstrate large regional differences, with implied enhanced ice shelf mass loss in some sectors but suppressed basal melting in others. The model ensemble indicates a warming feedback on the continental shelf in most East Antarctic regions, whereas in West Antarctica, most models simulate either cooling or reduced warming, suggesting a negative feedback. This regional contrast implies that East Antarctica may play an increasingly dominant role in future ice shelf mass loss. Simulations support existing hypotheses linking these asymmetric temperature responses to strong regional connectivity and shelf-break dynamics, including a strengthened Antarctic Slope Front, an accelerated Antarctic Slope Current, and reduced dense shelf water formation.

Enhanced Antarctic ice sheet mass loss yields ocean surface freshening, cooling and sea ice expansion, which result in changes in the atmospheric conditions. Using the Southern Ocean Freshwater Input from Antarctica (SOFIA) multi‐model ensemble, we study the atmospheric response to a 100‐year idealized freshwater release of 0.1 Sv. All models simulate a surface‐intensified tropospheric cooling and lower‐stratospheric warming south of 35°S. Tropospheric cooling is attributed to sea ice expansion and the associated albedo enhancement in winter and a colder sea surface in summer. This cooling yields a downward displacement of the tropopause, reduced stratospheric water vapor content and ultimately warming around 200 hPa. An enhanced southward eddy heat flux explains warming at 10–100 hPa during austral winter. Despite a temporally (and spatially) uniform prescribed freshwater flux, a prominent sea ice seasonal cycle and atmosphere dynamics result in a distinct seasonal pattern in the occurrence and magnitude of the temperature responses.

Aerosol samples collected during summer 2013 on GEOTRACES cruise GA04 in the Mediterranean and Black seas were analysed for their soluble and total metal and major ion composition. The fractional solubilities (soluble divided by total concentrations) of the lithogenic elements (Al, Ti, Mn, Fe, Co and Th) varied strongly with atmospheric dust loading. Solubilities of these elements in samples that contained high concentrations of mineral dust were noticeably lower than at equivalent dust concentrations over the Atlantic Ocean. This behaviour probably reflects the distinct transport and pollutant regimes of the Mediterranean basin. Elements with more intense anthropogenic sources (P, V, Ni, Cu, Zn, Cd and Pb) had a variety of largely independent sources in the region and generally displayed higher fractional solubilities than the lithogenic elements. Calculated dry-deposition fluxes showed a west-to-east decline in the N/P ratio in deposition over the Mediterranean, a factor that contributes to the P-limited status of the eastern basin. Atmospheric deposition may make a significant contribution to the surface water budgets of Mn and Zn in the western Mediterranean.

We assess the response of Antarctic sea ice, the Southern Ocean, and global climate to mass loss from the Antarctic continent in a new multi-model ensemble. Antarctic ice-mass loss from ice sheets and ice shelves is increasing and is projected to increase further as the climate warms. The fresh water entering the Southern Ocean due to this ice-mass loss has been proposed as a mechanism responsible for the lack of decline in Antarctic sea ice area between 1979 and 2015, in contrast to the sea-ice loss seen in the Arctic. The fresh water impacts sea ice by increasing the density gradient between the near-surface waters and deeper waters around the Antarctic continent, which inhibits vertical transport of warmer, deeper water to the surface. This results in surface cooling and increased sea ice growth, as has been shown in previous studies. Though this increased Antarctic ice-mass loss is expected to impact climate it is absent from almost all models in the current Coupled Model Intercomparison Project (CMIP6), which typically enforce that the continent remain in perpetual mass balance, with no gain or loss of mass over time. Further, previous non-CMIP6 model experiments that include changing Antarctic ice-mass loss suggest that the climate response depends on the model used, and that the reasons for this model dependence are not clear. We present results from the Southern Ocean Freshwater Input from Antarctica (SOFIA) Initiative, an international model intercomparison, in which freshwater is added to the ocean surrounding Antarctica to simulate the otherwise missing ice-sheet mass loss. This unique suite of models allows us compare the response to Antarctic mass loss across climate models, identify reasons for model discrepancies, and quantify the potential impact of the absence of increasing Antarctic ice-mass loss on Antarctic sea ice and climate. We will give an overview of the SOFIA initiative including the experiment design and participating models. We will present results from the “antwater” experiment outlined in the SOFIA protocol in which a constant freshwater input of 0.1 Sv is distributed evenly around the Antarctic continent at the ocean surface in an experiment with pre-industrial control forcing. We show that there is a spread of up to a factor of 3 across models in the Antarctic sea ice area response to identical freshwater forcing. There are also substantial differences in the spatial pattern of the sea ice response depending on the model used. We explore the dependence of the response on the mean state of Antarctic sea ice and the Southern Ocean in the pre-industrial control runs, as well as the response of the ocean stratification and oceanic deep convection in the models. We also explore the seasonality of the sea ice and oceanic response.

