The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is an infrared (IR) limb emission spectrometer on the Envisat platform. It measures trace gas distributions during day and night, pole-to-pole, over an altitude range from 6 to 70 km in nominal mode and up to 170 km in special modes, depending on the measurement mode, producing more than 1000 profiles day−1. We present the results of a validation study of methane, version V5R_CH4_222, retrieved with the IMK/IAA (Institut für Meteorologie und Klimaforschung, Karlsruhe/Instituto de Astrofisica de Andalucia, Grenada) MIPAS scientific level 2 processor. The level 1 spectra are provided by the ESA (European Space Agency) and version 5 was used. The time period covered is 2005–2012, which corresponds to the period when MIPAS measured trace gas distributions at a reduced spectral resolution of 0.0625 cm−1. The comparison with satellite instruments includes the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS), the HALogen Occultation Experiment (HALOE), the Solar Occultation For Ice Experiment (SOFIE) and the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY). Furthermore, comparisons with MkIV balloon-borne solar occultation measurements and with air sampling measurements performed by the University of Frankfurt are presented. The validation activities include bias determination, assessment of stability, precision validation, analysis of histograms and comparison of corresponding climatologies. Above 50 km altitude, MIPAS methane mixing ratios agree within 3 % with ACE-FTS and SOFIE. Between 30 and 40 km an agreement within 3 % with SCIAMACHY has been found. In the middle stratosphere, there is no clear indication of a MIPAS bias since comparisons with various instruments contradict each other. In the lower stratosphere (below 25 km) MIPAS CH4 is biased high with respect to satellite instruments, and the most likely estimate of this bias is 14 %. However, in the comparison with CH4 data obtained from cryogenic whole-air sampler (cryosampler) measurements, there is no evidence of a high bias in MIPAS between 20 and 25 km altitude. Precision validation is performed on collocated MIPAS–MIPAS pairs and suggests a slight underestimation of its uncertainties by a factor of 1.2. No significant evidence of an instrumental drift has been found.

The Solar Occultation for Ice Experiment (SOFIE) makes broadband transmission measurements centered at 5.32 μm to determine the concentration profile of nitric oxide (NO). These measurements show a signal oscillation due to detector temperature variations that severely limit the accuracy of NO retrievals if corrections are not applied. An empirical correction was developed to remove this instrumental error. This paper describes the correction, its impact on the retrieval, and presents a comparison from 87 to 105 km versus coincident atmospheric chemistry experiment-Fourier transform spectrometer (ACE-FTS) measurements. The southern hemisphere (SH) shows excellent agreement between the datasets, with statistically insignificant differences. The northern hemisphere (NH) SOFIE measurements exhibit a low bias of -18.5% compared to ACE-FTS. NH measurements (sunrise observations) are still under study, and only SH NO data (sunset observations) are currently publicly available as of SOFIE data version 1.2.

Observations of polar mesospheric clouds (PMC) and their environment from the Solar Occultation For Ice Experiment (SOFIE) are examined to quantify differences between the Northern Hemisphere (NH) and Southern Hemisphere (SH) during summer. The results indicate that hemispheric differences are smaller when using pressure as the vertical coordinate, instead of altitude. The peak in PMC mass density (Zmax) was found to exist 1.2km higher in the SH, but at about the same pressure (∼0.0055hPa) in both hemispheres. This occurs because systematically warmer temperatures in the SH polar summer stratosphere and mesosphere expand the overlying atmosphere to raise the altitudes of pressure levels in the SH mesosphere relative to the NH. For the five southern and five northern PMC seasons observed to date, the primary differences are that PMCs in the Northern Hemisphere are more frequent (24%±32%), have greater ice mass density (65%±26% at Zmax), and exist for a longer seasonal period (10±10 days). These differences are attributed primarily to lower temperatures (4 to 9K) in the north because water vapor differences are small (1.9%±5.4% at Zmax).

This work provides the first observational evidence that ice particles comprising polar mesospheric clouds (PMC) contain small amounts of meteoric smoke (0.01–3% by volume), using measurements from the Solar Occultation For Ice Experiment (SOFIE). PMC observations at wavelengths from the ultraviolet through the infrared are inconsistent with pure ice, but can be explained in terms of the extinction simulated for a mixture of ice and meteoric smoke. Simulations of ice–smoke mixtures considered 25 different smoke compositions. The PMC observations were consistent with smoke composed of carbon (C), wüstite (FeO), or magnesiowüstite (MgxFe1−xO, x=0.1–0.6), and inconsistent with the other compositions. A method was established for simultaneously retrieving PMC particle size and the volume fraction of smoke in ice using SOFIE observations at multiple wavelengths. Compared to assuming pure ice, SOFIE retrievals considering ice–smoke mixtures yield smaller ice radii (24%) and higher concentrations (137%).

Temperature observations in the polar mesosphere and lower thermosphere are critical for studies of polar mesospheric cloud (PMC) formation and variability. The Solar Occultation for Ice Experiment (SOFIE) on NASA's Aeronomy of Ice in the Mesosphere (AIM) satellite has been measuring temperatures in the polar atmosphere nearly continuously since 2007. We herein present an improved SOFIE temperature data set and validate it against a variety of satellite and ground‐based observations. We find that when taking all comparisons together, SOFIE temperatures are in agreement with independent observations to within reported systematic uncertainties from 15 to 88 km altitude. Between 88 and 95 km SOFIE temperatures have a warm bias that peaks between 10 and 15 K in the Arctic summer and 20–30 K in the Antarctic summer. Much of the warm bias is likely related to uncertainties in prescribed atomic oxygen densities that are required for the SOFIE temperature retrieval.

