We performed a detailed spectroscopic analysis of three extremely metal-poor RR Lyrae stars, exploring uncharted territories at these low metallicities for this class of stars. Using high-resolution spectra acquired with HARPS-N at TNG, UVES at VLT, and PEPSI at LBT, and employing Non-Local Thermodynamic Equilibrium (NLTE) spectral synthesis calculations, we provide abundance measurements for Fe, Al, Mg, Ca, Ti, Mn, and Sr. Our findings indicate that the stars have metallicities of [Fe/H] = -3.40 +/- 0.05, -3.28 +/- 0.02, and -2.77 +/- 0.05 for HD 331986, DO Hya, and BPS CS 30317-056, respectively. Additionally, we derived their kinematic and dynamical properties to gain insights into their origins. Interestingly, the kinematics of one star (HD 331986) is consistent with the Galactic disc, while the others exhibit Galactic halo kinematics, albeit with distinct chemical signatures. We compared the [Al/Fe] and [Mg/Mn] ratios of the current targets with recent literature estimates to determine whether these stars were either accreted or formed in situ, finding that the adopted chemical diagnostics are ineffective at low metallicities ([Fe/H] less than or similar to -1.5). Finally, the established horizontal branch evolutionary models, indicating that these stars arrive at hotter temperatures on the Zero-Age Horizontal Branch (ZAHB) and then transition into RR Lyrae stars as they evolve, fully support the existence of such low-metallicity RR Lyrae stars. As a consequence, we can anticipate detecting more of them when larger samples of spectra become available from upcoming extensive observational campaigns.

Context. As a key to chemical evolutionary studies, the distribution of elements in galactic provides a wealth of information to understand the individual star formation histories of galaxies. The r-process is a complex nucleosynthesis process, and the origin of r-process elements is heavily debated. Europium (Eu) is viewed as an almost pure r-process element. Accurate measurements of europium abundances in cool stars are essential for an enhanced understanding of the r-process mechanisms. Aims. We measure the abundance of Eu in solar spectra and a sample of metal-poor stars in the Galactic halo and metal-poor disk, with the metallicities ranging from -2.4 to -0.5 dex, using non-local thermodynamic equilibrium (NLTE) line formation. We compare these measurements with Galactic Chemical Evolution (GCE) models to explore the impact of the NLTE corrections on the contribution of r-process site in Galactic chemical evolution. Methods. In this work, we used NLTE line formation, as well as one-dimensional (1D) hydrostatic and spatial averages of three-dimensional hydrodynamical (<3D>) model atmospheres to measure the abundance of Eu based on both the Eu II 4129 & Aring; and Eu II 6645 & Aring; lines for solar spectra and metal-poor stars. Results. We find that for Eu II 4129 & Aring; line the NLTE modeling leads to higher (0.04 dex) solar Eu abundance in 1D and higher (0.07 dex) in <3D> NLTE while NLTE modeling leads to higher (0.01 dex) solar Eu abundance in 1D and lower (0.03 dex) in <3D> NLTE for Eu II 6645 & Aring; line. Although the NLTE corrections for the Eu II lambda 4129 & Aring; and Eu II lambda 6645 & Aring; lines are opposite, the discrepancy between the abundances derived from these individual lines reduces after applying NLTE corrections, highlighting the critical role of NLTE abundance determinations. By comparing these measurements with Galactic chemical evolution (GCE) models, we find that the amount of NLTE correction does not require significant change of the parameters for Eu production in GCE models.

Stellar mergers and accretion events have been crucial in shaping the evolution of the Milky Way (MW). These events have been dynamically identified and chemically characterised using red giants and main-sequence stars. RR Lyrae (RRL) variables can play a crucial role in tracing the early formation of the MW since they are ubiquitous, old (t$\ge$10 Gyr) low-mass stars and accurate distance indicators. We exploited Data Release 3 of the GALAH survey to identify 78 field RRLs suitable for chemical analysis. Using synthetic spectra calculations, we determined atmospheric parameters and abundances of Fe, Mg, Ca, Y, and Ba. Most of our stars exhibit halo-like chemical compositions, with an iron peak around [Fe/H]$\approx -$1.40, and enhanced Ca and Mg content. Notably, we discovered a metal-rich tail, with [Fe/H] values ranging from $-$1 to approximately solar metallicity. This sub-group includes almost ~1/4 of the sample, it is characterised by thin disc kinematics and displays sub-solar $\alpha$-element abundances, marginally consistent with the majority of the MW stars. Surprisingly, they differ distinctly from typical MW disc stars in terms of the s-process elements Y and Ba. We took advantage of similar data available in the literature and built a total sample of 535 field RRLs for which we estimated kinematical and dynamical properties. We found that metal-rich RRLs (1/3 of the sample) likely represent an old component of the MW thin disc. We also detected RRLs with retrograde orbits and provided preliminary associations with the Gaia-Sausage-Enceladus, Helmi, Sequoia, Sagittarius, and Thamnos stellar streams.

