Deep ice core drilling efforts have been ongoing since the 1960’ and several records of Greenland impurities exist thanks to huge multiple nation efforts and the work of many dedicated people over the years and include Camp Century, Dye3, GRIP, GISP2, Renland, NGRIP, NEEM, RECAP and the new EGRIP ice core. The 25 Dansgaard-Oeschger (DO) events, first named in the Greenland ice core δ 18O signal from GRIP, are found in all deep Greenland ice cores with a significant corresponding signal also reflected in chemistry and impurities contained in the ice. Continuous flow analysis (CFA) is the preferred method to investigate the long Greenland ice cores for their impurity content and often includes NH4+ , Ca2+ , and Na+ ions, while Ion Chromtography (IC) was previously utilized. The chemical impurities besides being influenced by transport and accumulation patterns, provide information about forest fires, wind-blown dust, and sea ice, respectively. We show here CFA measurements performed in Copenhagen in 2019 on the Dye3 old core at depths of 1753–1820m and 1865–1918m representing both Holocene, Younger Dryas and Glacial sections (GS 5 to 12) and the high accumulation RECAP ice core CFA profile. The ReCAP ice core extends 584.11m and while the glacial section is strongly thinned and covers just 20 meters of the ReCAP core, it nonetheless due to the high resolution of the CFA measurements done in 2015 and 2016, cover all 25 expected DO event. Here we present these two datasets of Dye 3 and RECAP by CFA done at University of Copenhagen and compare for DO'swith other central Greenland ice cores with the aim to constrain spatial patterns of DO events in Greenland ice core chemistry records.

Ancient texts and archaeological evidence indicate substantial lead exposure during antiquity that potentially impacted human health. Although lead exposure routes were many and included the use of glazed tablewares, paints, cosmetics, and even intentional ingestion, the most significant for the nonelite, rural majority of the population may have been through background air pollution from mining and smelting of silver and lead ores that underpinned the Roman economy. Here, we determined potential health effects of this air pollution using Arctic ice core measurements of Roman-era lead pollution, atmospheric modeling, and modern epidemiology-based relationships between air concentrations, blood lead levels (BLLs), and cognitive decline. Findings suggest air lead concentrations exceeded 150 ng/m 3 near metallurgical emission sources, with average enhancements of >1.0 ng/m 3 over Europe during the Pax Romana apogee of the Roman Empire. The result was blood lead enhancements in young children of about 2.4 µg/dl above an estimated Neolithic background of 1.0 µg/dl, leading to widespread cognitive decline including a 2.5-to-3 point reduction in intelligence quotient throughout the Roman Empire.

Rising temperatures and melting of snow and ice since 2000 CE may result in coastal soil regions in Greenland providing more mineral particles to the Greenland ice sheet than before. To examine seasonal variations of the concentrations and source regions of mineral particles in recent snow in inland Northeast Greenland, we analyzed the total (i.e., soluble and insoluble) concentrations of major metallic elements (Al. Ca, and Fe) and the size distributions of mineral particles in snow pit samples covering 2013-2017 at the East Greenland Ice Core Project site. The total concentrations of metallic elements showed clear seasonality with spring maxima, indicating that the mineral particle concentrations peaked in this season. Volcanic products from the 2014-2015 eruptions of B & aacute;r & eth;arbunga, Iceland, had little effect on the metallic element concentrations. The increased Ca/Al ratio, Ca solubility, and fine particle fraction (<= 5 mu m) in winter-spring indicated that the relative contributions of mineral particles originating from distant arid regions increased in those seasons. In summer-autumn, the Ca/Al ratio and Ca solubility decreased, and the coarse particle fraction (>5 mu m) increased, suggesting that the relative contributions from coastal soil regions in Greenland increased in those seasons.

