Overshooting storms are convective systems with updrafts that penetrate through the tropopause into the overlying stratosphere. These storms can rapidly transport a wide variety of chemical species and aerosols from the boundary layer and free troposphere directly to the stratosphere. The central plains of the U.S. and the Sierra Madre Occidental of Mexico are two of the global hotspots for overshooting convection. While the existence of these storms has been known for several decades, the amount of tropospheric air, including water vapor, trace gases, and aerosols, transported across the tropopause is poorly understood, as is their impact on the dynamics, chemistry, and radiative balance of the stratosphere. Climate models suggest that as Earth’s climate continues to warm, overshooting convection over the U.S. may increase, potentially causing changes to stratospheric composition and transport. To address these scientific questions, the NASA ER-2 high-altitude research aircraft flew 31 missions during the summers of 2021 and 2022 to make observations of the outflow from overshooting storms in the stratosphere over North America and the eastern Pacific Ocean as part of the Dynamics and Chemistry of the Summer Stratosphere (DCOTSS) project. The ER-2 carried a payload of 12 instruments to measure meteorological parameters, water and its isotopologues, trace gases, and aerosol properties. Ozone, water vapor, and aerosol sondes were also launched on balloons during the field deployments. This paper describes the science goals of the DCOTSS project, the aircraft measurement strategy, the data produced by the project, and highlights of science results to date.

The mid-infrared lightweight tunable diode laser hygrometer, “Pico-Light H2O”, the successor to Pico-SDLA H2O, is presented and its performances are evaluated during the AsA 2022 balloon-borne intercomparison campaign conducted at the CNES Aire-sur-l'Adour (AsA, 43.70° N; 0.25° W) balloon launch facility and the Aeroclub d'Aire-sur-l'Adour in France. The Pico-Light instrument has primarily been developed for sounding of the upper troposphere and stratosphere, although during the AsA 2022 campaign we expand the range of comparison to include additionally the lower troposphere. Three different types of hygrometer and two models of radiosonde were flown, operated by the French Space Agency (CNES) and the NOAA Global Monitoring Laboratory (GML) scientific teams: Pico-Light H2O, the NOAA Frost Point Hygrometer (FPH), the micro-hygrometer (in an early phase of development), and M20 and iMet-4 sondes. Within this framework, we intend to validate measurements of Pico-Light H2O through a first intercomparison with the NOAA FPH instrument. The in situ monitoring of water vapour in the upper troposphere–lower stratosphere continues to be very challenging from an instrumental point of view because of the very small amounts of water vapour to be measured in these regions of the atmosphere. Between the lapse rate tropopause (11–12.3 km) and 20 km, the mean relative difference between water vapour mixing ratio measurements by Pico-Light H2O and NOAA FPH was 4.2 % ± 7.7 %, and the mean tropospheric difference was 3.84 % ± 23.64 %, with differences depending on the altitude range considered. In the troposphere, relative humidity (RH) over water comparisons led to agreement between Pico-Light and NOAA FPH of −0.2 % on average, with excursions of about 30 % RH due to moisture variability. Expanding the comparison to meteorological sondes, the iMet-4 sondes agree well with both Pico-Light and FPH between the ground and 7.5 km (within ± 3 % RH), as do the M20 sondes, up to 13 km, which are wet-biased by 3 % RH and dry-biased by 20 % in cases of saturation.

The Hunga Tonga-Hunga Ha'apai (HT-HH) volcanic eruptions on January 13 and 15, 2022, produced a plume with the highest signal in stratospheric aerosol optical depth observed since the eruption of Mt. Pinatubo in 1991. Suites of balloon -borne instruments on a series of launches from Reunion Island intercepted the HT-HH plume between 7 and 10 d of the eruptions, yielding observations of the aerosol number and size distribution and sulfur dioxide (SO2) and water vapor (H2O) concentrations. The measurements reveal an unexpected abundance of large particles in the plume, constrain the total sulfur injected to approximately 0.2 Tg, provide information on the altitude of the injection, and indicate that the formation of sulfuric acid aerosol was complete within 3 wk. Large H2O enhancements contributed as much as -30% to ambient aerosol surface area and likely accelerated SO2 oxidation and aerosol formation rates in the plume to approximately three times faster than under normal stratospheric conditions.