Context. Abundances of s- and r-process elements in Sun-like stars constrain nucleosynthesis in extreme astrophysical events, such as compact binary mergers and explosions of highly magnetised rapidly rotating massive stars. Aims. We measure solar abundances of yttrium (Y) and europium (Eu) using 3D non-local thermal equilibrium (NLTE) models. We use the model to determine the abundance of Y, and also explore the model's ability to reproduce the solar centre-to-limb variation of its lines. In addition, we determine the Eu abundance using solar disc-centre and integrated flux spectra. Methods. We developed an NLTE model of Eu and updated our model of Y with collisional data from detailed quantum-mechanical calculations. We used the IAG spatially resolved high-resolution solar spectra to derive the solar abundances of Y across the solar disc and of Eu for integrated flux and at disc centre using a set of carefully selected lines and a 3D radiation-hydrodynamics model of the solar atmosphere. Results. We find 3D NLTE solar abundances of A(Y)(3D NLTE) = 2.30 +/- 0.03(stat) +/- 0.07(syst) dex based on observations at all angles and A(Eu) = 0.57 +/- 0.01(stat) +/- 0.06(syst) dex based on the integrated flux and disc-centre intensity. 3D NLTE modelling offers the most consistent abundances across the solar disc, and resolves the problem of severe systematic bias in Y and Eu abundances inherent to 1D LTE, 1D NLTE, and 3D LTE modelling.

Context. The chemical evolution history of slow neutron-capture elements in the Milky Way is still a matter of debate, especially in the metal-poor regime ([Fe/H] < -1). Aims. Based on Gaia-ESO spectroscopic data, a recent study investigated the chemical evolution of neutron-capture elements in the regime [Fe/H] > -1. Here, we aim to complement this study down to [Fe/H] = -3, and focus on Ba, Y, and Sr, along with the abundance ratios of [Ba/Y] and [Sr/Y], which give comprehensive views on s-process nucleosynthesis channels. Methods. We measured the local thermodynamic equilibrium (LTE) and non-local thermodynamic equilibrium (NLTE) abundances of Ba, Y, and Sr in 323 Galactic metal-poor stars using high-resolution optical spectra with high signal-to-noise ratios. We used the spectral fitting code TSFitPy together with 1D model atmospheres, using previously determined LTE and NLTE atmospheric parameters. Results. We find that the NLTE effects are on the order of similar to- 0.1 to similar to 0.2 dex, depending on the element. We find that stars enhanced (deficient) in [Ba/Fe] and [Y/Fe] are also enhanced (deficient) in [Sr/Fe], suggesting a common evolution channel for these three elements. We find that the ratio between heavy and light s-process elements [Ba/Y] varies weakly with [Fe/H] even in the metal-poor regime, which is consistent with the behaviour in the metal-rich regime. The [Ba/Y] scatter at a given metallicity is larger than the abundance measurement uncertainties. Homogeneous chemical evolution models with different yield prescriptions are not able to accurately reproduce the [Ba/Y] scatter in the low-[Fe/H] regime. Adopting the stochastic chemical evolution model by Cescutti & Chiappini allows us to reproduce the observed scatter in the abundance pattern of [Ba/Y] and [Ba/Sr]. Based on our observations, we have ruled out the need for an arbitrary scaling of the r-process contribution, as previously suggested by the authors behind the construction of the model. Conclusions. We show how important it is to properly include NLTE effects when measuring chemical abundances, especially in the metal-poor regime. This work demonstrates that the choice of the Galactic chemical evolution model (stochastic versus one-zone) is key when comparing models to observations. Upcoming large-scale spectroscopic surveys such as 4MOST and WEAVE are poised to deliver high-quality data for many thousands of metal-poor stars and this work gives a typical case study of what could be achieved with such surveys in the future.