Estimating fire emissions prior to the satellite era is challenging because observations are limited, leading to large uncertainties in the calculated aerosol climate forcing following the preindustrial era. This challenge further limits the ability of climate models to accurately project future climate change. Here, we reconstruct a gridded dataset of global biomass burning emissions from 1750 to 2010 using inverse analysis that leveraged a global array of 31 ice core records of black carbon deposition fluxes, two different historical emission inventories as a priori estimates, and emission-deposition sensitivities simulated by the atmospheric chemical transport model GEOS-Chem. The reconstructed emissions exhibit greater temporal variabilities which are more consistent with paleoclimate proxies. Our ice core constrained emissions reduced the uncertainties in simulated cloud condensation nuclei and aerosol radiative forcing associated with the discrepancy in preindustrial biomass burning emissions. The derived emissions can also be used in studies of ocean and terrestrial biogeochemistry. Two new gridded, model-ready historical biomass burning emission datasets (BB4CMIPpost and LPJ-LMfirepost) are developed by inverse modeling that leveraged 31 ice core records, existing emissions as a priori, and chemical transport model simulations.

The Millennium Eruption of Mt. Baekdu, one of the largest volcanic eruptions in the Common Era, initiated in late 946. It remains uncertain whether its two main compositional phases, rhyolite and trachyte, were expelled in a single eruption or in two. Investigations based on proximal and medial ash have not resolved this question, prompting us to turn to high-resolution ice-core evidence. Here, we report a suite of glaciochemical and tephra analyses of a Greenlandic ice core, identifying the transition from rhyolitic to trachytic tephra with corresponding spikes in insoluble particle fallout. By modeling annual snow accumulation, we estimate an interval of one to two months between these spikes, which approximates the hiatus between two eruptive phases. Additionally, negligible sulfur mass-independent fractionation, near-synchroneity between particle and sulfate deposition, and peak sulfur fallout in winter all indicate an ephemeral aerosol veil. These factors limited the climate forcing potential of the Millennium Eruption. The Millennium Eruption of Mt. Baekdu was a multiphase eruption with two main phases separated approximately by one or two months, and was less climatically significant than previously thought, according to high-resolution glaciochemical and tephra analyses of an ice core in Greenland.

We here describe, document, and make available a wide range of data sets used for annual-layer identification in ice cores from DYE-3, GRIP, NGRIP, NEEM, and EGRIP. The data stem from detailed measurements performed both on the main deep cores and shallow cores over more than 40 years using many different setups developed by research groups in several countries and comprise both discrete measurements from cut ice samples and continuous-flow analysis data. The data series were used for counting annual layers 60 000 years back in time during the construction of the Greenland Ice-Core Chronology 2005 (GICC05) and/or the revised GICC21, which currently only reaches 3800 years back. Now that the underlying data are made available (listed in Table 1) we also release the individual annual-layer positions of the GICC05 timescale which are based on these data sets. We hope that the release of the data sets will stimulate further studies of the past climate taking advantage of these highly resolved data series covering a large part of the interior of the Greenland ice sheet.

Insoluble particles in ice cores record signatures of past climate parameters like vegetation dynamics, volcanic activity, and aridity. For some of them, the analytical detection relies on intensive bench microscopy investigation and requires dedicated sample preparation steps. Both are laborious, require in-depth knowledge, and often restrict sampling strategies. To help overcome these limitations, we present a framework based on flow imaging microscopy coupled to a deep neural network for autonomous image classification of ice core particles. We train the network to classify seven commonly found classes, namely mineral dust, felsic and mafic (basaltic) volcanic ash grains (tephra), three species of pollen (Corylus avellana, Quercus robur, Quercus suber), and contamination particles that may be introduced onto the ice core surface during core handling operations. The trained network achieves 96.8 % classification accuracy at test time. We present the system's potential and its limitations with respect to the detection of mineral dust, pollen grains, and tephra shards, using both controlled materials and real ice core samples. The methodology requires little sample material, is non-destructive, fully reproducible, and does not require any sample preparation procedures. The presented framework can bolster research in the field by cutting down processing time, supporting human-operated microscopy, and further unlocking the paleoclimate potential of ice core records by providing the opportunity to identify an array of ice core particles. Suggestions for an improved system to be deployed within a continuous flow analysis workflow are also presented.

Black carbon emitted by incomplete combustion of fossil fuels and biomass has a net warming effect in the atmosphere and reduces the albedo when deposited on ice and snow; accurate knowledge of past emissions is essential to quantify and model associated global climate forcing. Although bottom-up inventories provide historical Black Carbon emission estimates that are widely used in Earth System Models, they are poorly constrained by observations prior to the late 20th century. Here we use an objective inversion technique based on detailed atmospheric transport and deposition modeling to reconstruct 1850 to 2000 emissions from thirteen Northern Hemisphere ice-core records. We find substantial discrepancies between reconstructed Black Carbon emissions and existing bottom-up inventories which do not fully capture the complex spatial-temporal emission patterns. Our findings imply changes to existing historical Black Carbon radiative forcing estimates are necessary, with potential implications for observation-constrained climate sensitivity.