Satellite data records of stratospheric water vapour have been compared to balloon-borne frost point hygrometer (FP) profiles that are coincident in space and time. The satellite data records of 15 different instruments cover water vapour data available from January 2000 through December 2016. The hygrometer data are from 27 stations all over the world in the same period. For the comparison, real or constructed averaging kernels have been applied to the hygrometer profiles to adjust them to the measurement characteristics of the satellite instruments. For bias evaluation, we have compared satellite profiles averaged over the available temporal coverage to the means of coincident FP profiles for individual stations. For drift determinations, we analysed time series of relative differences between spatiotemporally coincident satellite and hygrometer profiles at individual stations. In a synopsis we have also calculated the mean biases and drifts (and their respective uncertainties) for each satellite record over all applicable hygrometer stations in three altitude ranges (10–30 hPa, 30–100 hPa, and 100 hPa to tropopause). Most of the satellite data have biases <10 % and average drifts <1 % yr−1 in at least one of the respective altitude ranges. Virtually all biases are significant in the sense that their uncertainty range in terms of twice the standard error of the mean does not include zero. Statistically significant drifts (95 % confidence) are detected for 35 % of the ≈ 1200 time series of relative differences between satellites and hygrometers.

Stratospheric aerosol plays an important role in Earth's radiative balance. Systematic measurements of stratospheric aerosol number concentration and size are needed to characterize their baseline values and variability, improve understanding of aerosol microphysics, and assess the representation of stratospheric aerosol processes in global models. In situ measurements of particle size distribution provide insight into the responses of stratospheric aerosol processes to perturbations from volcanoes and wildfires, anthropogenic emissions from rockets and aircraft, or intentional injections related to climate intervention. The Baseline Balloon Stratospheric Aerosol Profiles (B 2 SAP) project uses compact, lightweight payloads carried by meteorological balloons to measure aerosol number density and size distributions, water vapor, ozone, and meteorological data from the surface to the middle stratosphere. The long‐term goal for the B 2 SAP project is to produce climatologies of aerosol number and size distributions into the middle stratosphere at latitudinally distributed measurement sites. Since March 2019, B 2 SAP payloads have been launched from Boulder, CO, USA once to twice per month and four to six times per year from Lauder, NZ. These measurements provide a new record of in situ stratospheric aerosol observations and are being used to help validate satellite‐based estimates of stratospheric aerosol size distributions. Here we present 50 vertical profiles from Boulder, CO, from March 2019 to March 2022, to build a NH mid‐latitude climatology of stratospheric aerosol and its variability and investigate the impact of natural perturbations on stratospheric aerosol microphysics.

Balloon sounding with the Compact Optical Backscatter Aerosol Detector (COBALD) and Frost Point hygrometers (FPs) provides in situ data for a better understanding of the vertical distribution of cirrus clouds. In this study, eight summer balloon-borne measurements in Kunming (2012, 2014, 2015, and 2017) and Lhasa (2013, 2016, 2018, and 2020) over the Tibetan Plateau were used to show the distribution characteristics of cirrus clouds. Differences of cirrus occurrence were compared by different indices: the backscatter ratio (BSR) at a 455 nm/940 nm wavelength (BSR455 > 1.2/BSR940 > 2), the color index (CI > 7), and the relative humidity with respect to ice (RHice > 70%). Analysis of the profiles indicated that BSR455 > 1.2 was the optimal criterion to identify the cirrus layer and depict the distribution of the CI and RHice within cirrus clouds. The results showed that the median CI (RHice) within the cirrus clouds at both sites was mostly in the 18-20 (90%-110%) range at pressures below 120 hPa. Furthermore, the balloon-borne measurements combined with Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) measurements indicated a high frequency of cirrus occurrence near the tropopause in Kunming and Lhasa. The top height of cirrus occurrence at both sites was above the cold point tropopause and the lapse rate tropopause. Both Kunming and Lhasa had the highest frequency of thin cirrus clouds in the 0-0.4 km vertical cirrus thickness range.