Separating stars enriched in the s- and r-processes of nucleosynthesis is usually achieved by analyzing the element ratios of s-process elements (like Ba or La) to r-process elements (like Eu). The situation becomes more complex when analyzing CEMP-rs stars, which are carbon-enriched metal-poor objects enriched in a mixture of s- and r-elements. These objects, possibly resulting from the i-process of nucleosynthesis, are notoriously difficult to classify based on elemental ratios. Recent theoretical studies have outlined, however, that the s-, i-, and r-processes produce distinct isotopic mixtures. Here, we propose to analyze a sample of stars known to be enriched in s, r, or r + s elements and to determine the odd-to-even isotopic ratio measured on atomic lines of barium, in order to validate or disprove their assignation.

Stars formed with initial mass over 50 Msun are very rare today, but they are thought to be more common in the early universe. The fates of those early, metal-poor, massive stars are highly uncertain. Most are expected to directly collapse to black holes, while some may explode as a result of rotationally powered engines or the pair-creation instability. We present the chemical abundances of J0931+0038, a nearby low-mass star identified in early followup of SDSS-V Milky Way Mapper, which preserves the signature of unusual nucleosynthesis from a massive star in the early universe. J0931+0038 has relatively high metallicity ([Fe/H] = -1.76 +/- 0.13) but an extreme odd-even abundance pattern, with some of the lowest known abundance ratios of [N/Fe], [Na/Fe], [K/Fe], [Sc/Fe], and [Ba/Fe]. The implication is that a majority of its metals originated in a single extremely metal-poor nucleosynthetic source. An extensive search through nucleosynthesis predictions finds a clear preference for progenitors with initial mass > 50 Msun, making J0931+0038 one of the first observational constraints on nucleosynthesis in this mass range. However the full abundance pattern is not matched by any models in the literature. J0931+0038 thus presents a challenge for the next generation of nucleosynthesis models and motivates study of high-mass progenitor stars impacted by convection, rotation, jets, and/or binary companions. Though rare, more examples of unusual early nucleosynthesis in metal-poor stars should be found in upcoming large spectroscopic surveys.

Accurate measurements of europium abundances in cool stars are essential for an enhanced understanding of the r-process mechanisms. We measure the abundance of Eu in solar spectra and a sample of metal-poor stars in the Galactic halo and metal-poor disk, with the metallicities ranging from \GG{$-2.4$} to $-0.5$ dex, using non-local thermodynamic equilibrium (NLTE) line formation. We compare these measurements with Galactic Chemical Evolution (GCE) models to \GG{explore the impact of the NLTE corrections on the contribution of r-process site in Galactic chemical evolution. In this work, we use NLTE line formation, as well as one-dimensional (1D) hydrostatic and spatial averages of 3D hydrodynamical ($<$3D$>$) model atmospheres to measure the abundance of Eu based on both the Eu II 4129 \AA\ and Eu II 6645 \AA\ lines for solar spectra and metal-poor stars. We find that \GG{for Eu II 4129 \AA\ line the NLTE modelling leads to higher (0.04 dex) solar Eu abundance in 1D and higher (0.07 dex) in \GG{$<$3D$>$} NLTE while} NLTE modelling leads to higher (0.01 dex) solar Eu abundance in 1D and lower (0.03 dex) in \GG{$<$3D$>$} NLTE for Eu II 6645 \AA\ line. Although the NLTE corrections for the Eu II $\lambda$ 4129 \AA\ and Eu II $\lambda$ 6645 \AA\ lines are opposite, the discrepancy between the abundances derived from these individual lines reduces after applying NLTE corrections, highlighting the critical role of NLTE abundance determinations. By comparing these measurements with Galactic chemical evolution (GCE) models, we find that the \G{amount of NLTE correction does not require significant change of the parameters for Eu production} in the GCE models.