Chemical profiles from Greenland ice cores show that the frequency of volcanism was higher during the last glacial-interglacial transition (LGIT) and early Holocene, (17–9 ka b2k) than in any other period during the last 110 kyr. This increased frequency has partly been linked to climate-driven melting of the Icelandic ice sheet during the last deglaciation, with regional isostatic changes thought to alter mantle viscosity and lead to more eruptions. Our study is the first to construct a comprehensive tephrochronological framework from Greenland ice cores over the LGIT to aid in the reconstruction of volcanic activity over this period. The framework is based on extensive high-resolution sampling of three Greenland ice cores between 17.4 and 11.6 ka b2k and comprises a total of 64 cryptotephra deposits from the NGRIP, GRIP and NEEM ice cores. We show that many of these tephras are preserved within the core without an associated chemical signature in the ice, which implies that reconstructions of volcanism based solely on glacio-chemical indicators might underestimate the number of events. Single glass shards from each deposit were geochemically characterised to trace the volcanic source and many of these deposits could be correlated between cores. We show that the 64 deposits represent tephra deposits from 42 separate volcanic events, and of these, 39 are from Iceland, two from the north Pacific region (Japan and USA) and one has an unknown source. Six deposits can be correlated to terrestrial and/or marine tephra deposits in the Northern Hemisphere and the remaining 36 are unreported in other archives. We did not locate tephra from the compositionally distinctive Laacher See eruption (∼13 ka b2k) in our records. Combining our new discoveries with the previously published tephra framework, raises the number of individual tephra horizons found in Greenland ice over this interval to 50. This significantly improves the regional tephrochronological framework, our knowledge of the eruptive history of Iceland during the LGIT and provides new tephra constraints over key LGIT climate events. Consequentially, this framework can guide sampling strategies of future tephra studies in the terrestrial and marine realms aiming to link these records to the Greenland ice cores to assess regional climate synchroneity.

Large volcanic eruptions occurring in the last glacial period can be detected by their accompanying sulfuric acid deposition in continuous ice cores. Here we employ continuous sulfate and sulfur records from three Greenland and three Antarctic ice cores to estimate the emission strength, the frequency and the climatic forcing of large volcanic eruptions that occurred during the second half of the last glacial period and the early Holocene, 60–9 kyr before 2000 CE (b2k). Over most of the investigated interval the ice cores are synchronized, making it possible to distinguish large eruptions with a global sulfate distribution from eruptions detectable in one hemisphere only. Due to limited data resolution and large variability in the sulfate background signal, particularly in the Greenland glacial climate, we only list Greenland sulfate depositions larger than 20 kg km−2 and Antarctic sulfate depositions larger than 10 kg km−2. With those restrictions, we identify 1113 volcanic eruptions in Greenland and 737 eruptions in Antarctica within the 51 kyr period – for which the sulfate deposition of 85 eruptions is found at both poles (bipolar eruptions). Based on the ratio of Greenland and Antarctic sulfate deposition, we estimate the latitudinal band of the bipolar eruptions and assess their approximate climatic forcing based on established methods. A total of 25 of the identified bipolar eruptions are larger than any volcanic eruption occurring in the last 2500 years, and 69 eruptions are estimated to have larger sulfur emission strengths than the Tambora, Indonesia, eruption (1815 CE). Throughout the investigated period, the frequency of volcanic eruptions is rather constant and comparable to that of recent times. During the deglacial period (16–9 ka b2k), however, there is a notable increase in the frequency of volcanic events recorded in Greenland and an obvious increase in the fraction of very large eruptions. For Antarctica, the deglacial period cannot be distinguished from other periods. This confirms the suggestion that the isostatic unloading of the Northern Hemisphere (NH) ice sheets may be related to the enhanced NH volcanic activity. Our ice-core-based volcanic sulfate records provide the atmospheric sulfate burden and estimates of climate forcing for further research on climate impact and understanding the mechanism of the Earth system.