Nitrous oxide (N2O) is the fourth most important greenhouse gas in the atmosphere and is considered the most important current source gas emission for global stratospheric ozone depletion (O3). It has natural and anthropogenic sources, mainly as an unintended by-product of food production activities. This work examines the identification and quantification of trends in the N2O concentration from the middle troposphere to the middle stratosphere (MTMS) by in situ and remote sensing observations. The temporal variability of N2O is addressed using a comprehensive dataset of in situ and remote sensing N2O concentrations based on aircraft and balloon measurements in the MTMS from 1987 to 2018. We determine N2O trends in the MTMS, based on observations. This consistent dataset was also used to study the N2O seasonal cycle to investigate the relationship between abundances and its emission sources through zonal means. The results show a long-term increase in global N2O concentration in the MTMS with an average of 0.89 ± 0.07 ppb/yr in the troposphere and 0.96 ± 0.15 ppb/yr in the stratosphere, consistent with 0.80 ppb/yr derived from ground-based measurements and 0.799 ± 0.024 ppb/yr ACE-FTS (Atmospheric Chemistry Experiment Fourier Transform Spectrometer) satellite measurements.

Water vapor measurements by frost point hygrometers (FPHs) carried aboard aircraft during the mid-1940s revealed the ubiquitous dryness of the stratosphere. It was not until the 1960s that a lightweight and compact FPH was developed for use on meteorological balloons, allowing water vapor vertical profiles to be measured in situ from the very wet surface layer to the extremely dry stratosphere. Though modern balloon-borne FPHs are very technologically advanced compared to the early instruments, the actual measurement principle has remained unchanged. Today, balloon-borne FPHs are routinely launched from a number of sites to detect water vapor changes in the upper troposphere and stratosphere. The vertical profiles of water vapor provided by balloon-borne FPHs have proven extremely useful in the evaluation of stratospheric water vapor measurements by satellite-based instruments, especially in refining the algorithms used to retrieve water vapor profile information from satellite radiance data. Two such examples are provided here.

The significant climate feedback of stratospheric water vapor (SWV) necessitates quantification of changes in the SWV budget. Model simulations driven by the newest ECMWF reanalysis ERA5, satellite observations from the Microwave Limb Sounder (MLS) and in-situ frost point hygrometer observations from Boulder consistently show substantial stratospheric moistening after the year 2000, following a drop in water vapor at the turn of the millenium. The time evolution of the simulated SWV anomalies is in excellent agreement with that derived from MLS. We find strong positive SVW trends in the Northern Hemisphere and weakly negative trends over the South Pole, mainly during austral winter. Moistening of the tropical stratosphere after 2000 occurs mainly during late boreal winter/spring, reaches values of ∼0.2 ppm/decade, is well correlated with a warming of the cold point tropopause by ∼0.4 K/decade and is partially caused by volcanic eruptions and ENSO.

The structure of the tropopause transition layer (TTL) over the Asian summer monsoon (ASM) anticyclone is analyzed on the basis of high-resolution balloon soundings of temperature, ozone, and water vapor at Kunming and Lhasa, China during 11 summer monsoon seasons between 2009 and 2019. Two definitions of the TTL, one based on thermal structure and one based on tracer correlations of O-3 and H2O, are analyzed and compared. In tracer-tracer space, the air masses of mixed stratospheric and tropospheric characteristics are identified by using the O-3-H2O correlations. The mixed air formed a transitional layer and shows strong spatial variation in the altitude space. Statistical result shows that the altitude range of mixed air parcels spans a layer of approximately 5.5 km depth between 12.5 km and 18 km. This vertical distribution of mixed air masses is basically consistent with thermally-based TTL, which takes the level of minimum stability (LMS) and the cold point tropopause (CPT) as its lower and upper boundaries, respectively. The thermal definition regards the TTL as a thermal transition zone, but does not consider the tracer mixing features between stratosphere and troposphere. Tracer correlations can identify the mixed air mass, which is a basic feature of the TTL, whether they are from the range of the thermally-based TTL, or below the LMS, or above the CPT. Based on the O-3-H2O correlations, statistical analysis shows that about 30%-50% of air masses between the LMS and the CPT are identified as mixed. And up to 1-1.5 km above the CPT, a small fraction of air masses is also mixed, which means that air masses from the troposphere can be lifted and mixed into the free stratosphere within the ASM anticyclone region.

