Due to the widely application of Pcs in the fields, such as the communication, medical treatment, chemical industry and so on, therefore, it have been a hot research topic over several decades by scientists. However, along with the human society development and the progress in science and technology, the new phthalocyanine with novlecharacteristics is still the goal of the scientists. In this dissertion, the synthetic methods of the phthlocyanine are improved. The 4, 8, 15, 22-tetra[3, 3-bis (phydroxyphenyl)phthalide] phthalocyanines were synthesized and characterized. Using 3-[3, 3-bis(p-hydroxyphenyl) phthalide] 2, 3-dicyanonitrobenzene and copper acetate monohydrate, dehydrate nicle acetate as starting materials in n-pentanol, DBU as a catalyst, to synthesize 4, 8,15, 22-tetra[3, 3-bis(p-hydroxyphenyl) phthalide] phthalocyanines. The phthalocyanines were characterized, then the results proved that compounds were the target products. And the relevant ultraviolet spectrum, fluorescence spectroscopy and optical luminescence spectroscopy properties were studied..

In this dissertation, we study the synthesis and character of new substituted Phthalocyanine. Due to the widely application of Pcs in the fields, such as the communication, medical treatment, chemical industry and so on, therefore, they have been a hot topic over several decades by scientists. Nowadays, scientists have prepared thousands of Pcs and their derivatives. However, along with the human society development and the progress in science and technology, the new phthalocyanine with novle characteristics are still the goal of the scientists. In this dissertion, the synthetic methods of the phthlocyanine is improved. The synthesis and characterization of 1,11,15,25-tetrahydroxy-4,8,18,22-di(bridged dipropionate carboxyl) phthalocyanines are reported in this paper. The mixtures of malonic acid and 3,6-dihydroxy-phthalonitrile was added to water under stiriing. Then, a catalyst amount of sulfuric acid was added. The first synthetic precursor, i. e., malonic acid 3,3'-bis(6-hydroxy phthalonitrile) butter, its molecular formula is C19H8N4O6. phthalocyanines was prepared by malonic acid 3,3'-bis(6-hydroxy phthalonitrile) butter and dihydrate zinc acetate, copper acetate monohydrate in n-amyl alcohol, using DBU as a catalyst under the 135 °C, molecular formula of phthalocyanine complexes is C38H16N8O12M. The product was characterized by Ultraviolet-visible (UV/Vis) Spectrum absorption and fluorescence, The results are agreement with the proposed structures. And electrochemical properties were studied.

通过用1,3-二亚氨基异吲哚啉和二水乙酸合镍为反应原料,在不同有机溶剂中,以不同物质的量的催化剂,用溶剂热合成法直接合成酞菁镍晶体的过程,来探究酞菁镍晶体的最优化合成工艺.通过控制不同的反应条件,如反应温度、反应时间、催化剂等来确定反应最佳条件,为酞菁镍晶体的合成工艺提供理论依据.通过实验得出合成酞菁镍的最优化工艺条件是反应温度为270℃,溶剂为喹啉,体积为14 mL,反应时间为8h.

Water oxidation to produce oxygen as a means of renewable energy applications has attracted intense interest. However, the oxygen evolution reaction (OER) is still a huge challenge due to its a kinetically slow process requiring high overpotential. Therefore, the design and fabrication of highly active, durable, and cost-effective electrocatalysts are crucial. Here, we demonstrate the graphene/Ni-Fe layered double-hydroxide (RGO-Ni-Fe LDH) composite as highly active and durable electrocatalyst for OER, which exhibits excellent OER activity with a small overpotential (similar to 250 mV in 0.1 M KOH) based on the onset of catalytic current and stability. Furthermore, the electrocatalytic activity of RGO-Ni-Fe LDH composite is much better than that of others similar structures of electrocatalysts. (C) 2015 Elsevier Ltd. All rights reserved.

A novel copper phthalocyanine complex with bridging butanedioic acid moieties, 1,11,15,25-tetrahydroxy-4,8,18,22-bis(bridging butanedioic acid) phthalocyanine copper, is reported. This complex is soluble in chloroform, THF, DMSO and DMF, and sparingly soluble in i-PrOH. The compound is characterized by elemental analysis, IR, H-1 NMR and UV/Vis spectroscopies and MALDI-TOF-MS. Cyclic voltammetry showed that the complex exhibited well-defined ring-based reduction and oxidation processes. NIR OLEDs containing tris-(8-hydroxyquinoline) aluminum doped with the copper phthalocyanine complex were fabricated. Room-temperature electroluminescence was observed near 1098 nm originating from the transition from the first excited singlet state to the ground state. (C) 2015 Elsevier B.V. All rights reserved.

首次对一系列氮杂酞菁荧光谱图性质研究,这些酞菁是氮杂酞菁铜、氮杂酞菁锌、氮杂酞菁钴、氮杂酞菁镍和氮杂酞菁汞,这5种氮杂金属酞菁的荧光谱图性质进行研究与比较.发现有所不同,原因是中心金属原子的不同而引起.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

C27H51Mo12N6O40P, trigonal, R3c (no. 161), a = 20.212(5) Å, c = 23.801(5) Å, V = 8420.8 Å3, Z = 6, Rgt(F) = 0.0318, wRref(F2) = 0.0610, T = 293 K.

