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1ChemInform Abstract: THE RADICAL ANIONS OF 5,5′‐ AND 6,6′‐BIAZULENYL

F GERSON,J LOPEZ,A METZGER,C JUTZ

AbstractESR. and, in part, ENDOR. studies are reported on the radical anions of 5,5′‐and 6,6′‐biazulenyl (1 and 2, resp.), as well as on their 1, 1′, 3, 3′‐tetradeuterioderivatives (1‐d4 and 2‐d4). The reduction processes of 1 and 2 leading to these radical anions (\documentclass{article}\pagestyle{empty}\begin{document}$ 1^{\ominus \atop \dot{}}$\end{document} and \documentclass{article}\pagestyle{empty}\begin{document}$ 2^{\ominus \atop \dot{}}$\end{document}) and the dianions ( equation image ) have been investigated by polarography and cyclic voltammetry. The half‐wave reduction potential of 1 and the π‐spin distribution in \documentclass{article}\pagestyle{empty}\begin{document}$ 1^{\ominus \atop \dot{}}$\end{document} are consistent with the model of two weakly interacting azulene π‐systems, whereas the analogous findings for 2 and \documentclass{article}\pagestyle{empty}\begin{document}$ 2^{\ominus \atop \dot{}}$\end{document} point to a strong interaction between two such systems. This difference can be traced to the distinct inequality ∥c65 ∥ « ∥ c66 ∥ in the LCAO coefficients c6μ at the centres μ=5 and 6 for the LUMO Ψ6 of azulene.

1981Chemischer Informationsdienst（1981）引用：25

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2ChemInform Abstract: PYRIDINES BY ELECTROCYCLIZATION WITH ELIMINATION

C. JUTZ, H.‐G. LOEBERING, K. H. TRINKL

Abstract3‐Aminocrotonsäureester (Ia) und 3‐Aminocrotonnitril (Ib) kondensieren mit Vinamidinium‐Salzen (II) und Natriummethanolat oder mit 3,3‐Diäthoxy‐1‐dimethylaminopropenen (IV) in guten Ausbeuten zu Pyridin‐Derivaten (III) und (V).

1977Chemischer Informationsdienst

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3Umsetzung Von Vinylogen Formamidiniumsalzen Mit Nucleophilen, III. Über Die Reduktion Von Polymethiniumsalzen Mit Natriumtetra‐hydroborat. Eine Methode Zum Aufbau Substituierter 1,3‐Diaminopropane

C JUTZ, AF KIRSCHNER,RM WAGNER

Die Einwirkung von überschüssigem Natriumtetrahydroborat auf Polymethiniumsalze verläuft unter Reduktion der Iminium- und der Enamin-Doppelbindung. Substituierte 1,3-Diaminopropane (4a–q) werden durch die Boranatreduktion der Trimethiniumsalze 3a–k und der vinylogen Formamidine 51–q dargestellt. Reaction of Vinylogous Formamidinium Salts with Nucleophiles, III. On the Reduction of Polymethinium Salts with Sodium Tetrahydroborate. A Method for the Synthesis of Substituted 1,3-Diaminopropanes The action of sodium tetrahydroborate in excess on polymethinium salts proceeds by reduction of the double bonds of the iminium and enamine groups. Numerous substituted 1,3-diaminopropanes (4a–q) were prepared by boranate reduction of trimethinium perchlorates 3a–k and vinylogous formamidines 51–q.

1977CHEMISCHE BERICHTE-RECUEIL（1977）引用：21

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4Pyridines Via Electrocyclic Ring-Closure With Elimination

C Jutz, Hg Lobering, Kh Trinkl

1977SYNTHESIS-STUTTGART（1977）

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5Azuleno(1,2-F)Azulene, Tetracyclic, Non-Benzoid, Aromatic Hydrocarbon

C JUTZ,HG PEUKER,W KOSBAHN

AbstractAzulen‐2‐acetonitril (I) kondensiert mit 6‐Dimethylamino‐2‐dimethyliminomethylfulven‐perchlorat (II) in Chinolin in Gegenwart von Natriummethylat zum Azulenaminonitril (III), das beim Erhitzen auf 120‐130°C zum Azuleno(1,2‐f)azulen (IV) cyclisiert.

1976SYNTHESIS-STUTTGART（1976）

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6The Electronic Structure of Azuleno[1,2,3‐cd]phenalene and Azuleno[5,6,7‐cd]phenalene, a Comparison

R GLEITER,J SPANGETLARSEN,EW THULSTRUP,I MURATA,K NAKASUJI,C JUTZ

AbstractThe photoelectron (PE.) spectra of azuleno[l, 2, 3‐cd]phenalene (1) and azuleno‐ [5,6,7‐cd]phenalene(2) have been recorded. The first five bands of both compounds could be assigned to transitions corresponding to removal of electrons from 4a2, 6b1, 5b1, 3a2 and 4bl orbitals. This assignment is based mainly on a comparison between the observed ionization potentials and orbital energies calculated in a HMO and a PPP model.The UV./VIS. polarized absorption spectrum of 1 in the region 10000–45000 cm−1 has been measured by means of the stretched film technique. The measurements were performed in polyethylene sheets at 77°K. Several bands could be assigned to π* ← π transitions calculated by a PPP‐CI method.A comparison between the electronic structures of 1 and2 is made by means of a simple HMO diagram.