Definition of the tropopause has remained a focus of atmospheric science since its discovery near the beginning of the twentieth century. An accurate identification of the tropopause is a vital component to upper troposphere and lower stratosphere research, especially for studies that seek to assess and quantify the two-way exchange of air across the tropopause, which in turn impacts our understanding and prediction of Earth’s radiation budget and climate. Few universal definitions (those that can be reliably applied globally and to both common observations and numerical model output) exist and many definitions with unique limitations have been developed over the years. The most commonly used universal definition of the tropopause is the temperature lapse-rate definition established by the World Meteorological Organization (WMO) in 1957 (the LRT). Despite its widespread use, there are recurrent situations where the LRT definition fails to reliably identify the tropopause. Motivated by increased availability of coincident observations of stability and composition, we reexamine the relationship between stability and composition change in the tropopause transition layer and identify areas for improvement in a stability-based definition of the tropopause. Six locations with long-term (up to 40+ years) balloon observations of temperature, ozone, and water vapor were selected for analysis to offer a variety of environments, including tropical, subtropical, extratropical, and polar environments. Data from these sites are then used to identify covariability between several metrics of atmospheric stability and composition. We show that the vertical gradient of potential temperature is a superior stability metric to identify the greatest composition change in the tropopause transition layer, which we use to propose a new universally applicable potential temperature gradient tropopause (PTGT) definition. A comparison of the PTGT and LRT applied to both observations and reanalysis output will be shown. Overall, our results reveal that the PTGT largely agrees with the LRT, but more reliably identifies tropopause-level composition change when the two definitions differ greatly.

The Stratospheric Aerosol and Gas Experiment III (SAGE III) instrument installed on the International Space Station (ISS) has completed almost half of a decade of data collection and production of science data products. The SAGE III/ISS is a solar and lunar occultation instrument that scans the light from the Sun and Moon through the limb of the Earth’s atmosphere to produce vertical profiles of aerosol, ozone, water vapor, and other trace gases. It continues the legacy of previous SAGE instruments dating back to the 1970s to provide data continuity of stratospheric constituents critical for assessing trends in the ozone layer. This presentation shows how SAGE III/ISS aerosol and gas vertical profiles continue to benefit a worldwide database of in situ and satellite data for climate observation.

Caption: Lightning discharges appear in various colours depending on the scatter of light inside the thundercloud and in the atmosphere.The intracloud lightning discharges in the centre of the thundercloud appear to be white with a bluish tint, and the cloud-to-ground discharge below appears to be orange.The right hand side of the thundercloud exhibits a green tint that is attributed to the unique composition of hydrometeors inside the thundercloud.The photo was taken in the late evening of 10 September 2013, near Tarragona in northeastern Spain.

&lt;p&gt;The Stratospheric Aerosol and Gas Experiment III (SAGE III) instrument installed on the International Space Station (ISS) has completed almost half of a decade of data collection and production of science data products. The SAGE III/ISS is a solar and lunar occultation instrument that scans the light from the Sun and Moon through the limb of the Earth&amp;#8217;s atmosphere to produce vertical profiles of aerosol, ozone, water vapor, and other trace gases. It continues the legacy of previous SAGE instruments dating back to the 1970s to provide data continuity of stratospheric constituents critical for assessing trends in the ozone layer. This presentation shows how SAGE III/ISS aerosol and gas vertical profiles continue to benefit a worldwide database of in situ and satellite data for climate observation.&lt;/p&gt;

