Abstract Early studies revealed relationships between barium (Ba), particulate organic carbon and silicate, suggesting applications for Ba as a paleoproductivity tracer and as a tracer of modern ocean circulation. But, what controls the distribution of barium (Ba) in the oceans? Here, we investigated the Arctic Ocean Ba cycle through a one‐of‐a‐kind data set containing dissolved (dBa), particulate (pBa), and stable isotope Ba ratio (δ138Ba) data from four Arctic GEOTRACES expeditions conducted in 2015. We hypothesized that margins would be a substantial source of Ba to the Arctic Ocean water column. The dBa, pBa, and δ138Ba distributions all suggest significant modification of inflowing Pacific seawater over the shelves, and the dBa mass balance implies that ∼50% of the dBa inventory (upper 500 m of the Arctic water column) was supplied by nonconservative inputs. Calculated areal dBa fluxes are up to 10 μmol m−2 day−1 on the margin, which is comparable to fluxes described in other regions. Applying this approach to dBa data from the 1994 Arctic Ocean Survey yields similar results. The Canadian Arctic Archipelago did not appear to have a similar margin source; rather, the dBa distribution in this section is consistent with mixing of Arctic Ocean‐derived waters and Baffin Bay‐derived waters. Although we lack enough information to identify the specifics of the shelf sediment Ba source, we suspect that a sedimentary remineralization and terrigenous sources (e.g., submarine groundwater discharge or fluvial particles) are contributors.

This chapter provides a concise overview of the entire monograph by assembling summaries of 10 individual chapters starting with a global review of large-scale, persistent nutrient fronts of the World Ocean followed by regional chapters on the Arctic Ocean, North Atlantic, Baltic Sea, Kuroshio Current, and the Yellow Sea, a global review of CDOM dynamics at fronts, a chapter on persistent organic pollutants and marine organisms in the Kuroshio-Oyashio frontal zone, and two chapters on marine litter and its dynamics in frontal zones.

Sea ice affects the exchange of energy and matter between the atmosphere and the ocean from local to hemispheric scales. Salt fluxes across the ice-ocean interface that drive thermohaline mixing beneath growing sea ice are important elements of upper ocean nutrient and carbon exchange. Sea-ice melt releases freshwater into the upper ocean and results in formation of melt ponds that affect gas and energy transfer across the atmosphere-ice interface. The Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) provided an opportunity to follow sea-ice evolution and exchange processes over a full seasonal cycle in a rapidly changing ice cover. To this end, approximately 25 sea-ice cores were collected at 2 distinct sites, representing first-year and multi-year ice, to monitor physical, biological and geochemical processes relevant to atmosphere-ice-ocean exchange processes. Here we compare the growth and decay of first-year ice in the Central Arctic during the winter 2019-2020 to that of landfast first-year ice at Utqiaġvik, Alaska, from 1998 to 2016. Ice stratigraphy was similar at both sites with about 15 cm of granular ice on top of columnar ice, with a comparable growth history with a similar maximum ice thickness of 1.6-1.7 m. We aggregated the sea-ice bulk salinity and temperature profiles using a degree-day approach, and examined brine and freshwater fluxes at lower and upper interfaces of the ice, respectively. Preliminary results show lower sea-ice bulk salinity during the growth season and greater desalination at the ice surface during the melt season at the MOSAiC floe in comparison to Utqiaġvik.

It is the purpose of this paper to introduce the reader to the various water masses that are found in the Arctic Ocean and describe how fronts, separating these water masses, are identified through the application of physical and biogeochemical measurements. Variations in the positions/alignments of these fronts help to describe changes in circulation patterns that impact local physical, chemical, and biological systems. In this chapter, the distributions of various physical and geochemical parameters representing summer conditions in the Arctic during 2015, a year of particularly good spatial coverage in terms of scientific observations, will be presented and analyzed with a focus on identifying the front separating Atlantic and Pacific halocline waters in the East Siberian Sea by qualitative means.