1976Chemischer Informationsdienst（1976）引用：17

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7Benzo(B)Biphenylene From Biphenylene Derivatives By Means Of Electrocyclic Ring-Closure

C Jutz, Hg Peuker

1975SYNTHESIS-STUTTGART（1975）

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8REACTION OF VINYLOGOUS FORMAMIDINIUM SALTS WITH NUCLEOPHILES .2. POLYMETHINIUM SALTS FROM METHYLENE-ACTIVE KETONES

C JUTZ, RM WAGNER, A KRAATZ, HG LOBERING

1975ANNALEN DER CHEMIE-JUSTUS LIEBIG（1975）

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9A Novel Simple Synthesis of Helicenes

C JUTZ, HG LOBERING

1975ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH（1975）引用：21

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10ChemInform Abstract: BENZO(B)BIPHENYLEN AUS BIPHENYLEN‐DERIVATEN DURCH ELEKTROCYCLISCHEN RINGSCHLUSS

C. JUTZ, H. G. PEUKER

AbstractBiphenylen‐2‐acetonitril (I) kondensiert sich mit den Diazapentadieniumperchloraten (II) in Chinolin in Gegenwart von Natriummethylat bei 50‐70°C zu den Verbindungen (III), die bei Temperaturen von 145 ‐ 205°C zu den Benzo(b)biphenylenen (IV) cyclisieren.

1975Chemischer Informationsdienst

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11Improved Synthesis Of Dicyclopenta[Ef,Kl]Heptalene

C Jutz, Schweige.E

1974SYNTHESIS-STUTTGART（1974）

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12A New Synthesis of Indolizines

C JUTZ,RM WAGNER, HG LOBERING

Angewandte Chemie International Edition in EnglishVolume 13, Issue 11 p. 737-739 Communication A New Synthesis of Indolizines† Prof. Dr. Christian Jutz, Corresponding Author Prof. Dr. Christian Jutz Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this authorDr. Rudolf M. Wagner, Dr. Rudolf M. Wagner Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this authorDipl.-Chem. Hans-G. Löbering, Dipl.-Chem. Hans-G. Löbering Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this author Prof. Dr. Christian Jutz, Corresponding Author Prof. Dr. Christian Jutz Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this authorDr. Rudolf M. Wagner, Dr. Rudolf M. Wagner Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this authorDipl.-Chem. Hans-G. Löbering, Dipl.-Chem. Hans-G. Löbering Organisch-Chemisches Laboratorium der Technischen Universität, 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this author First published: November 1974 https://doi.org/10.1002/anie.197407371Citations: 21 † This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Citing Literature Volume13, Issue11November 1974Pages 737-739 RelatedInformation

1974Angewandte Chemie International Edition（1974）引用：31

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13[Synthesis of 2,3-Acepyrene and 6,7-Aceazuleno(5,6,7-cd)phenalene; Relationships Between Structure and Promoting or Inhibiting Effects on the Biogenesis of Zoxazolamine Hydroxylase in the Pyrene Series].

N P Buu-Hoi,P Jacquignon,J P Hoeffinger,C Jutz

1972Bulletin de la Societe chimique de France（1972）引用：23

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14Synchronous Six‐Electron Cyclization of Hexatriene Systems As a New Synthetic Principle for Preparation of Aromatic and Heteroaromatic Compounds

C JUTZ,RM WAGNER

Angewandte Chemie International Edition in EnglishVolume 11, Issue 4 p. 315-318 Communication Synchronous Six-Electron Cyclization of Hexatriene Systems as a New Synthetic Principle for Preparation of Aromatic and Heteroaromatic Compounds† Prof. Dr. Christian Jutz, Prof. Dr. Christian Jutz Organisch-Chemisches Laboratorium der Technischen Universität, 8 München, Arcisstrasse 21 (Germany)Search for more papers by this authorDipl.-Chem. Rudolph M. Wagner, Corresponding Author Dipl.-Chem. Rudolph M. Wagner Organisch-Chemisches Laboratorium der Technischen Universität, 8 München, Arcisstrasse 21 (Germany)Organisch-Chemisches Laboratorium der Technischen Universität, 8 München, Arcisstrasse 21 (Germany)Search for more papers by this author Prof. Dr. Christian Jutz, Prof. Dr. Christian Jutz Organisch-Chemisches Laboratorium der Technischen Universität, 8 München, Arcisstrasse 21 (Germany)Search for more papers by this authorDipl.-Chem. Rudolph M. Wagner, Corresponding Author Dipl.-Chem. Rudolph M. Wagner Organisch-Chemisches Laboratorium der Technischen Universität, 8 München, Arcisstrasse 21 (Germany)Organisch-Chemisches Laboratorium der Technischen Universität, 8 München, Arcisstrasse 21 (Germany)Search for more papers by this author First published: April 1972 https://doi.org/10.1002/anie.197203151Citations: 49 † This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Citing Literature Volume11, Issue4April 1972Pages 315-318 RelatedInformation