Nineteen limb-viewing data sets (occultation, passive thermal, and UV scattering) and two nadir upper tropospheric humidity (UTH) data sets are intercompared and also compared to frost-point hygrometer balloon sondes. The upper troposphere considered here covers the pressure range from 300–100 hPa. UTH is a challenging measurement, because concentrations vary between 2–1000 ppmv (parts per million by volume), with sharp changes in vertical gradients near the tropopause. Cloudiness in this region also makes the measurement challenging. The atmospheric temperature is also highly variable ranging from 180–250 K. The assessment of satellite-measured UTH is based on coincident comparisons with balloon frost-point hygrometer sondes, multi-month mapped comparisons, zonal mean time series comparisons, and coincident satellite-to-satellite comparisons. While the satellite fields show similar features in maps and time series, quantitatively they can differ by a factor of 2 in concentration, with strong dependencies on the amount of UTH. Additionally, time-lag response-corrected Vaisala RS92 radiosondes are compared to satellites and the frost-point hygrometer measurements. In summary, most satellite data sets reviewed here show on average ∼30 % agreement amongst themselves and frost-point data but with an additional ∼30 % variability about the mean bias. The Vaisala RS92 sonde, even with a time-lag correction, shows poor behavior for pressures less than 200 hPa.

We would like to thank the authors for their work that will help to improve the time stability of the Aura MLS observations of H2O and N2O. We also would like to advertise them that the N2O drift of the MLS v4 has already been discussed in the evaluation paper of the BASCOE Reanalysis of Aura MLS, version 2 (BRAM2, Errera et al., 2019) using observations from ACEFTS v3.6, MIPAS IMK v5 and MLS N2O from the 640 GHz radiometer. The N2O drift is clearly visible on the Fig. 6 of Errera et al. (reproduced here below) which shows the time series of the monthly mean bias and standard deviation of the differences between BRAM2 and the above mentioned satellite data for several pressure levels and latitude bands. Also, Errera et al. wrote that “analyses of the deseasonalized time series of the biases [of BRAM2] reveal a significant drift of 5, 7 and 5% per decade against ACE-FTS, MIPAS and MLS_N2O_640 for the period 2005–2012 and 10% against ACE-FTS for 2005–2017” (see on their page 14). We thus believe that Errera et al. could be cited in your paper.

ABSTRACTLife on Earth vitally depends on the availability of water. Human pressure on freshwater resources is increasing, as is human exposure to weather-related extremes (droughts, storms, floods) caused by climate change. Understanding these changes is pivotal for developing mitigation and adaptation strategies. The Global Climate Observing System (GCOS) defines a suite of essential climate variables (ECVs), many related to the water cycle, required to systematically monitor Earth’s climate system. Since long-term observations of these ECVs are derived from different observation techniques, platforms, instruments, and retrieval algorithms, they often lack the accuracy, completeness, and resolution, to consistently characterize water cycle variability at multiple spatial and temporal scales. Here, we review the capability of ground-based and remotely sensed observations of water cycle ECVs to consistently observe the hydrological cycle. We evaluate the relevant land, atmosphere, and ocean water storages and the fluxes between them, including anthropogenic water use. Particularly, we assess how well they close on multiple temporal and spatial scales. On this basis, we discuss gaps in observation systems and formulate guidelines for future water cycle observation strategies. We conclude that, while long-term water cycle monitoring has greatly advanced in the past, many observational gaps still need to be overcome to close the water budget and enable a comprehensive and consistent assessment across scales. Trends in water cycle components can only be observed with great uncertainty, mainly due to insufficient length and homogeneity. An advanced closure of the water cycle requires improved model–data synthesis capabilities, particularly at regional to local scales.

The Stratospheric Aerosol and Gas Experiment III (SAGE III) instrument installed on the International Space Station (ISS) has completed over three and a half years of data collection and production of science data products. The SAGE III/ISS is a solar and lunar occultation instrument that scans the light from the Sun and Moon through the limb of the Earth’s atmosphere to produce vertical profiles of aerosol, ozone, water vapor, and other trace gases. It continues the legacy of previous SAGE instruments dating back to the 1970s to provide data continuity of stratospheric constituents critical for assessing trends in the ozone layer. This presentation shows the validation results of comparing SAGE III/ISS ozone and water vapor vertical profiles from the newly released v5.2 science product with those of in situ and satellite data .