Abstract We investigate the impacts of meltwater from Antarctic Ice Sheet (AIS) mass loss on New Zealand climate in a state‐of‐the‐art global climate model. We conduct simulations with additional meltwater from AIS mass loss for both the historical period and a high‐emissions future scenario. The ocean surface to the southeast of New Zealand cools, with the largest change in winter and spring. The additional meltwater results in a northward shift of the oceanic sub‐tropical front near New Zealand, which partially offsets the projected southward shift of this front in a warming climate. Wintertime surface westerly winds to the south of New Zealand also increase with the addition of the meltwater. The magnitude of the impact of Antarctic meltwater is uncertain due to the wide spread in estimates of Antarctic mass imbalance, but has important implications for future projections for New Zealand climate.

Abstract. We investigate the effect of partial dissolution on the transport of chemicals in sea ice. Physically plausible mechanisms are added to a brine convection model that decouples chemicals from convecting brine. The model is evaluated against a recent observational dataset where a suite of qualitatively similar chemicals (poly- and perfluoroalkylated substances, PFASs) with quantitatively different physico-chemical properties were frozen into growing sea ice. With no decoupling the model performs poorly – underestimating the measured concentrations of high-chain-length PFASs. A decoupling scheme where PFASs are decoupled from salinity as a constant fraction of their brine concentration and a scheme where decoupling is proportional to the brine salinity give better performance and bring the model into reasonable agreement with observations. A scheme where the decoupling is proportional to the internal sea-ice surface area performs poorly. All decoupling schemes capture a general enrichment of longer-chained PFASs and can produce concentrations in the uppermost sea-ice layers above that of the underlying water concentration, as observed. Our results show that decoupling from convecting brine can enrich chemical concentrations in growing sea ice and can lead to bulk chemical concentrations greater than that of the liquid from which the sea ice is growing. Brine convection modelling is useful for predicting the dynamics of chemicals with more complex behaviour than sea salt, highlighting the potential of these modelling tools for a range of biogeochemical research areas.

AbstractEarlier chapters of this work have described procedures and protocols that are applicable to most chambers, this chapter has a slightly different focus; we predominantly consider multiphase processes where the applications are on phase transfer of chemical species rather than chemical reactions and the processes are generally occurring in highly specialized chambers. Three areas are described. Firstly, cloud formation processes; here, precise control of physical and thermodynamic properties is required to generate reproducible results. The second area examined is the air/sea interface, looking at the formation of aerosols from nonanoic acid as a surfactant with humic acid as a photosensitizer. The final apparatus described is the Roland von Glasow sea-ice chamber where a detailed protocol for the reproducible formation of sea-ice is given along with an outlook of future work. The systems studied in all three sections are characterized by difficulties in making detailed in situ observations in the real world, either due to the transitory nature of systems or the practical difficulties in accessing the systems. While these specialized simulation chambers may not perfectly reproduce conditions in the real world, the chambers do provide more facile opportunities for making extended and reproducible measurements to investigate fundamental physical and chemical processes, at significantly lower costs.