Camp Century is an American military base built in 1959 under the surface of the Greenland ice sheet and decommissioned in 1967. Here, we use outputs from RACMO2.3p2 and CanESM2 climate models, adjusted to meteorological observations, and a firn model to simulate the firn density and temperature at Camp Century between 1966 and 2100. The model output is evaluated against an extensive set of firn 3observations and three Representative Concentration Pathways (RCP2.6, 4.5 and 8.5) are considered as future scenarios. Our model suggests that the upper horizon of the Camp Century debris field – observed at a depth of 32 m in 2017 – will continue to be buried by persistent net accumulation over the next eighty years under all RCP scenarios. This horizon depth will be between 58 and 64 m in 2100, depending on the RCP scenario. We estimate a maximum meltwater percolation depth of 1.1 m under all RCP scenarios. We therefore find it extremely unlikely that surface meltwater interacts with the subsurface debris field at Camp Century before 2100 under all RCP scenarios. Camp Century’s future is representative of the firn area in northwestern Greenland, bound to shift from dry snow to a percolation regime. Our model suggests that 10 m firn temperatures at Camp Century will increase from −24.0°C in 1966 to −21.3, −20.0 and −18.6°C in 2100 under the RCP2.6, 4.5 and 8.5 scenarios, respectively. We reveal a previously unknown warm bias in air temperatures simulated at Camp Century by both RACMO2.3p2 and CanESM2 climate models which needs to be accounted for when using these models to predict melt, firn evolution and sea-level contribution of the Greenland ice sheet. We also present novel in situ measurements of firn compaction rates, which indicate that about 25% of firn compaction of the top 62 m of firn occurs below 20 m depth. This highlights the importance of deep-firn compaction measurements for model evaluation and correction of altimetry products.

To reconstruct climate history of the past 1.5 Million years, the project: Beyond EPICA Oldest Ice (BEOI) will drill about 2700 m of ice core in East Antarctica (2021–2025). As drilling fluid, an aliphatic ester fluid, EstisolTM 140, will be used. Newly drilled ice cores will be retrieved from the drill soaked in fluid, and this fluid should be removed from the cores. Most of it will be vacuum-cleaned off in a Fluid Extraction Device and wiped off with paper towels. Based on our experiences in Greenland deep ice coring, most of the residual fluid can be removed by storing the cores openly on shelves in a ventilated room. After a week of “drying”, the cores have a dry feel, handling them do not give “wet” gloves and they can easily be marked with lead pencils. This paper presents a theoretical investigation and some simple testing on the “drying” process. The rates of sublimation of ice and evaporation of fluid have been calculated at different temperatures. The calculations show that sublimation of the ice core should not occur, and that evaporation of fluid should be almost negligible. Our test results support these calculations, but also revealed significant fluid run-off and dripping, resulting in the removal of most of the fluid in a couple of days, independent of temperature and ventilation conditions. Finally, we discuss crucial factors that ensure optimal long-term ice core preservation in storage, such as temperature stability, defrosting cycles of freezers and open core storage versus storage of cores in insulated crates.

SignificanceThe first century BCE fall of the Roman Republic and Ptolemaic Kingdom and subsequent rise of the Roman Empire were among the most important political transitions in the history of Western civilization. Volcanic fallout in well-dated Arctic ice core records, climate proxies, and Earth system modeling show that this transition occurred during an extreme cold period resulting from a massive eruption of Alaska’s Okmok volcano early in 43 BCE. Written sources describe unusual climate, crop failures, famine, disease, and unrest in the Mediterranean immediately following the eruption—suggesting significant vulnerability to hydroclimatic shocks in otherwise sophisticated and powerful ancient states. Such shocks must be seen as having played a role in the historical developments for which the period is famed.

Temporal variability in surface mass balance (SMB) on the Greenland ice sheet is important for understanding the mass balance of the ice sheet. Additionally, knowledge of the spatial variability in SMB at ice core drilling sites helps to interpret the spatial representativeness of SMB data obtained from a single ice core. In this study, to investigate the spatiotemporal variability in recent SMB in the East Greenland Ice Core Project (EGRIP) area in the northeastern Greenland ice sheet, pit observations were made at six sites in the summers of 2016?2018. In all pits, depth profiles of water isotope ratios showed clear seasonal variations. The annual SMB differed from site to site, which is probably due to post-depositional redistribution of snow caused by wind erosion and snowdrift. However, the multiple-site averages of annual SMBs, which ranged from 134 to 157 mm w. e. yr-1 (average 146 mm w. e. yr? 1) during 2009?2017, were very similar. This indicates that annual SMBs in the EGRIP area were nearly constant in this period. The seasonal SMBs in the EGRIP area tended to be larger in the summer?winter period than in the winter?summer period.