Context. The chemical evolution history of slow neutron-capture elements in the Milky Way is still a matter of debate, especially in the metal-poor regime ([Fe/H] < −1). Aims. Based on Gaia -ESO spectroscopic data, a recent study investigated the chemical evolution of neutron-capture elements in the regime [Fe/H] > −1. Here, we aim to complement this study down to [Fe/H] = −3, and focus on Ba, Y, and Sr, along with the abundance ratios of [Ba/Y] and [Sr/Y], which give comprehensive views on s -process nucleosynthesis channels. Methods. We measured the local thermodynamic equilibrium (LTE) and non-local thermodynamic equilibrium (NLTE) abundances of Ba, Y, and Sr in 323 Galactic metal-poor stars using high-resolution optical spectra with high signal-to-noise ratios. We used the spectral fitting code TSFitPy together with 1D model atmospheres, using previously determined LTE and NLTE atmospheric parameters. Results. We find that the NLTE effects are on the order of ∼ − 0.1 to ∼0.2 dex, depending on the element. We find that stars enhanced (deficient) in [Ba/Fe] and [Y/Fe] are also enhanced (deficient) in [Sr/Fe], suggesting a common evolution channel for these three elements. We find that the ratio between heavy and light s -process elements [Ba/Y] varies weakly with [Fe/H] even in the metal-poor regime, which is consistent with the behaviour in the metal-rich regime. The [Ba/Y] scatter at a given metallicity is larger than the abundance measurement uncertainties. Homogeneous chemical evolution models with different yield prescriptions are not able to accurately reproduce the [Ba/Y] scatter in the low-[Fe/H] regime. Adopting the stochastic chemical evolution model by Cescutti & Chiappini allows us to reproduce the observed scatter in the abundance pattern of [Ba/Y] and [Ba/Sr]. Based on our observations, we have ruled out the need for an arbitrary scaling of the r -process contribution, as previously suggested by the authors behind the construction of the model. Conclusions. We show how important it is to properly include NLTE effects when measuring chemical abundances, especially in the metal-poor regime. This work demonstrates that the choice of the Galactic chemical evolution model (stochastic versus one-zone) is key when comparing models to observations. Upcoming large-scale spectroscopic surveys such as 4MOST and WEAVE are poised to deliver high-quality data for many thousands of metal-poor stars and this work gives a typical case study of what could be achieved with such surveys in the future.

Context. Abundances of s- and r-process elements in Sun-like stars constrain nucleosynthesis in extreme astrophysical events, such as compact binary mergers and explosions of highly magnetised rapidly rotating massive stars. Aims. We measure solar abundances of yttrium (Y) and europium (Eu) using 3D non-local thermal equilibrium (NLTE) models. We use the model to determine the abundance of Y, and also explore the model's ability to reproduce the solar centre-to-limb variation of its lines. In addition, we determine the Eu abundance using solar disc-centre and integrated flux spectra. Methods. We developed an NLTE model of Eu and updated our model of Y with collisional data from detailed quantum-mechanical calculations. We used the IAG spatially resolved high-resolution solar spectra to derive the solar abundances of Y across the solar disc and of Eu for integrated flux and at disc centre using a set of carefully selected lines and a 3D radiation-hydrodynamics model of the solar atmosphere. Results. We find 3D NLTE solar abundances of A(Y)$_{\textrm{3D NLTE}}$=$2.30 \pm 0.03_{\textrm{stat}} \pm 0.07_{\textrm{syst}}$ dex based on observations at all angles and A(Eu)$_{\textrm{3D NLTE}}$=$0.57 \pm 0.01_{\textrm{stat}} \pm 0.06_{\textrm{syst}}$ dex based on the integrated flux and disc-centre intensity. 3D NLTE modelling offers the most consistent abundances across the solar disc, and resolves the problem of severe systematic bias in Y and Eu abundances inherent to 1D LTE, 1D NLTE, and 3D LTE modelling.