Abstract We investigate feedbacks between subsurface continental shelf ocean temperatures and Antarctic glacial melt using a coupled climate model. The model was forced with SSP5‐8.5 and an uncoupled projection of basal melt and calving fluxes. SSP5‐8.5 forcing with fixed pre‐industrial glacial melt warms all continental shelves, such that historically “cool” and “fresh” shelves transition to “warm.” Additional glacial melt, added at depth, cools the Eastern Ross, Amundsen, and Bellingshausen seas, suggesting a negative feedback on basal melt—a novel result for a coarse resolution coupled model. From the Weddell Sea, along East Antarctica, and into the western Ross Sea—where continental shelves transition to a “warm” state—additional glacial melt increases temperatures at the continental shelf sea floor, suggesting a positive feedback. The sign of the glacial melt–subsurface temperature feedback is critically dependent on continental shelf properties, climate state, and the vertical distribution of glacial melt inputs.

Abstract. As the climate warms, the grounded ice sheet and floating ice shelves surrounding Antarctica are losing mass at an increasing rate and injecting the resulting meltwater into the Southern Ocean. This freshwater input could feed back onto climate change, particularly since the Southern Ocean is a key contributor to global heat and carbon uptake. Nonetheless, almost all existing coupled climate models have fixed ice sheets, and lack the physics required to represent the dominant sources of Antarctic melt. These missing ice dynamics represent a key uncertainty that is unaccounted for in current global climate change projections. Previous studies have inserted additional Antarctic meltwater into models, demonstrating that it can alter Southern Ocean stratification, circulation, and sea ice, as well as influence remote atmospheric circulation, tropical precipitation, and global temperature. However, these previous studies have used widely varying rates of freshwater forcing, been conducted using different climate models and configurations, and have reached differing conclusions on the magnitude of meltwater-climate feedbacks. The Southern Ocean Freshwater release model experiments InitiAtive (SOFIA) brings together a team of scientists to quantify the climate system response to Antarctic meltwater input. In this paper, we summarize the state of knowledge on meltwater discharge from the Antarctic ice sheet and ice shelves to the Southern Ocean and explain the scientific objectives of our initiative. We propose a series of coupled and ocean/sea-ice model experiments, including idealized meltwater experiments, historical experiments with observationally consistent meltwater input, and future scenarios driven by meltwater inputs derived from stand-alone ice sheet models. Through coordinating a multi-model ensemble of simulations, with data housed in a common archive, SOFIA will be able to produce a consistent estimate of the climate system response to Antarctic meltwater, as well as the uncertainty of this response.

As the climate warms, the grounded ice sheet and floating ice shelves surrounding Antarctica are melting and releasing additional freshwater into the Southern Ocean. Nonetheless, almost all existing coupled climate models have fixed ice sheets and lack the physics required to represent the dominant sources of Antarctic melt. These missing ice dynamics represent a key uncertainty that is typically unaccounted for in current global climate change projections. Previous modelling studies that have imposed additional Antarctic meltwater have demonstrated regional impacts on Southern Ocean stratification, circulation, and sea ice, as well as remote changes in atmospheric circulation, tropical precipitation, and global temperature. However, these previous studies have used widely varying rates of freshwater forcing, have been conducted using different climate models and configurations, and have reached differing conclusions on the magnitude of meltwater–climate feedbacks. The Southern Ocean Freshwater Input from Antarctica (SOFIA) initiative brings together a team of scientists to quantify the climate system response to Antarctic meltwater input along with key aspects of the uncertainty. In this paper, we summarize the state of knowledge on meltwater discharge from the Antarctic ice sheet and ice shelves to the Southern Ocean and explain the scientific objectives of our initiative. We propose a series of coupled and ocean–sea ice model experiments, including idealized meltwater experiments, historical experiments with observationally consistent meltwater input, and future scenarios driven by meltwater inputs derived from stand-alone ice sheet models. Through coordinating a multi-model ensemble of simulations using a common experimental design, open data archiving, and facilitating scientific collaboration, SOFIA aims to move the community toward better constraining our understanding of the climate system response to Antarctic melt.