The surface waters of the Arctic Ocean include an important inventory of freshwater from rivers, sea ice melt, and glacial meltwaters. While some freshwaters are mixed directly into the surface ocean, cryospheric reservoirs, such as snow, sea ice, and melt ponds act as incubators for trace metals, as well as potential sources to the surface ocean upon melting. The availability and reactivity of these metals depends on their speciation, which may vary across each pool or undergo transformation upon mixing. We present here baseline measurements of colloidal (similar to 0.003-0.200 mu m) iron (Fe), zinc (Zn), nickel (Ni), copper (Cu), cadmium (Cd), and manganese (Mn) in snow, sea ice, melt ponds, and the underlying seawater. We consider both the total concentration of colloidal metals ([cMe]) in each cryospheric reservoir and the contribution of cMe to the overall dissolved metal phase (%cMe). Notably, snow contained higher (cMe) as well as higher %cMe relative to seawater for metals such as Fe and Zn across most stations. Stations close to the North Pole had relatively high aerosol deposition, imparting high (cFe) and (cZn), as well as high %cFe, %cZn, %cMn, and %cCd (>80%). In contrast, surface seawater concentrations of Cd, Cu, Mn, and Ni were dominated by the soluble phase (<0.003 mu m), suggesting little impact of cMe from the melting cryosphere, or rapid aggregation/disaggregation dynamics within surface waters leading to the loss of cMe. This has important implications for how trace metal biogeochemistry speciation and thus fluxes may change in a future ice-free Arctic Ocean.

Mooring observations in the eastern Eurasian Basin of the Arctic Ocean showed that mean 2013–2018 along-slope volume and heat (calculated relative to the freezing temperature) transports in the upper 800 m were 4.8 ± 0.1 Sv (1 Sv = 106 m3/s) and 34.8 ± 0.6 TW, respectively. Volume and heat transports within the Atlantic Water (AW) layer (∼150–800 m) in 2013–2018 lacked significant temporal shifts at annual and longer time scales: averaged over the two periods of mooring deployment in 2013–2015 and 2015–2018, volume transports were 3.1 ± 0.1 Sv, while AW heat transports were 31.3 ± 1.0 TW and 34.8 ± 0.8 TW. Moreover, the reconstructed AW volume transports over longer, 2003–2018, period of time showed strong interannual variations but lacked a statistically significant trend. However, we found a weak positive trend of 0.08 ± 0.07 Sv/year in the barotropic AW volume transport estimated using dynamic ocean topography (DOT) measurements in 2003–2014 – the longest period spanned by the DOT dataset. Vertical coherence of 2013–2018 transports in the halocline (70–140 m) and AW (∼150–800 m) layers was high, suggesting the essential role of the barotropic forcing in constraining along-slope transports. Quantitative estimates of transports and their variability discussed in this study help identify the role of atlantification in critical changes of the eastern Arctic Ocean.

A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river-influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high-resolution pan-Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and similar to 25-50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle-reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 +/- 0.4 Sv (10(6) m(3)s(-1)). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean. Plain Language Summary A major feature of the Arctic Ocean circulation is the Transpolar Drift (TPD), a surface current that carries ice and continental shelf-derived materials from Siberia across the North Pole to the North Atlantic Ocean. In 2015, an international team of oceanographers conducted a survey of trace elements in the Arctic Ocean, traversing the TPD. Near the North Pole, they observed much higher concentrations of trace elements in surface waters than in regions on either side of the current. These trace elements originated from land, and their journey across the Arctic Ocean is made possible by chemical reactions with dissolved organic matter that originates mainly in Arctic rivers. This study reveals the importance of rivers and shelf processes combined with strong ocean currents in supplying trace elements to the central Arctic Ocean and onward to the Atlantic. These trace element inputs are expected to increase as a result of permafrost thawing and increased river runoff in the Arctic, which is warming at a rate much faster than anywhere else on Earth. Since many of the trace elements are essential building blocks for ocean life, these processes could lead to significant changes in the marine ecosystems and fisheries of the Arctic Ocean.

A 15-yr duration record of mooring observations from the eastern (>70 degrees E) Eurasian Basin (EB) of the Arctic Ocean is used to show and quantify the recently increased oceanic heat flux from intermediate-depth (similar to 150-900m) warmAtlantic Water (AW) to the surfacemixed layer and sea ice. The upward release ofAWheat is regulated by the stability of the overlying halocline, which we show has weakened substantially in recent years. Shoaling of theAWhas also contributed, with observations in winter 2017-18 showing AWat only 80m depth, just below the wintertime surfacemixed layer, the shallowest in our mooring records. The weakening of the halocline for several months at this time implies that AW heat was linked to winter convection associated with brine rejection during sea ice formation. This resulted in a substantial increase of upward oceanic heat flux during the winter season, froman average of 3-4W m(-2) in 2007-08 to.10Wm(-2) in 2016-18. This seasonalAWheat loss in the easternEBis equivalent to a more than a twofold reduction of winter ice growth. These changes imply a positive feedback as reduced sea ice cover permits increased mixing, augmenting the summer-dominated ice-albedo feedback.