The last glacial period is characterized by a number of millennial climate events that have been identified in both Greenland and Antarctic ice cores and that are abrupt in Greenland climate records. The mechanisms governing this climate variability remain a puzzle that requires a precise synchronization of ice cores from the two hemispheres to be resolved. Previously, Greenland and Antarctic ice cores have been synchronized primarily via their common records of gas concentrations or isotopes from the trapped air and via cosmogenic isotopes measured on the ice. In this work, we apply ice core volcanic proxies and annual layer counting to identify large volcanic eruptions that have left a signature in both Greenland and Antarctica. Generally, no tephra is associated with those eruptions in the ice cores, so the source of the eruptions cannot be identified. Instead, we identify and match sequences of volcanic eruptions with bipolar distribution of sulfate, i.e. unique patterns of volcanic events separated by the same number of years at the two poles. Using this approach, we pinpoint 82 large bipolar volcanic eruptions throughout the second half of the last glacial period (12–60 ka). This improved ice core synchronization is applied to determine the bipolar phasing of abrupt climate change events at decadal-scale precision. In response to Greenland abrupt climatic transitions, we find a response in the Antarctic water isotope signals (δ18O and deuterium excess) that is both more immediate and more abrupt than that found with previous gas-based interpolar synchronizations, providing additional support for our volcanic framework. On average, the Antarctic bipolar seesaw climate response lags the midpoint of Greenland abrupt δ18O transitions by 122±24 years. The time difference between Antarctic signals in deuterium excess and δ18O, which likewise informs the time needed to propagate the signal as described by the theory of the bipolar seesaw but is less sensitive to synchronization errors, suggests an Antarctic δ18O lag behind Greenland of 152±37 years. These estimates are shorter than the 200 years suggested by earlier gas-based synchronizations. As before, we find variations in the timing and duration between the response at different sites and for different events suggesting an interaction of oceanic and atmospheric teleconnection patterns as well as internal climate variability.

HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés. Impact of past environmental changes on the genetic diversity of the remnant natural populations of Cilician fir in Lebanon Lara Awad, Bruno Fady, Carla Khater, Rachid Cheddadi

We collected snow samples from two pits with depths of 4.02 and 3.18 m at the East Greenland Ice Core Project camp (75?37?N, 35?59?W), Greenland in the summer of 2016 to estimate recent annual snow deposition and examine seasonal variation in major ion species, stable isotopes of water and microparticles (dust). Dating based on clear seasonal variation in chemical components indicated that the 4.02- and 3.18-m-deep pits included snow deposition corresponding to ten years from 2006 to 2016 and seven years from 2009 to 2016, respectively. The mean values for annual snow deposition for the 4.02-m-deep pit were 138 and 145 mm yr? 1 in water equivalent (mm w.e. Yr? 1) in 2006?2016 and 2009?2016, respectively. The average deposition for the 3.18-m-deep pit was 149 mm w.e. Yr? 1 between 2009 and 2016. Seasonal variation in concentrations of major ion species and dust were similar to those previously reported for Greenland. The maximum Cl-/Na+ concentration ratios in the summer were much higher than the ratios at other sites in Greenland.

SignificanceDetailed lead pollution measurements in an array of 13 ice cores spanning nearly half the Arctic showed surprisingly similar temporal variability during the past 2 millennia until the Industrial Revolution. Lead pollution increased by 250- to 300-fold from the Early Middle Ages to the 1970s industrial peak, reflecting large-scale emissions changes from ancient European silver production, recent fossil fuel burning, and other industrial activities. Pronounced decadal-scale increases coincided with exploitation of new mining districts, technology development, and periods of economic prosperity, while decreases coincided with climate disruptions, famines, major wars, and plagues. Despite midlatitude pollution abatement policies that reduced Arctic lead pollution by >80% since the 1970s, recent levels remain 60-fold higher than at the start of the Middle Ages.