Abstract The additional water from the Antarctic ice sheet and ice shelves due to climate‐induced melt can impact ocean circulation and global climate. However, the major processes driving melt are not adequately represented in Coupled Model Intercomparison Project phase 6 (CMIP6) models. Here, we analyze a novel multi‐model ensemble of CMIP6 models with consistent meltwater addition to examine the robustness of the modeled response to meltwater, which has not been possible in previous single‐model studies. Antarctic meltwater addition induces a substantial weakening of open‐ocean deep convection. Additionally, Antarctic Bottom Water warms, its volume contracts, and the sea surface cools. However, the magnitude of the reduction varies greatly across models, with differing anomalies correlated with their respective mean‐state climatology, indicating the state‐dependency of the climate response to meltwater. A better representation of the Southern Ocean mean state is necessary for narrowing the inter‐model spread of response to Antarctic meltwater.

Sample collection and field studies of sea ice take place under harsh conditions which, combined with the logistical difficulties and high cost of voyages to the polar regions, limits the abilities of researchers to determine its properties. Observations of laboratory-grown sea ice can help quantify important sea-ice properties and incorporate them into numerical models. The growth of laboratory sea ice requires experimental set-ups that consider the complexity of sea-ice growth. Regulation and monitoring of environmental variables allow for growth and melt conditions to be controlled, manipulated and reproduced. Facilities thus vary widely because of differing research objectives. This paper presents a summary of some of the published sea-ice laboratories that study the physical properties of sea ice and an overview of their major design considerations, such as tank size, freezing method and instrumentation. It also discusses how these design considerations were implemented in the set-up of the new sea-ice growth laboratory at the Marine and Antarctic Research for Innovation and Sustainability. This paper should guide others in designing their facilities as well as in their understanding of other facilities for results comparison.

We present MISTRA-v9.0, a one-dimensional (1D) and box (0D) atmospheric chemistry model. The model includes a detailed particle description with regards to the microphysics, gas–particle interactions, and liquid-phase chemistry within particles. Version 9.0 (v9.0) is the first release of MISTRA as an open-source community model. A major review of the code has been performed along with this public version release to improve the user friendliness and platform independence of the model. The purpose of this public release is to maximise the benefit of MISTRA to the community by making the model freely available and easier to use and develop. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA, finding that v9.0 is consistent with previous versions.

Sea ice is difficult, expensive, and potentially dangerous to observe in nature. The remoteness of the Arctic Ocean and Southern Ocean complicates sampling logistics, while the heterogeneous nature of sea ice and rapidly changing environmental conditions present challenges for conducting process studies. Here, we describe the Roland von Glasow Air-Sea-Ice Chamber (RvG-ASIC), a laboratory facility designed to reproduce polar processes and overcome some of these challenges. The RvG-ASIC is an open-topped 3.5 m3 glass tank housed in a cold room (temperature range: −55 to +30 ∘C). The RvG-ASIC is equipped with a wide suite of instruments for ocean, sea ice, and atmospheric measurements, as well as visible and UV lighting. The infrastructure, available instruments, and typical experimental protocols are described. To characterise some of the technical capabilities of our facility, we have quantified the timescale over which our chamber exchanges gas with the outside, τl=(0.66±0.07) d, and the mixing rate of our experimental ocean, τm=(4.2±0.1) min. Characterising our light field, we show that the light intensity across the tank varies by less than 10 % near the centre of the tank but drops to as low as 60 % of the maximum intensity in one corner. The temperature sensitivity of our light sources over the 400 to 700 nm range (PAR) is (0.028±0.003) W m−2 ∘C−1, with a maximum irradiance of 26.4 W m−2 at 0 ∘C; over the 320 to 380 nm range, it is (0.16±0.1) W m−2 ∘C−1, with a maximum irradiance of 5.6 W m−2 at 0 ∘C. We also present results characterising our experimental sea ice. The extinction coefficient for PAR varies from 3.7 to 6.1 m−1 when calculated from irradiance measurements exterior to the sea ice and from 4.4 to 6.2 m−1 when calculated from irradiance measurements within the sea ice. The bulk salinity of our experimental sea ice is measured using three techniques, modelled using a halo-dynamic one-dimensional (1D) gravity drainage model, and calculated from a salt and mass budget. The growth rate of our sea ice is between 2 and 4 cm d−1 for air temperatures of (-9.2±0.9) ∘C and (-26.6±0.9) ∘C. The PAR extinction coefficients, vertically integrated bulk salinities, and growth rates all lie within the range of previously reported comparable values for first-year sea ice. The vertically integrated bulk salinity and growth rates can be reproduced well by a 1D model. Taken together, the similarities between our laboratory sea ice and observations in nature, as well as our ability to reproduce our results with a model, give us confidence that sea ice grown in the RvG-ASIC is a good representation of natural sea ice.