A 15‐year (2004–2018) record of mooring observations from the upper 50 m of the ocean in the eastern Eurasian Basin reveals increased current speeds and vertical shear, associated with an increasing coupling between wind, ice, and the upper ocean over 2004–2018, particularly in summer. Substantial increases in current speeds and shears in the upper 50 m are dominated by a two times amplification of currents in the semidiurnal band, which includes tides and wind‐forced near‐inertial oscillations. For the first time the strengthened upper ocean currents and shear are observed to coincide with weakening stratification. This coupling links the Atlantic Water heat to the sea ice, a consequence of which would be reducing regional sea ice volume. These results point to a new positive feedback mechanism in which reduced sea ice extent facilitates more energetic inertial oscillations and associated upper‐ocean shear, thus leading to enhanced ventilation of the Atlantic Water.

Sea ice, an intrinsic component of the Arctic system, is undergoing rapid change. Sea ice dynamics play a role in the distributions of trace metals in Arctic waters through the incorporation, transport, and release of particles derived from atmospheric, sedimentary, and biological sources. Particulate (>0.2 mu m) trace metals (Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, Ba, and Pb) were measured in Arctic pack ice, associated snow, and underlying surface waters collected from September to October 2015 during the US GEOTRACES Western Arctic cruise (GN01). Sampled ice contained low sediment loads, was permeable, and had undergone desalination prior to collection. To assess the lability and refractory nature of particles from snow, sea ice, and underlying surface waters, samples were subjected to an acetic acid leach solution prior to complete digestion. In general, snow particles were of lithogenic origin, with enrichment of Co, Ni, Cu, and Zn at one station in the Canada Basin. Lower than expected particulate metal loads were observed within the sea ice matrix at all stations. Our measurements of the top 1 m of the ice column yielded higher loads for Al, and Fe (88 and 23 mu mol m(-2), respectively), intermediate loads for Mn, Zn, and Ba (0.82, 0.38, and 0.12 mu mol m(-2), respectively), and lower loads for Co, Ni, Cu, Cd, and Pb (20, 50, 40, 1, and 20 nmol m(-2), respectively). Because sediment-laden "dirty ice" was not sampled during this study, these values likely reflect the lower range of particulate metal loads in Arctic sea ice. To determine heterogeneity at the meter-scale (within station) vs the mesoscale (among stations) multiple cores were collected at each sea ice station. Particulate Al and Fe were the only two metals with a discernible pattern of greater heterogeneity at the mesoscale for the sampled ice. These two metals also showed a distinct atmospheric source, while Cd and Pb appeared to have a source from the surface seawater below the ice. Except for Fe, labile particulate metals were close to, or at, the detection limit. Low leachable particulate metal fractions in snow and sea ice could reflect prior in situ leaching of particles in contact with brine pockets and/or a consequence of procedural artifacts during melting. As multiyear ice becomes less abundant in the Arctic Ocean, the reservoir of particulate metals previously exported to the North Atlantic via sea ice will instead be released within Arctic waters during the melting season, impacting dissolved metal loads and the export of particulate metals.

Fronts in the NO parameter, a semiconservative tracer combining nitrate and dissolved oxygen, and dynamic height were observed in the central East Siberian Sea that distinguished Atlantic and Pacific contributions to the upper halocline of the Amerasian Basin during the summer of 2015. The NO front was aligned with the Transpolar Drift, and its position over the Mendeleyev Ridge indicates that Pacific waters were generally restricted to the Canada Basin and did not spread to the central Arctic. This interpretation lies in contrast to the distribution of Pacific water fractions, calculated using established relationships between nitrate and phosphate, and indicates that traditional tracers used to quantify Pacific water contributions to the Arctic Ocean are no longer accurate.