1972ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（1972）引用：76

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15Simple Synthesis of Pyraceheptylene and Benzo[A]-Pyraceheptylene

C JUTZ, SCHWEIGE.E

Angewandte Chemie International Edition in EnglishVolume 10, Issue 11 p. 808-809 Communication Simple Synthesis of Pyraceheptylene and Benzo[a]pyraceheptylene† Prof. Dr. Christian Jutz, Prof. Dr. Christian Jutz Organisch-Chemisches Laboratorium der Technischen Universität 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this authorDipl.-Chem. Erich Schweiger, Corresponding Author Dipl.-Chem. Erich Schweiger Organisch-Chemisches Laboratorium der Technischen Universität 8 München 2, Arcisstrasse 21 (Germany)Organisch-Chemisches Laboratorium der Technischen Universität 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this author Prof. Dr. Christian Jutz, Prof. Dr. Christian Jutz Organisch-Chemisches Laboratorium der Technischen Universität 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this authorDipl.-Chem. Erich Schweiger, Corresponding Author Dipl.-Chem. Erich Schweiger Organisch-Chemisches Laboratorium der Technischen Universität 8 München 2, Arcisstrasse 21 (Germany)Organisch-Chemisches Laboratorium der Technischen Universität 8 München 2, Arcisstrasse 21 (Germany)Search for more papers by this author First published: November 1971 https://doi.org/10.1002/anie.197108081Citations: 15 † This work has been supported by the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article.Citing Literature Volume10, Issue11November 1971Pages 808-809 RelatedInformation

1971ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（1971）引用：28

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16Uber Die Vilsmeir-Formylierung Von Ungesattigten Kohlenwasserstoffen 2

C JUTZ,W MULLER

Die Lokalisationsenergien L einer Anzahl konjugierter Polyene weisen auf ihre leichte Substituierbarkeit durch Vilsmeier‐Komplexe hin. Bei Kohlenwasserstoffen mit dem System des 2‐Vinyl‐butadiens‐(1.3) und 2‐Phenyl‐butadiens‐(1.3) gelingt Monoformylierung zu Imoniumsalzen. Isobutylen wird fünffach zu einem gelben Trikation substituiert, beim 2‐Phenyl‐propen konnten die Salze der Mono‐ und Triformylierung isoliert werden.

1966Chemische Berichte（1966）引用：75

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17Studies On Azalogous Sesquifulvapolyenes

C Jutz, Kirchlec.R, W Muller

1965ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（1965）

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18Methinfarbstoffe Metallorganischer Verbindungen Diferrocenylmethin-Perchlorat

1959TETRAHEDRON LETTERS（1959）引用：69

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19Synthese Von Azulen‐polyenalen

Angewandte ChemieVolume 70, Issue 9 p. 270-270 Zuschriften Synthese von Azulen-polyenalen Dr. C. Jutz, Dr. C. Jutz Organisch-Chemisches Institut der T. H. MünchenSearch for more papers by this author Dr. C. Jutz, Dr. C. Jutz Organisch-Chemisches Institut der T. H. MünchenSearch for more papers by this author First published: 7. Mai 1958 https://doi.org/10.1002/ange.19580700909Citations: 15AboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat No abstract is available for this article. References 1 Vgl. Naturwissenschaften 44, 352 [1957] u. Diese Ztschr. 69, 532 [1957]. 2 Vgl. Diese Ztschr. 69, 104 [1957]. Citing Literature Volume70, Issue97. Mai 1958Pages 270-270 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation

1958Angewandte Chemie（1958）引用：26

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D. Grosse

D. Grosse合作论文数2

R Zimmergaller

R Zimmergaller合作论文数1

Werner Müller

Werner Müller合作论文数1

Np Buuhoi

Np Buuhoi合作论文数1

K. NAKASUJI

K. NAKASUJI合作论文数1

Alfred Treibs

Alfred Treibs合作论文数1

R. Gleiter合作论文数Institute of Organic Chemistry, Fakultät für Chemie und Geowissenschaften, Universität Heidelberg1

Jens Spanget-Larsen合作论文数Department of Life Sciences and Chemistry, Roskilde University1

Pierre Jacquignon

Pierre Jacquignon合作论文数1

Isao Murata合作论文数Division of Sustainable Energy and Environmental Engineering,Graduate School of Engineering,Osaka University1

Erik W Thulstrup

Erik W Thulstrup合作论文数1

Herr H. Amschler

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J. P. Hoeffinger

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