Poly- and perfluoroalkyl substances (PFAS) are contaminants of emerging Arctic concern and are present in the marine environments of the polar regions. Their input to and fate within the marine cryosphere are poorly understood. We conducted a series of laboratory experiments to investigate the uptake, distribution, and release of 10 PFAS of varying carbon chain length (C4–C12) in young sea ice grown from artificial seawater (NaClsolution). We show that PFAS are incorporated into bulk sea ice during ice formation and regression analyses for individual PFAS concentrations in bulk sea ice were linearly related to salinity (r2 = 0.30 to 0.88, n = 18, p < 0.05). This shows that their distribution is strongly governed by the presence and dynamics of brine (high salinity water) within the sea ice. Furthermore, long-chain PFAS (C8–C12), were enriched in bulk ice up to 3-fold more than short-chain PFAS (C4–C7) and NaCl. This suggests that chemical partitioning of PFAS between the different phases of sea ice also plays a role in their uptake during its formation. During sea ice melt, initial meltwater fractions were highly saline and predominantly contained short-chain PFAS, whereas the later, fresher meltwater fractions predominantly contained long-chain PFAS. Our results demonstrate that in highly saline parts of sea ice (near the upper and lower interfaces and in brine channels) significant chemical enrichment (ε) of PFAS can occur with concentrations in brine channels greatly exceeding those in seawater from which it forms (e.g., for PFOA, εbrine = 10 ± 4). This observation has implications for biological exposure to PFAS present in brine channels, a common feature of first-year sea ice which is the dominant ice type in a warming Arctic.

Every winter, a frozen blanket known as sea ice completely covers the Arctic Ocean. For centuries, sea ice has been viewed as a solid lid on the ocean that acts as a boundary to block gases traveling between the ocean and the atmosphere. However, scientific discoveries over recent years have shown that sea ice is more like a sponge, a porous substance that is also home to microscopic life forms. The pores in sea ice are filled with very salty liquid called brine that is rich in carbon dioxide (CO2). These liquid pockets create a network of tubes or channels that move gases like CO2, similar to the way veins and arteries move blood in our bodies. In this article, you will discover how CO2 enters, exits, and is transformed in one of the harshest environments on Earth.

Abstract. We present MISTRA-v9.0, a one dimensional (1D) atmospheric chemistry model. The model includes a detailed particle description with regards to the microphysics, gas-particle interactions, and liquid phase chemistry within particles. Version 9.0 is the first release of MISTRA as an open-source community model. A major review of the code has been performed along with this public version release to improve the user-friendliness and platform-independence of the model. In the past 20 years, MISTRA has been used in over 25 studies to address a wide range of scientific questions. The purpose of this public release is to maximise the benefit of MISTRA to the community by making the model freely available and easier to use and develop. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA, finding that version 9.0 is consistent with previous versions.