C8H14N8S2, monoclinic, P21/n (no. 14), a = 8.455(1) Å, b = 9.7574(8) Å, c = 8.9024(9) Å, β = 116.23(1)°, V = 658.8 Å3, Z = 2, Rgt(F) = 0.0528, wRref(F2) = 0.1224, T = 293 K.

因为酞菁在信息、医疗、化工等众多领域有很广泛的应用,所以近百年来一直是科学家研究的热点课题.本文首次对一系列氮杂金属酞菁谱图性质研究,这些酞菁是氮杂酞菁铜、氮杂酞菁锌、氮杂酞菁钴、氮杂酞菁镍和氮杂酞菁汞,这5种氮杂金属酞菁的红外光谱图性质进行研究与比较.这些原因主要和中心配位为金属原子不同引起的.

Abstract C12H10ClCuN6, monoclinic, P21/n (no. 14), a = 7.7819(4) Å, b = 12.9634(6) Å, c = 12.4449(6) Å, β = 91.456(4)°, V = 1255.0 Å3, Z = 4, Rgt(F) = 0.0474, wRref(F2) = 0.0938, T = 293 K.

The relationships between Confucian essence and modem concept of the honor and disgrace were discussed in this paper. Eight key words of the Confucian culture ＂benevolence, righteousness, propriety, wisdom, faith, loyalty, diligence and frugality＇can brilliantly summarize and condense ＂eight honors and eight disgraces＂. ＂Eight honors and eight disgraces＂ make new interpretation with the characteristics of times to Confucian eight virtues, and show the academic quality of the Confucian culture keeping pace with the times.

C36H26CoN9O, monoclinic, P2(1)/n (no. 14), a = 13.3290(5) angstrom, b = 12.5385(5) angstrom, c = 18.3604(8) angstrom, beta = 103.007(4)degrees, V = 2989.8 angstrom(3), Z = 4, R-gt(F) = 0.056, wR(ref)(F-2) = 0.121, T = 293 K.

C10H8Cd2O7, monoclinic, P2(1)/n (no. 14), a = 6.886(5) angstrom, b = 7.359(5) angstrom, c = 22.779(5) angstrom, beta = 94.518(5)degrees, V = 1150.7 angstrom(3), Z = 4, R-gt(F) = 0.042, wR(ref)(F-2) = 0.096, T = 293 K.

C18H20CuN4O7, orthorhombic, Pccn (no. 56), a = 21.6590(4) angstrom, b = 11.0123(3) angstrom, c = 16.9230(6) angstrom, V = 4036.4 angstrom(3), Z = 8, R-gt(F) = 0.030, wR(ref)(F-2) = 0.051, T = 293 K.

C25H23Cl2CuN3, monoclinic, P12(1)/c1 (no. 14), a = 7.8744(3) angstrom, b = 10.9456(5) angstrom, c = 25.939(1) angstrom, beta = 94.129(3)degrees, V = 2229.9 angstrom(3), Z = 4, R-gt(F) = 0.053, wR(ref)(F-2) = 0.120, T = 293 K.

历代学者都在研究《中庸》，他们立足于自己的时代，从不同角度对这部著作进行研读和解释．近年来，随着国学研究的升温，人们更加注重对它的解读，这里首次对《中庸》中的“诚”所体现的规律进行了研究，研究发现书中对“诚”的论述体现了著者对人与自然界共同遵循的规律、人可以认识和利用规律、人类社会也是有规律可循的这样一些问题的哲学思考．

C48H58N8NiO6, triclinic, P (1) over bar (no. 2), a = 9.1579(4) angstrom, = 10.8716(5) angstrom, c = 12.4645(6) angstrom, alpha =74.678(4)degrees, beta = 83.415(4)degrees, gamma = 67.395(4)degrees, V = 1104.8 angstrom(3), Z = 1, R-gt(F)= 0.035, wR(ref)(F-2) = 0.081, T = 293 K.

C18H20N4NiO7, orthorhombic, Pccn (no. 56), a = 21.9716(5) angstrom, b = 10.9527(3) angstrom, c = 16.6617(5) angstrom, V = 4009.6 angstrom(3), Z = 8, R-gt(F) = 0.031, wR(ref)(F-2) = 0.050, T = 293 K.

In this article,we first take 3,6-dihydroxy-phthalonitrile and chlorinated n-butane as the starting reactants to prepare 1,4,8,11,15,18,22,25-octa-butoxy copper phthalocyanine,3,6-dibutoxy phthalonitrile were prepared through nucleophilic substitution reaction in the solvent of DMF under the catalysis of anhydrous potassium carbonate.The mixture of 3,6-dibutoxy phthalonitrile and CuCl were used as precursors to synthesis 1,4,8,11,15,18,22,25-octa-butoxy copper phthalocyanine which was generated by cyclotetramerisation in the presence of 1,8-diazabicyclo undec-7-ene(DBU).At last,the compound was characterized by elemental analysis,infrared,fluorescence and UV-visible spectrum and atomic absorption,which were proving its structure.Thus confirmed that the product was the target compound.