Most heavy elements beyond the iron peak are synthesized via neutron capture processes. The nature of the astrophysical sites of neutron capture processes is still very unclear. In this work we explore the observational constraints of the chemical abundances of s-process and r-process elements on the sites of neutron-capture processes by applying Galactic chemical evolution (GCE) models to the data from Gaia-ESO large spectroscopic stellar survey. For the r-process, the [Eu/Fe]-[Fe/H] distribution suggests a short delay time of the site that produces Eu. Other independent observations (e.g., NS-NS binaries), however, suggest a significant fraction of long delayed ($>1$Gyr) neutron star mergers (NSM). When assuming NSM as the only r-process sites, these two observational constraints are inconsistent at above 1$\sigma$ level. Including short delayed r-process sites like magneto-rotational supernova can resolve this inconsistency. For the s-process, we find a weak metallicity dependence of the [Ba/Y] ratio, which traces the s-process efficiency. Our GCE model with up-to-date yields of AGB stars qualitatively reproduces this metallicity dependence, but the model predicts a much higher [Ba/Y] ratio compared to the data. This mismatch suggests that the s-process efficiency of low mass AGB stars in the current AGB nucleosynthesis models could be overestimated.

Yttrium (Y), a key s-process element, is commonly used in nucleosynthesis studies and as a Galactic chemical clock when combined with magnesium (Mg). We study the applicability of the previously assumed local thermal equilibrium (LTE) line formation assumption in Y abundance studies of main-sequence and red giant stars, and probe the impact of NLTE (non-LTE) effects on the [Y/Mg] ratio, a proposed stellar age indicator. We derive stellar parameters, ages, and NLTE abundances of Fe, Mg, and Y for 48 solar analogue stars from high-resolution spectra acquired within the Gaia-ESO survey. For Y, we present a new NLTE atomic model. We determine a solar NLTE abundance of A(Y)(NLTE) = 2.12 +/- 0.04 dex, 0.04 dex higher than LTE. NLTE effects on Y abundance are modest for optical Yii lines, which are frequently used in Sun-like stars diagnostics. NLTE has a small impact on the [Y/Mg] ratio in such stars. For metal-poor red giants, NLTE effects on Yii lines are substantial, potentially exceeding +0.5 dex. For the Gaia/4MOST/WEAVE benchmark star, HD 122563, we find the NLTE abundance ratio of [Y/Fe](NLTE) = -0.55 +/- 0.04 dex with consistent abundances obtained from different Yii lines. NLTE has a differential effect on Y abundance diagnostics in late-type stars. They notably affect Yii lines in red giants and very metal-poor stars, which are typical Galactic enrichment tracers of neutron-capture elements. For main-sequence stars, NLTE effects on optical diagnostic Yii lines remain minimal across metallicities. This affirms the [Y/Mg] ratio's reliability as a cosmochronometer for Sun-like stars.

Recently Lian et al. (2023), thanks to Gaia-ESO data, studied the chemical evolution of neutron-capture elements in the regime [Fe/H]>-1. We aim here to complement this study down to [Fe/H]=-3, and focus on Ba, Y, Sr, and abundance ratios of [Ba/Y] and [Sr/Y], which give comprehensive views on s-process nucleosynthesis channels. We measured LTE and NLTE abundances of Ba, Y, and Sr in 323 Galactic metal-poor stars using high-resolution optical spectra with high S/N. We used the spectral fitting code TSFitPy, together with 1D model atmospheres using previously determined LTE and NLTE atmospheric parameters. The NLTE effects are on the order of -0.1 to ~0.2dex depending on the element. T he ratio between heavy and light s-process elements [Ba/Y] varies weakly with [Fe/H] even in the metal-poor regime, consistently with the behavior in the metal-rich regime. The [Ba/Y] scatter at a given metallicity is larger than the abundance measurement uncertainties. Homogeneous chemical evolution models with different yields prescriptions are unable to accurately reproduce the [Ba/Y] scatter at low-[Fe/H]. Adopting the stochastic chemical evolution model by Cescutti & Chaippini (2014) allows to reproduce the observed scatter in the abundance pattern of [Ba/Y] and [Ba/Sr]. With our observations, we rule out the need for an arbitrary scaling of the r-process contribution as previously suggested by the model authors. We have showed how important it is to properly include NLTE effects when measuring chemical abundances, especially in the metal-poor regime. This work shows that the choice of the Galactic chemical evolution model (stochastic vs. 1-zone) is key when comparing models to observations. The upcoming surveys such as 4MOST and WEAVE will deliver high quality spectra of many thousands of metal-poor stars, and this work gives a typical case study of what could be achieved with such surveys.