The diffusive layering (DL) form of double-diffusive convection cools the Atlantic Water (AW) as it circulates around the Arctic Ocean. Large DL steps, with heights of homogeneous layers often greater than 10 m, have been found above the AW core in the Eurasian Basin (EB) of the eastern Arctic. Within these DL staircases, heat and salt fluxes are determined by the mechanisms for vertical transport through the high-gradient regions (HGRs) between the homogeneous layers. These HGRs can be thick (up to 5 m and more) and are frequently complex, being composed of multiple small steps or continuous stratification. Microstructure data collected in the EB in 2007 and 2008 are used to estimate heat fluxes through large steps in three ways: using the measured dissipation rate in the large homogeneous layers; utilizing empirical flux laws based on the density ratio and temperature step across HGRs after scaling to account for the presence of multiple small DL interfaces within each HGR; and averaging estimates of heat fluxes computed separately for individual small interfaces (as laminar conductive fluxes), small convective layers (via dissipation rates within small DL layers), and turbulent patches (using dissipation rate and buoyancy) within each HGR. Diapycnal heat fluxes through HGRs evaluated by each method agree with each other and range from ~2 to ~8 W m−2, with an average flux of ~3–4 W m−2. These large fluxes confirm a critical role for the DL instability in cooling and thickening the AW layer as it circulates around the eastern Arctic Ocean.

Arctic Expedition (GN01, HLY1502).

The first full transarctic section of Ra-228 in surface waters measured during GEOTRACES cruises PS94 and HLY1502 (2015) shows a consistent distribution with maximum activities in the transpolar drift. Activities in the central Arctic have increased from 2007 through 2011 to 2015. The increased Ra-228 input is attributed to stronger wave action on shelves resulting from a longer ice-free season. A concomitant decrease in the Th-228/Ra-228 ratio likely results from more rapid transit of surface waters depleted in Th-228 by scavenging over the shelf. The Ra-228 activities observed in intermediate waters (<1,500 m) in the Amundsen Basin are explained by ventilation with shelf water on a time scale of about 15-18 years, in good agreement with estimates based on SF6 and I-129/U-236. The Th-228 excess below the mixed layer up to 1,500m depth can complement Th-234 and Po-210 as tracers of export production, after correction for the inherent excess resulting from the similarity of Ra-228 and Th-228 decay times. We show with a Th/Ra profile model that the Th-228/Ra-228 ratio below 1,500m is inappropriate for this purpose because it is a delicate balance between horizontal supply of Ra-228 and vertical flux of particulate Th-228. The accumulation of Ra-226 in the deep Makarov Basin is not associated with an accumulation of Ba and can therefore be attributed to supply from decay of Th-230 in the bottom sediment. We estimate a ventilation time of 480 years for the deep Makarov-Canada Basin, in good agreement with previous estimates using other tracers.

Abstract. This study discusses along-slope volume, heat, and salt transports derived from observations collected in 2013–15 using a cross-slope array of six moorings ranging from 250 m to 3900 m in the eastern Eurasian Basin (EB) of the Arctic Ocean. These observations demonstrate that in the upper 780 m layer, the along-slope boundary current advected, on average, 5.1 ± 0.1 Sv of water, predominantly in the eastward (shallow-to-right) direction. Monthly net volume transports across the Laptev Sea slope vary widely, from ~ 0.3 ± 0.8 in April 2014 to ~ 9.9 ± 0.8 Sv in June 2014. 3.1 ± 0.1 Sv (or 60 %) of the net transport was associated with warm and salty intermediate-depth Atlantic Water (AW). Calculated heat transport for 2013–15 (relative to −1.8 °C) was 46.0 ± 1.7 TW, and net salt transport (relative to zero salinity) was 172 ± 6 Mkg/s. Estimates for AW heat and salt transports were 32.7 ± 1.3 TW (71 % of net heat transport) and 112 ± 4 Mkg/s (65 % of net salt transport). The variability of currents explains ~ 90 % of the variability of the heat and salt transports. The remaining ~ 10 % is controlled by temperature and salinity anomalies together with temporal variability of the AW layer thickness. The annual mean volume transports decreased by 25 % from 5.8 ± 0.2 Sv in 2013–14 to 4.4 ± 0.2 Sv in 2014–15 suggesting that changes of the transports at interannual and longer time scales in the eastern EB may be significant.

The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017.This article is part of a special issue entitled: "Cycles of trace elements and isotopes in the ocean – GEOTRACES and beyond" - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.