UCATS (the UAS Chromatograph for Atmospheric Trace Species) was designed and built for observations of important atmospheric trace gases from unmanned aircraft systems (UAS) in the upper troposphere and lower stratosphere (UTLS). Initially it measured major chlorofluorocarbons (CFCs) and the stratospheric transport tracers nitrous oxide (N2O) and sulfur hexafluoride (SF6), using gas chromatography with electron capture detection. Compact commercial absorption spectrometers for ozone (O3) and water vapor (H2O) were added to enhance its capabilities on platforms with relatively small payloads. UCATS has since been reconfigured to measure methane (CH4), carbon monoxide (CO), and molecular hydrogen (H2) instead of CFCs and has undergone numerous upgrades to its subsystems. It has served as part of large payloads on stratospheric UAS missions to probe the tropical tropopause region and transport of air into the stratosphere; in piloted aircraft studies of greenhouse gases, transport, and chemistry in the troposphere; and in 2021 is scheduled to return to the study of stratospheric ozone and halogen compounds, one of its original goals. Each deployment brought different challenges, which were largely met or resolved. The design, capabilities, modifications, and some results from UCATS are shown and described here, including changes for future missions.

The Microwave Limb Sounder (MLS), launched on NASA's Aura spacecraft in 2004, measures vertical profiles of the abundances of key atmospheric species from the upper troposphere to the mesosphere with daily near-global coverage. We review the first 15 years of the record of H2O and N2O measurements from the MLS 190 GHz subsystem (along with other 190 GHz information), with a focus on their long-term stability, largely based on comparisons with measurements from other sensors. These comparisons generally show signs of an increasing drift in the MLS “version 4” (v4) H2O record starting around 2010. Specifically, comparisons with v4.1 measurements from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) indicate a ∼ 2 %–3 % per decade drift over much of the stratosphere, increasing to as much as ∼ 7 % per decade around 46 hPa. Larger drifts, of around 7 %–11 % per decade, are seen in comparisons to balloon-borne frost point hygrometer measurements in the lower stratosphere. Microphysical calculations considering the formation of polar stratospheric clouds in the Antarctic winter stratosphere corroborate a drift in MLS v4 water vapor measurements in that region and season. In contrast, comparisons with the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument on NASA's Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED) mission, and with ground-based Water Vapor Millimeter-wave Spectrometer (WVMS) instruments, do not show statistically significant drifts. However, the uncertainty in these comparisons is large enough to encompass most of the drifts identified in other comparisons. In parallel, the MLS v4 N2O product is shown to be generally decreasing over the same period (when an increase in stratospheric N2O is expected, reflecting a secular growth in emissions), with a more pronounced drift in the lower stratosphere than that found for H2O. Comparisons to ACE-FTS and to MLS N2O observations in a different spectral region, with the latter available from 2004 to 2013, indicate an altitude-dependent drift, growing from 5 % per decade or less in the mid-stratosphere to as much as 15 % per decade in the lower stratosphere. Detailed investigations of the behavior of the MLS 190 GHz subsystem reveal a drift in its “sideband fraction” (the relative sensitivity of the 190 GHz receiver to the two different parts of the microwave spectrum that it observes). Our studies indicate that sideband fraction drift accounts for much of the observed changes in the MLS H2O product and some portion of the changes seen in N2O. The 190 GHz sideband fraction drift has been corrected in the new “version 5” (v5) MLS algorithms, which have now been used to reprocess the entire MLS record. As a result of this correction, the MLS v5 H2O record shows no statistically significant drifts compared to ACE-FTS. However, statistically significant drifts remain between MLS v5 and frost point measurements, although they are reduced. Drifts in v5 N2O are about half the size of those in v4 but remain statistically significant. Scientists are advised to use MLS v5 data in all future studies. Quantification of interregional and seasonal to annual changes in MLS H2O and N2O will not be affected by the drift. However, caution is advised in studies using the MLS record to examine long-term (multiyear) variability and trends in either of these species, especially N2O; such studies should only be undertaken in consultation with the MLS team. Importantly, this drift does not affect any of the MLS observations made in other spectral regions such as O3, HCl, CO, ClO, or temperature.