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Water vapor measured by the Solar Occultation for Ice Experiment (SOFIE) instrument on the Aeronomy of Ice in the Mesosphere satellite has been validated in the vertical range 45–95 km. Precision estimates for SOFIE v1.022 H2O are ∼0.2%–2.5% up to 80 km and degrade to ∼20% at ∼90 km. The SOFIE total systematic error from the retrieval analysis remains at ∼3%–4% throughout the lower to middle mesosphere and increases from ∼9% at 85 km to ∼16% at 95 km. Comparisons with Atmospheric Chemistry Experiment‐Fourier Transform Spectrometer (ACE‐FTS) and Microwave Limb Sounder (MLS) H2O show excellent agreement (0%–2%) up to 80 km in the Northern Hemisphere with rare exceptions. Percentage differences above ∼85 km increase to ∼20% or worse due largely to the low H2O volume mixing ratios in the upper mesosphere. For the Southern Hemisphere SOFIE is consistently biased low by 10%–20% relative to both ACE‐FTS and MLS H2O. Slopes of SOFIE daily mean H2O isopleths on an altitude versus time cross section are used as an indicator of upwelling air motion. In the lower to middle mesosphere, the slope is the largest from mid‐May to mid‐June (maximum of ∼1.5 cm/s), and then in July and August, it is reduced significantly. Both SOFIE and MLS daily mean H2O volume mixing ratios at the polar mesospheric cloud height increase rapidly from ∼2.0 to ∼5.0 ppmv prior to the solstice and then approach a near‐constant but slightly increasing level (6.0–6.5 ppmv) throughout the season.

This work describes the first remote observations of meteoric smoke particles (MSPs) from satellite, by the Solar Occultation For Ice Experiment (SOFIE) onboard the Aeronomy of Ice in the Mesosphere (AIM) platform. The measurements show a layer of MSPs from roughly 35 to 85 km altitude, and indicate a seasonal cycle with reduced MSP abundance during polar summer. The measurements agree favorably with model results, and confirm that MSP transport by the global meridional circulation causes the dramatic reduction in MSPs during polar summer. These new observations represent a major advance in our ability to understand a hitherto poorly characterized class of particles that are thought to be important in numerous atmospheric and terrestrial processes.

The Solar Occultation For Ice Experiment (SOFIE) was launched onboard the Aeronomy of Ice in the Mesosphere (AIM) satellite on 25 April 2007, and began science observations on 14 May 2007. SOFIE conducts solar occultation measurements in 16 spectral bands that are used to retrieve vertical profiles of temperature, O3, H2O, CO2, CH4, NO, and polar mesospheric cloud (PMC) extinction at wavelengths from 0.330 to 5.006μm. SOFIE performs 15 sunset measurements at latitudes from 65° to 85°S and 15 sunrise measurements from 65° to 85°N each day. This work describes the SOFIE instrument, measurement approach, and retrieval results for the northern summer of 2007.

A new method for measuring atmospheric refraction angles is presented, with in-orbit measurements demonstrating a precision of +/-0.02 arcsec (+/-0.1 microrad). Key advantages of the method are the following: (1) Simultaneous observation of two celestial points during occultation (i.e., top and bottom edges of the solar image) eliminates error from instrument attitude uncertainty. (2) The refraction angle is primarily a normalized difference measurement, causing only scale error, not absolute error. (3) A large number of detector pixels are used in the edge location by fitting to a known edge shape. The resulting refraction angle measurements allow temperature sounding up to the lower mesosphere.

The goal of this work is to explore relationships between polar mesospheric clouds (PMCs), temperature, and water vapor and to understand the extent that bulk thermodynamic equilibrium can explain observed PMC characteristics. We use observations from the Solar Occultation for Ice Experiment (SOFIE) and employ a simple PMC model which assumes that ice exists in thermodynamic equilibrium with the local temperature and water vapor. Model results using SOFIE temperatures and water vapor are found to reproduce the observed ice layer altitudes, ice frequency versus time and altitude, ice mass density (expressed as the gas phase equivalent contained in the ice phase, Qice) versus time and altitude, and the vertical column abundance of ice (or ice water content (IWC)). The differences (model ‐ SOFIE) for July 2008 were −0.1 km in the altitude of peak ice mass density (Zmax), 16% in Qice at Zmax, and 35% in IWC. These results suggest that on average, PMCs can exist in equilibrium with the surrounding environment, and the results also imply that ice nucleation may occur throughout the PMC altitude range. Good correlations were found between ice abundance and temperature (or saturation ratio), although knowledge of both water vapor and temperature is required for a quantitative prediction of observed ice characteristics. Our results indicate that the seasonal dependence of ice abundance is generally controlled by temperature and that in a broad sense, changes in water vapor are a result of changes in ice. We also find that lower temperatures are associated with higher ice mass density, higher ice concentration, and slightly smaller particle radii. This finding indicates that the increase in ice mass density is due to the nucleation of more particles rather than the growth of existing ice, and this finding points to nucleation as an important factor in determining PMC variability.