The Eurasian Basin (EB) of the Arctic Ocean is subject to substantial seasonality. We here use data collected between 2013 and 2015 from six moorings across the continental slope in the eastern EB and identify three domains, each with its own unique seasonal cycle: 1) The upper ocean (<100 m), with seasonal temperature and salinity differences of Δθ = 0.16°C and ΔS = 0.17, is chiefly driven by the seasonal sea ice cycle. 2) The upper-slope domain is characterized by the influence of a hydrographic front that spans the water column around the ~750-m isobath. The domain features a strong temperature and moderate salinity seasonality (Δθ = 1.4°C; ΔS = 0.06), which is traceable down to ~600-m depth. Probable cause of this signal is a combination of along-slope advection of signals by the Arctic Circumpolar Boundary Current, local wind-driven upwelling, and a cross-slope shift of the front. 3) The lower-slope domain, located offshore of the front, with seasonality in temperature and salinity mainly confined to the halocline (Δθ = 0.83°C; ΔS = 0.11; ~100–200 m). This seasonal cycle can be explained by a vertical isopycnal displacement (ΔZ ~ 36 m), arguably as a baroclinic response to sea level changes. Available long-term oceanographic records indicate a recent amplification of the seasonal cycle within the halocline layer, possibly associated with the erosion of the halocline. This reduces the halocline’s ability to isolate the ocean surface layer and sea ice from the underlying Atlantic Water heat with direct implications for the evolution of Arctic sea ice cover and climate.

Certification of trace metals in seawater certified reference materials (CRMs) NASS-7 and CASS-6 is described. At the National Research Council Canada (NRC), column separation was performed to remove the seawater matrix prior to the determination of Cd, Cr, Cu, Fe, Pb, Mn, Mo, Ni, U, V, and Zn, whereas As was directly measured in 10-fold diluted seawater samples, and B was directly measured in 200-fold diluted seawater samples. High-resolution inductively coupled plasma mass spectrometry (HR-ICPMS) was used for elemental analyses, with double isotope dilution for the accurate determination of B, Cd, Cr, Cu, Fe, Pb, Mo, Ni, U, and Zn in seawater NASS-7 and CASS-6, and standard addition calibration for As, Co, Mn, and V. In addition, all analytes were measured using standard addition calibration with triple quadrupole (QQQ)-ICPMS to provide a second set of data at NRC. Expert laboratories worldwide were invited to contribute data to the certification of trace metals in NASS-7 and CASS-6. Various analytical methods were employed by participants including column separation, co-precipitation, and simple dilution coupled to ICPMS detection or flow injection analysis coupled to chemiluminescence detection, with use of double isotope dilution calibration, matrix matching external calibration, and standard addition calibration. Results presented in this study show that majority of laboratories have demonstrated their measurement capabilities for the accurate determination of trace metals in seawater. As a result of this comparison, certified/reference values and associated uncertainties were assigned for 14 elements in seawater CRMs NASS-7 and CASS-6, suitable for the validation of methods used for seawater analysis.

Data collected during the US Arctic GEOTRACES expedition in 2015 are used to estimate the mean residence time of dissolved trace elements (Fe, Mn, Ni, Cd, Zn, Cu, Pb, V) in surface water with respect to atmospheric deposition. The calculations utilize mixed layer trace element (TE) inventories, aerosol solubility determinations, and estimates of the atmospheric trace element flux into the upper ocean. The trace element flux is estimated by the product of the Be-7 flux (determined by the ocean Be-7 inventory) and the TE/Be-7 ratio of aerosols. This method has been established elsewhere and is tested here by comparing Be-7-derived TE flux to the measured TE accumulation in recently deposited snow. Given the variability in snow and aerosol TE concentration observed over the expedition, and the limited timescale of the observations, agreement between the two methods is reasonable. While there are assumptions in these calculations, the distribution of residence times with respect to atmospheric input across the expedition track informs us of additional sources or sinks for each element. The residence time of dissolved Fe was similar to 20-40 y for most stations. However, several stations that display a longer, oceanographically inconsistent apparent Fe residence time of similar to 300-500 years are likely influenced by additional input from the Transpolar Drift (TPD), which has been shown to convey shelf water properties to the central Arctic. This was seen for Cu, Ni and Zn as well. The flux of Fe delivered by the TPD was similar to 10 nmol/m(2)/d for these stations, an order of magnitude greater than the soluble atmospheric input. On the other hand, V and Pb show a decrease in the apparent residence times within TPD water, suggesting removal of these elements from the source region of the TPD. For Mn, there is no obvious trend in residence time among the stations; however the apparent residence time (400-1400 y) is significantly greater than the similar to 20 y calculated for atmospheric input elsewhere, signifying appreciable input from other sources. It has been suggested that about 90% of Mn input to the Arctic Ocean originates from Arctic rivers, shelf sediments, and coastal erosion. Results here suggest a flux from these sources of similar to 30 nmol/m(2)/d which is significantly greater than the atmospheric input of Mn in the Arctic.